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US6248482B1 Expired / Lapsed US ⏱️ 0.0 years remaining

Ink, color filter, liquid crystal panel, and computer, and process for producing color filter

Assignee: Canon Inc
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Filing: 1999-03-25
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Granted: 2001-06-19
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Expires: 2019-03-25
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Abstract

Abstract Provided is a novel ink which is suitable for producing a color filter by use of an ink-jet system. The ink comprises a pyrazolone dye of the general formula (I):wherein R1 and R2 are each independently a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF3 group or an SO3(M1) group, where M1 is an alkali metal or NH4; both R3 and R4 are an SO3(M2) group, where M2 is an alkali metal or NH4.

Inventors

  • 👤 Akio Kashiwazaki
  • 👤 Katsuhiro Shirota
  • 👤 Koichiro Nakazawa
  • 👤 Masashi Hirose
  • 👤 Mayumi Yokoyama
  • 👤 Yoshihisa Yamashita

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 05:23
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30; C09D11/32; C09D11/328; G; G02; G02B; G02B5/00; G02B5/20; G02B5/201

Claims Analysis

Total Claims: 46
Claim 1
Independent Claim 109 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; at least one of R 1 and R 2 is a CF 3 group; and both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 .
Claim 2
Dependent Claim 109 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; at least one of R 1 and R 2 is a CF 3 group; and both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 .
Claim 3
Dependent Claim 31 words
The ink according to claim 1 , wherein in the pyrazolone dye of the general formula (I), R 1 is a CF 3 group and R 2 is a hydrogen atom.
Claim 4
Dependent Claim 103 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; and wherein the ink further comprises a phthalocyanine dye.
Claim 5
Dependent Claim 103 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; and wherein the ink further comprises a phthalocyanine dye.
Claim 6
Dependent Claim 126 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein at least one of R 1 and R 2 in the pyrazolone dye of the general formula (I) is a nitro group; and wherein the ink further comprises a phthalocyanine dye.
Claim 7
Dependent Claim 126 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein at least one of R 1 and R 2 in the pyrazolone dye of the general formula (I) is a nitro group; and wherein the ink further comprises a phthalocyanine dye.
Claim 8
Dependent Claim 127 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein at least one of R 1 and R 2 in the pyrazolone dye of the general formula (I) is a CF 3 group; and wherein the ink further comprises a phthalocyanine dye.
Claim 9
Dependent Claim 127 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein at least one of R 1 and R 2 in the pyrazolone dye of the general formula (I) is a CF 3 group; and wherein the ink further comprises a phthalocyanine dye.
Claim 10
Dependent Claim 127 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein in the pyrazolone dye of the general formula (I), R 1 is a CF 3 group and R 2 is a hydrogen atom; and wherein the ink further comprises a phthalocyanine dye.
Claim 11
Dependent Claim 127 words
An ink for ink-jet recording, comprising a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein in the pyrazolone dye of the general formula (I), R 1 is a CF 3 group and R 2 is a hydrogen atom; and wherein the ink further comprises a phthalocyanine dye.
Claim 12
Dependent Claim 122 words
The ink according to claim 3 , 4 , 5 or 6 , wherein the phthalocyanine dye has a structure of the general formula (II): wherein Pc is a phthalocyanine residue; M3 is Cu, Zn or Ni; R 5 and R 6 are each independently an SO 3 (M5) group, a substituted or unsubstituted amide group, or a substituted or unsubstituted alkyl group; R 7 and R 8 are each independently a substituted or unsubstituted alkyl group; R 9 is —CONHR 10 , —COOH or —COO(M6); R 10 is a hydrogen atom, or a substituted or unsubstituted alkyl group; n is an integer of 0, 1 or 2; M4, M5 and M6 are each independently an alkali metal or NH 4 .
Claim 13
Dependent Claim 40 words
The ink according to claim 1 , 3 , 4 , 5 or 6 , wherein the ink comprises the dyes at a total concentration ranging from 0.1 to 15% by weight based on the total weight of the ink.
Claim 14
Dependent Claim 50 words
The ink according to claim 1 , 3 , 4 , 5 or 6 , wherein the ink comprises a solvent having a boiling point ranging from 150° C. to 250° C. at a concentration ranging from 5 to 50% by weight based on the total weight of the ink.
Claim 15
Dependent Claim 23 words
The ink according to claim 1 , 3 , 4 , 5 or 6 , wherein the ink comprises further a curable resin.
Claim 16
Dependent Claim 23 words
The ink according to claim 10 , wherein the curable resin is curable by at least one of light irradiation and heat application.
Claim 17
Dependent Claim 64 words
A process for producing a color filter provided with colored pixels on a light-transmissive base plate, comprising the steps of: ejecting an ink set forth in claim 10 on a light-transmissive base plate by an ink-jet system to deposit the ink on prescribed points on the surface of the base plate, and curing the curable resin contained in the ink to form colored pixels.
Claim 18
Dependent Claim 62 words
A process for producing a color filter provided with colored pixels on a light-transmissive base plate, comprising the step of: ejecting an ink set forth in claim 1 , 3 , 4 , 5 or 6 onto the light-transmissive base plate by an ink-jet system to deposit the ink on prescribed points, thereby forming at least one of the colored pixels there.
Claim 19
Dependent Claim 26 words
The process for producing a color filter according to claim 13 , wherein the light-transmissive base plate has a curable resin layer on the surface thereof.
Claim 20
Dependent Claim 29 words
The process for producing a color filter according to claim 14 , wherein a material for forming the resin layer is a polymer comprising a water-soluble acrylic monomer unit.
Claim 21
Dependent Claim 25 words
The process for producing a color filter according to claim 14 , wherein a material for forming the resin layer comprises a cellulosic water-soluble polymer.
Claim 22
Dependent Claim 30 words
The process for producing a color filter according to claim 14 , comprising further the step of: curing the resin layer after the ink is deposited on the resin layer.
Claim 23
Dependent Claim 26 words
The process for producing a color filter according to claim 13 , wherein the light-transmissive base plate has a light-shielding layer to separate the colored pixels.
Claim 24
Dependent Claim 21 words
The process for producing a color filter according to claim 18 , wherein the surface of the light-shielding layer is noncolorable.
Claim 25
Dependent Claim 23 words
The process for producing a color filter according to claim 18 , wherein a colorable resin layer is formed between the light-shielding layers.
Claim 26
Dependent Claim 57 words
The process for producing a color filter according to claim 13 , wherein the light-transmissive base plate has a light-shielding layer which separates colored pixels formed on the surface of the base plate from each other and a resin layer formed on the light-shielding layer, the surface of the resin layer on the light-shielding layer being noncolorable.
Claim 27
Dependent Claim 37 words
The process for producing a color filter according to claim 13 , wherein the process further comprises the steps of: forming a curable resin layer so as to cover the colored pixels, and curing the curable resin.
Claim 28
Dependent Claim 29 words
The process for producing a color filter according to claim 22 , wherein the curable resin is cured by applying at least one of light energy and heat energy.
Claim 29
Dependent Claim 128 words
A color filter comprising: a light-transmissive base plate; and a colored pixel at prescribed positions on the base plate, wherein the colored pixel comprises a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are each independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; at least one of R 1 and R 2 is a CF 3 group; and both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 .
Claim 30
Dependent Claim 128 words
A color filter comprising: a light-transmissive base plate; and a colored pixel at prescribed positions on the base plate, wherein the colored pixel comprises a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are each independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; at least one of R 1 and R 2 is a CF 3 group; and both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 .
Claim 31
Dependent Claim 32 words
The color filter according to claim 24 , wherein in the pyrazolone dye of the general formula (I), R 1 is a CF 3 group and R 2 is a hydrogen atom.
Claim 32
Dependent Claim 131 words
A color filter comprising: a light-transmissive base plate; and colored pixels at prescribed positions on the base plate, wherein at least one of the colored pixels comprises a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are each independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; at least one of R 1 and R 2 is a CF 3 group; and both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 .
Claim 33
Dependent Claim 131 words
A color filter comprising: a light-transmissive base plate; and colored pixels at prescribed positions on the base plate, wherein at least one of the colored pixels comprises a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are each independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; at least one of R 1 and R 2 is a CF 3 group; and both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 .
Claim 34
Dependent Claim 31 words
The color filter according to claim 26 , wherein the pyrazolone dye of the general formula (I), R 1 is a CF 3 group and R 2 is a hydrogen atom.
Claim 35
Dependent Claim 126 words
A color filter comprising: a light-transmissive base plate; and a colored pixel at prescribed positions on the base plate, wherein the colored pixel comprises a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are each independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein the colored pixel comprising the pyrazolone dye further comprises a phthalocyanine dye.
Claim 36
Dependent Claim 126 words
A color filter comprising: a light-transmissive base plate; and a colored pixel at prescribed positions on the base plate, wherein the colored pixel comprises a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are each independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein the colored pixel comprising the pyrazolone dye further comprises a phthalocyanine dye.
Claim 37
Dependent Claim 117 words
The color filter according to claim 28 , wherein the phthalocyanine dye has a structure of the general formula (II): wherein Pc is a phthalocyanine residue; M3 is Cu, Zn or Ni; R 5 and R 6 are each independently an SO 3 (M5) group, a substituted or unsubstituted amide group, or a substituted or unsubstituted alkyl group; R 7 and R 8 are each independently a substituted or unsubstituted alkyl group; R 9 is —CONHR 10 , —COOH or —COO(M6); R 10 is a hydrogen atom or a substituted or unsubstituted alkyl group; n is an integer of 0, 1 or 2; M4, M5 and M6 are each independently an alkali metal or NH 4 .
Claim 38
Dependent Claim 129 words
A color filter comprising: a light-transmissive base plate; and colored pixels at prescribed positions on the base plate, wherein at least one of the colored pixels comprises a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are each independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein the colored pixel comprising the pyrazolone dye further comprises a phthalocyanine dye.
Claim 39
Dependent Claim 129 words
A color filter comprising: a light-transmissive base plate; and colored pixels at prescribed positions on the base plate, wherein at least one of the colored pixels comprises a pyrazolone dye of the general formula (I): wherein R 1 and R 2 are each independently selected from the group consisting of a hydrogen atom, an OH group, a halogen atom, a linear or branched alkyl group having 1 to 5 carbon atoms, a nitro group, a CF 3 group and an SO 3 (M1) group, where M1 is an alkali metal or NH 4 ; both R 3 and R 4 are an SO 3 (M2) group, where M2 is an alkali metal or NH 4 ; wherein the colored pixel comprising the pyrazolone dye further comprises a phthalocyanine dye.
Claim 40
Dependent Claim 117 words
The color filter according to claim 30 , wherein the phthalocyanine dye has a structure of the general formula (II): wherein Pc is a phthalocyanine residue; M3 is Cu, Zn or Ni; R 5 and R 6 are each independently an SO 3 (M5) group, a substituted or unsubstituted amide group, or a substituted or unsubstituted alkyl group; R 7 and R 8 are each independently a substituted or unsubstituted alkyl group; R 9 is —CONHR 10 , —COOH or —COO(M6); R 10 is a hydrogen atom or a substituted or unsubstituted alkyl group; n is an integer of 0, 1 or 2; M4, M5 and M6 are each independently an alkali metal or NH 4 .
Claim 41
Dependent Claim 42 words
The color filter according to claim 24 , 26 , 25 , 27 , 28 , 30 , 29 or 31 , wherein the base plate has a resin layer on the surface thereof, and the resin layer constitutes the colored pixels.
Claim 42
Dependent Claim 34 words
The color filter according to claim 26 , 27 , 30 , or 31 , wherein the colored pixels are separated from each other, and a light-shielding layer is provided between respective colored pixels.
Claim 43
Dependent Claim 16 words
The color filter according to claim 33 , wherein the light-shielding layer has a noncolorable surface.
Claim 44
Dependent Claim 54 words
The color filter according to claim 26 , 27 , 30 , or 31 , wherein the colored pixels are separated from each other; a light-shielding layer and a resin layer covering the light-shielding layer are provided between the colored pixels; and the surface of the resin layer on the light-shielding layer is noncolorable.
Claim 45
Dependent Claim 46 words
A liquid crystal panel comprising: a color filter set forth in claim 24 , 26 , 28 or 30 , a panel base plate placed in opposition to the color filter, and a liquid crystal compound enclosed between the color filter and the panel base plate.
Claim 46
Dependent Claim 18 words
A computer provided with the liquid crystal panel set forth in claim 36 as an image display device.

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