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EP0101267A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Anaerobically curable compositions

Assignee: Henkel Loctite Corp
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Filing: 1983-08-05
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Granted: —
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Expires: 2003-08-05
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Abstract

Abstract A self-emulsifying anaerobically curable composition is rendered self-emulsifying upon mixing with water by incorporating polymerizable monomers with surfactant properties in a concentration range of 1 % to 80% by weight of the composition. The preferred surfactant monomers are the reaction product of a surfactant, containing an active hydrogen atom, particularly from an hydroxyl or amino group, and an isocyanate acrylic monomer. The surfactant monomers can be used in any anaerobically curing monomer or monomer mixture in which they are compatible. These self-emulsifiable compositions have the advantages of being readily removable from surfaces by washing with water, without the disadvantages of loss of bond strength, solvent resistance or migration of the surfactant to the surface of the cured composition. The surfactant monomers are co-polymerizable with the anaerobically curable monomers. These self-emulsifiable compositions are especially useful in impregnation processes where uncured resin must be removed from areas which are difficult to wash, such as small, blind holes.

Inventors

  • 👤 Joann Demarco
  • 👤 Qcheng Sun Lien

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-30 04:40
CPC Classifications
C; C09; C09J; C09J4/00

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 72 words
An anaerobically curable adhesive sealant composition which is self-emulsifiable upon mixing with water and comprising at least one anaerobically curable monomer, at least one surfactant and a free radical initiator in an amount sufficient to initiate cure of the composition in the substantial absence of oxygen but insufficient to initiate cure thereof in the presence of oxygen characterised in that the surfactant is a surfactant monomer co-curable with the anaerobically curable monomer.
Claim 2
Dependent Claim 72 words
An anaerobically curable adhesive sealant composition which is self-emulsifiable upon mixing with water and comprising at least one anaerobically curable monomer, at least one surfactant and a free radical initiator in an amount sufficient to initiate cure of the composition in the substantial absence of oxygen but insufficient to initiate cure thereof in the presence of oxygen characterised in that the surfactant is a surfactant monomer co-curable with the anaerobically curable monomer.
Claim 3
Dependent Claim 17 words
A composition as claimed in Claim 1, characterised in that the surfactant monomer is itself anaerobically curable.
Claim 4
Dependent Claim 35 words
A composition as claimed in Claim 1 or 2, characterised in that the surfactant monomer comprises the reaction product of a surfactant containing an active hydrogen atom with a vinyl monomer containing an isocyanate group.
Claim 5
Dependent Claim 16 words
A composition as claimed in Claim 3, characterised in that the isocyanate-containing monomer is isocyanatoethyl methacrylate.
Claim 6
Dependent Claim 54 words
A composition as claimed in Claim 1 or 2, characterised in that the surfactant monomer has the general formula: wherein R 1 is H or lower alkyl; R 2 is C 1-6 alkylene or R 3 is H or lower alkyl; R L is a lipophilic group selected from alkyls, alkylphenols or polypropylene oxi.des.
Claim 7
Dependent Claim 23 words
A composition as claimed in claim 1 or 2, characterised in that the surfactant monomer is a methacrylate ester of a polyethoxylated nonylphenol.
Claim 8
Dependent Claim 25 words
A composition as claimed in any of claims 1 to 6, characterised in that the surfactant monomer has an HLB number from 8 to 18.
Claim 9
Dependent Claim 83 words
A composition as claimed in any of Claims 1 to 7, characterised in that the anaerobically curable monomer, has the formula: wherein R 5 represents hydrogen, lower alkyl of from 1 to 4 carbon atoms, hydroxy alkyl of from 1 to 4 carbon atoms, or R 4 is hydrogen, halogen or lower alkyl of from 1 to 4 carbon atoms; R 6 is hydrogen, hydroxyl, or m is 0 to 12; n is equal to at least 1; and-p is 0 or 1.
Claim 10
Dependent Claim 23 words
A composition as claimed in any of claims 1 to 8, characterised in that the composition additionally contains an accelerator of anaerobic polymerization.
Claim 11
Dependent Claim 19 words
A composition as claimed in claim 9, characterised in that the accelerator is a sulfimide or a hydrazine derivative.
Claim 12
Dependent Claim 59 words
A process for impregnating and sealing a porous article comprising the steps of: (a) impregnating the article with a self-emulsifying anaerobically curable composition; (b) washing the surface of the article with water; and (c) permitting the composition to cure, characterised in that the self-emulsifying anaerobically curable composition is a composition as claimed in any of claims 1 to 10.
Claim 13
Dependent Claim 37 words
A process as claimed in Claim 11 characterised in that the article surface is treated with a surface activator selected from amine-aldehyde condensation products, aromatic tertiary amines, sulfur containing free radical accelerators and organic transition metal compounds.

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