Process and apparatus for reducing nitrogen-oxide emissions in exhaust gas

Claim 1

An exhaust gas cleaning system, comprising three serially connected catalysts: a first catalyst that stores nitrogen oxide in a lean combustion operation and desorbs the nitrogen oxides in a rich combustion operation; a second catalyst connected behind the first catalyst that produces ammonia in the rich combustion operation; and a third catalyst connected behind the second catalyst that stores the ammonia in the rich combustion operation and desorbs the ammonia in the lean combustion operation.

Claim 3

A method of cleaning an exhaust gas from a combustion system, comprising: alternately operating said combustion system in a lean condition and in a rich condition, thereby generating exhaust gas; passing said exhaust gas through a first catalyst that stores nitrogen oxide in a lean combustion operation and releases the nitrogen oxides in a rich combustion operation; further passing said exhaust gas through a second catalyst that produces ammonia in the rich combustion operation; and further passing said exhaust gas through a third catalyst that stores the ammonia in the rich combustion operation and releases the ammonia in the lean combustion operation.

Claim 4

A method of cleaning an exhaust gas from a combustion system, comprising: alternately operating said combustion system in a lean condition and in a rich condition, thereby generating exhaust gas; passing said exhaust gas through a first catalyst that stores nitrogen oxide in a lean combustion operation and releases the nitrogen oxides in a rich combustion operation; further passing said exhaust gas through a second catalyst that produces ammonia in the rich combustion operation; and further passing said exhaust gas through a third catalyst that stores the ammonia in the rich combustion operation and releases the ammonia in the lean combustion operation.

Claim 5

A method of cleaning an exhaust gas from a combustion system that operates in rich and in lean conditions, comprising: a) operating the combustion system in a rich condition, thereby producing a rich exhaust gas composition comprising nitrogen oxides and hydrogen; b) directing the rich exhaust gas composition through a first catalyst unit to a second catalyst unit which produces ammonia; c) directing the rich exhaust gas composition and ammonia to a third catalyst unit which stores the ammonia; d) switching the combustion system to a lean condition, thereby producing a lean exhaust gas composition comprising nitrogen oxides; e) directing the lean exhaust gas composition to the first catalyst unit which stores a first portion of the nitrogen oxides; f) directing the lean exhaust composition with a remaining second portion of nitrogen oxides through the second catalyst unit to the third catalyst unit which releases the ammonia and reduces the remaining second portion of nitrogen oxides using the ammonia as a reducing agent; and repeating steps a) through f).

Claim 6

A method of cleaning an exhaust gas from a combustion system that operates in rich and in lean conditions, comprising: a) operating the combustion system in a rich condition, thereby producing a rich exhaust gas composition comprising nitrogen oxides and hydrogen; b) directing the rich exhaust gas composition through a first catalyst unit to a second catalyst unit which produces ammonia; c) directing the rich exhaust gas composition and ammonia to a third catalyst unit which stores the ammonia; d) switching the combustion system to a lean condition, thereby producing a lean exhaust gas composition comprising nitrogen oxides; e) directing the lean exhaust gas composition to the first catalyst unit which stores a first portion of the nitrogen oxides; f) directing the lean exhaust composition with a remaining second portion of nitrogen oxides through the second catalyst unit to the third catalyst unit which releases the ammonia and reduces the remaining second portion of nitrogen oxides using the ammonia as a reducing agent; and repeating steps a) through f).