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Electrochemical cell with high capacity polyaniline electrodes

Assignee: University Patents Inc
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Filing: 1986-07-10
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Granted: —
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Expires: 2006-07-10
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Abstract

Abstract Electrochemical electrodes are provided having improved capacity and efficiency. In accordance with preferred embodiments polyaniline species wherein oxidation and hydrogenation levels are carefully controlled are formulated into such electrodes and into batteries and fuel cells.

Inventors

  • 👤 Alan G. Macdiarmid

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-01 13:01
CPC Classifications
H; H01; H01M; H01M4/00; H01M4/86; H01M4/90; H01M4/9008; C; C08; C08G; C08G73/00; C08G73/02; C08G73/026; C08G73/0266; H01M4/02; H01M4/36; H01M4/60; Y; Y02; Y02E; Y02E60/00; Y02E60/10; Y02E60/30; Y02E60/50

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 50 words
An electrochemical cell comprising anode active means, cathode active means and an aprotic electrolyte characterised in that at least one of said anode and cathode means comprises a polyanaline species wherein each nitrogen of the polymer chain is associated with at least one, but not more than two, hydrogen atoms.
Claim 2
Dependent Claim 50 words
An electrochemical cell comprising anode active means, cathode active means and an aprotic electrolyte characterised in that at least one of said anode and cathode means comprises a polyanaline species wherein each nitrogen of the polymer chain is associated with at least one, but not more than two, hydrogen atoms.
Claim 3
Dependent Claim 23 words
The cell of Claim 1 characterised in that each nitrogen of the polymer chain is associated with one, but only one, hydrogen atom.
Claim 4
Dependent Claim 17 words
The cell of claim 1 or 2 characterised in that said polyaniline species comprises the cathode means.
Claim 5
Dependent Claim 19 words
The cell of claim 3 characterised in that said anode active means comprises an alkalai or alkaline earth metal.
Claim 6
Dependent Claim 20 words
The cell of any preceding claim characterised in that said polyaniline species comprises subunits selected from lA and 25 subunits.
Claim 7
Dependent Claim 33 words
The cell of any of claims 1 to 4 characterised in that said polyaniline species is reversibly oxidizable to the formula where A- is a counterion, and is reversibly reducible to the formula
Claim 8
Dependent Claim 17 words
The cell of any preceding claim adapted to function as a secondary battery or a fuel cell.
Claim 9
Dependent Claim 24 words
An electrochemical electrode characterised by a polyaniline species wherein each nitrogen of the polymer chain is associated with one, but only one, hydrogen atom.
Claim 10
Dependent Claim 24 words
An electrochemical electrode characterised by a polyaniline species wherein each nitrogen of the polymer chain is associated with one, but only one, hydrogen atom.
Claim 11
Dependent Claim 30 words
The electrode of claim 8, characterised in that it is cyclable between oxidized and reduced forms wherein the oxidized form has the formula and the reduced form has the formula
Claim 12
Dependent Claim 16 words
The electrode of claim 8 characterised in that it is in contact with an aprotic electrolyte.
Claim 13
Independent Claim 36 words
A method of reversible energy storage characterised by providing an electrode in an aprotic electrolyte and cyclically oxidizing and reducing said electrode between oxidized formula and reduced formula where A- is a counterion from the electrolyte.
Claim 14
Independent Claim 36 words
A method of reversible energy storage characterised by providing an electrode in an aprotic electrolyte and cyclically oxidizing and reducing said electrode between oxidized formula and reduced formula where A- is a counterion from the electrolyte.

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