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EP0180455A2
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Process for the preparation of alkoxylated tertiary amine compounds
Assignee: Atlantic Richfield Co
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Filing: 1985-10-29
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Granted: —
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Expires: 2005-10-29
Abstract
Abstract Novel alkoxylated tertiary amine compounds of the formula are prepared by reacting an oxyalkylated alcohol with a secondary amine in the presence of a reductive amination catalyst at above ambient temperature and superatmospheric pressure. The amine compounds are useful as corrosion inhibitors, full additives, curing agents for epoxy resins and as biocides.
Inventors
- 👤 Haven S. Kesling, Jr.
- 👤 Charles F. Cooper
Bibliographic Details
Application Number
—
Jurisdiction
EP
Data Source
google_patents
Last Synchronized
2026-11-05 04:52
CPC Classifications
C; C07; C07C; C07C41/00; C07C41/01; C07C41/02; C07C41/03; B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/85; B01J23/86; B01J23/868
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
263 words
, 1. A process for the preparation of an alkoxylated tertiary amine having the formula or a mixture of such amines which comprises reacting an oxy- alkated alcohol of the formula or a mixture of such alcohols, with a secondary amine of the formula HNR 3 R 4 at a temperature in the range of from about 150°C to 325°C and a pressure of from about 50 psig to 3000 psig in the presence of from.0.5 to 20 weight percent of an amination catalyst based on the total reaction mixture and wherein R is a straight or branched chain alkyl group having from 1 to 11 carbon atoms, a cyclic alkyl group having from 5 to 10 carbon atoms, an aryl group having up to 12 carbon atoms, or an aralkyl or alkaryl group having up to 18 carbon atoms, R 1 is a single unit or a series of units of the formula: wherein in each unit R 5 is independently selected from the group consisting of hydrogen and a straight or branched chain alkyl group having from 1 to 12 carbon atoms and x is an integer of from 0 to 40, R 2 is hydrogen or a straight or branched chain alkyl group having from 1 to 12 carbon atoms, R 3 and R 4 are each independently selected from the group consisting of straight and branched chain alkyl groups having from 1 to 12 carbon atoms cyclic alkyl groups having from 5 to 10 carbon atoms, 1 to 4 carbon atom alkyl substituted or unsubstituted benzyl groups and allyl.
Claim 2
Dependent Claim
43 words
A process according to claim 1 wherein R is a straight chain alkyl group having from 8 to 10 carbon atoms, R 1 is a group with x being 7 and R 2 , R 3 and R 4 are CH 3 groups.
Claim 3
Dependent Claim
18 words
A process according to claim 2 but wherein R 1 is a group, a group or a group.
Claim 4
Dependent Claim
26 words
A process according to any one of claims 1 to 3 wherein the amination catalyst is a mixture of Cu0 and Cr 2 0 3 .
Claim 5
Dependent Claim
24 words
A process according to any one of claims 1 to 3 wherein the amination catalyst is copper and chromium supported on magnesium aluminate spinel.
Claim 6
Dependent Claim
21 words
A process according to any one of claims 1 to 3 wherein the amination catalyst is ruthenium supported on activated carbon.
Claim 7
Dependent Claim
27 words
A process according to any one of claims 1 to 6 wherein the amination catalyst is employed in an amount of from 2.5 to 10 weight percent.
Claim 8
Dependent Claim
23 words
A process according to any one of claims 1 to 7 wherein the temperature is in the range of from 175°C to 275°C.
Claim 9
Dependent Claim
21 words
A process according to any one of claims 1 to 8 wherein the pressure is from 100 psig to 250 psig.
References Cited (Backward Citations)
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