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EP0013451A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Removal of caffeine by selective adsorption using zeolite adsorbents

Assignee: Union Carbide Corp
•
Filing: 1979-12-20
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Granted: —
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Expires: 1999-12-20
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Abstract

Abstract Caffeine is selectively adsorbed from aqueous solutions such as coffee and tea by contact with a particular form of zeolites created by high temperature rigorous steaming of a low sodium form of zeolite Y.

Inventors

  • 👤 Thomas Paul John Izod

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-08 21:18
CPC Classifications
A; A23; A23F; A23F5/00; A23F5/20; A23F5/22; A23F5/223; A23F3/00; A23F3/36; A23F3/38; A23F3/385; B; B01; B01J; B01J20/00; B01J20/02; B01J20/10; B01J20/16; B01J20/18

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 145 words
Process for removing caffeine from aqueous solutions which comprises contacting in the liquid phase at a temperature of not more than 100°C. an aqueous solution containing at least 0.01 weight percent caffeine dissolved therein with a crystalline zeolitic molecular sieve having a SiO 2 /Al 2 O 3 molar ratio of from 4.5 to 35, the essential X-ray powder diffraction pattern of zeolite Y, an ion-exchange capacity of not greater than 0.070, a unit cell dimension, a o , of from 24.20 to 24.45 Angstroms, a surface area of at least 350 m 2 /g., a sorptive capacity for water at 25°C. and a p/p o value of 0.10 of less than 5.00 weight percent, and a Residual Butanol Test value of not more than 0.40 weight percent, whereby caffeine is adsorbed on said zeolite, and thereafter isolating the said zeolite from said aqueous solution.
Claim 2
Dependent Claim 145 words
Process for removing caffeine from aqueous solutions which comprises contacting in the liquid phase at a temperature of not more than 100°C. an aqueous solution containing at least 0.01 weight percent caffeine dissolved therein with a crystalline zeolitic molecular sieve having a SiO 2 /Al 2 O 3 molar ratio of from 4.5 to 35, the essential X-ray powder diffraction pattern of zeolite Y, an ion-exchange capacity of not greater than 0.070, a unit cell dimension, a o , of from 24.20 to 24.45 Angstroms, a surface area of at least 350 m 2 /g., a sorptive capacity for water at 25°C. and a p/p o value of 0.10 of less than 5.00 weight percent, and a Residual Butanol Test value of not more than 0.40 weight percent, whereby caffeine is adsorbed on said zeolite, and thereafter isolating the said zeolite from said aqueous solution.
Claim 3
Dependent Claim 23 words
Process according to claim 1 wherein the SiO 2 /Al 2 O 3 molar ratio of the zeolite is from 4.5 to 9.0.
Claim 4
Dependent Claim 37 words
Process according to claim 1 which includes the further step of desorbing at least a portion of the caffeine from the zeolite containing same by contacting the zeolite with ethanol at a temperature of at least 20°C.
Claim 5
Dependent Claim 23 words
Process according to claim 3 wherein the ethanol is in the form of an aqueous solution containing at least 5 weight percent ethanol.
Claim 6
Dependent Claim 18 words
Process according to claim 4 wherein the aqueous solution of ethanol contains at least 10 weight percent ethanol.
Claim 7
Dependent Claim 19 words
Process according to claim 1 wherein the aqueous solution of caffeine is the aqueous extract of green coffee beans.
Claim 8
Dependent Claim 18 words
Process according to claim 1 wherein the aqueous solution of caffeine is an extract of roasted coffee beans.

References Cited (Backward Citations)

US2391981A Cited
FR1523979A Cited
US3591488A Cited
US3929672A Cited
FR2303765A1 Cited
US4113887A Cited
US4113888A Cited
FR2418198A1 Cited

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