EP0013451A1
Expired / Lapsed
EP
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Removal of caffeine by selective adsorption using zeolite adsorbents
Assignee: Union Carbide Corp
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Filing: 1979-12-20
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Granted: —
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Expires: 1999-12-20
Abstract
Abstract Caffeine is selectively adsorbed from aqueous solutions such as coffee and tea by contact with a particular form of zeolites created by high temperature rigorous steaming of a low sodium form of zeolite Y.
Inventors
- 👤 Thomas Paul John Izod
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-08 15:14
CPC Classifications
A; A23; A23F; A23F5/00; A23F5/20; A23F5/22; A23F5/223; A23F3/00; A23F3/36; A23F3/38; A23F3/385; B; B01; B01J; B01J20/00; B01J20/02; B01J20/10; B01J20/16; B01J20/18
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
145 words
Process for removing caffeine from aqueous solutions which comprises contacting in the liquid phase at a temperature of not more than 100°C. an aqueous solution containing at least 0.01 weight percent caffeine dissolved therein with a crystalline zeolitic molecular sieve having a SiO 2 /Al 2 O 3 molar ratio of from 4.5 to 35, the essential X-ray powder diffraction pattern of zeolite Y, an ion-exchange capacity of not greater than 0.070, a unit cell dimension, a o , of from 24.20 to 24.45 Angstroms, a surface area of at least 350 m 2 /g., a sorptive capacity for water at 25°C. and a p/p o value of 0.10 of less than 5.00 weight percent, and a Residual Butanol Test value of not more than 0.40 weight percent, whereby caffeine is adsorbed on said zeolite, and thereafter isolating the said zeolite from said aqueous solution.
Claim 2
Dependent Claim
145 words
Process for removing caffeine from aqueous solutions which comprises contacting in the liquid phase at a temperature of not more than 100°C. an aqueous solution containing at least 0.01 weight percent caffeine dissolved therein with a crystalline zeolitic molecular sieve having a SiO 2 /Al 2 O 3 molar ratio of from 4.5 to 35, the essential X-ray powder diffraction pattern of zeolite Y, an ion-exchange capacity of not greater than 0.070, a unit cell dimension, a o , of from 24.20 to 24.45 Angstroms, a surface area of at least 350 m 2 /g., a sorptive capacity for water at 25°C. and a p/p o value of 0.10 of less than 5.00 weight percent, and a Residual Butanol Test value of not more than 0.40 weight percent, whereby caffeine is adsorbed on said zeolite, and thereafter isolating the said zeolite from said aqueous solution.
Claim 3
Dependent Claim
23 words
Process according to claim 1 wherein the SiO 2 /Al 2 O 3 molar ratio of the zeolite is from 4.5 to 9.0.
Claim 4
Dependent Claim
37 words
Process according to claim 1 which includes the further step of desorbing at least a portion of the caffeine from the zeolite containing same by contacting the zeolite with ethanol at a temperature of at least 20°C.
Claim 5
Dependent Claim
23 words
Process according to claim 3 wherein the ethanol is in the form of an aqueous solution containing at least 5 weight percent ethanol.
Claim 6
Dependent Claim
18 words
Process according to claim 4 wherein the aqueous solution of ethanol contains at least 10 weight percent ethanol.
Claim 7
Dependent Claim
19 words
Process according to claim 1 wherein the aqueous solution of caffeine is the aqueous extract of green coffee beans.
Claim 8
Dependent Claim
18 words
Process according to claim 1 wherein the aqueous solution of caffeine is an extract of roasted coffee beans.
References Cited (Backward Citations)
US2391981A
Cited
FR1523979A
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US3591488A
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US3929672A
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FR2303765A1
Cited
US4113887A
Cited
US4113888A
Cited
FR2418198A1
Cited
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