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EP0219273A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Transparent article having high visible transmittance

Assignee: Messer LLC
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Filing: 1986-10-01
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Granted: —
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Expires: 2006-10-01
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Abstract

Abstract A transparent article comprising a base, at least four coated layers, and a top protective layer is disclosed. The coated layers include a first dereflecting region, a transparent layer of silver or other metal, and a second dereflecting region comprising a layer of titanium dioxide and a layer of another dielectric material. A titanium dioxide layer may also be a component of the first dereflecting region. Each dereflecting region that includes a titanium dioxide layer also comprises a layer of a transparent oxide or other dielectric material having an index of refraction intermediate between about 2.7, the approximate index of titanium dioxide, and the index of the nearby base ortop layer, respectively. The intermediate index material is preferably zinc oxide because this material can be relatively quickly and inexpensively deposited by reactive sputtering. Also disclosed is a method for depositing the coated layers by sputtering and reactive sputtering of titanium and silver, zinc or other materials. The coating is useful as a component of a laminated window, particularly on electrically heated windshields for automobiles.

Inventors

  • 👤 Roy Lee Bernardi
  • 👤 Donald V. Jacobsen
  • 👤 Francis Walter Ryan

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-29 17:10
CPC Classifications
C; C03; C03C; C03C17/00; C03C17/34; C03C17/36; C03C17/3602; C03C17/3618; B; B32; B32B; B32B7/00; B32B7/02; C03C17/3642; C03C17/3652; C03C17/3657; C03C17/366; C03C17/3668; C03C17/3673; C03C17/3681; G; G02; G02B; G02B5/00; G02B5/20; G02B5/28; C03C2217/00; C03C2217/70; C03C2217/73; C03C2217/734

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 43 words
A transparent article, comprising in order: a transparent base; a first transparent dereflecting layer; a transparent metallic layer; a titanium dioxide layer; a second dereflecting layer having an index of refraction intermediate between a top layer and 2.7; and a top protective layer.
Claim 2
Dependent Claim 43 words
A transparent article, comprising in order: a transparent base; a first transparent dereflecting layer; a transparent metallic layer; a titanium dioxide layer; a second dereflecting layer having an index of refraction intermediate between a top layer and 2.7; and a top protective layer.
Claim 3
Dependent Claim 23 words
A transparent article according to claim 1, wherein the metallic layer is selected from the group consisting of silver, copper, aluminum and gold.
Claim 4
Dependent Claim 48 words
A transparent article according to claim 1 or claim 2, wherein the material of the first dereflecting layer and the material of the second dereflecting layer are each selected from the group consisting of zinc oxide, bismuth oxide, indium oxide, silicon monoxide, tin oxide, and mixed indium-tin oxide.
Claim 5
Dependent Claim 28 words
A transparent article according to any one of the preceding claims, wherein the metallic layer is silver having a thickness in the range of 15 to 20 nm.
Claim 6
Dependent Claim 40 words
A transparent article according to any one of the preceding claims, further including a sacrificial metal oxide layer adjacent the metallic layer and the sacrificial metal is selected from the group consisting of titanium, aluminum, zinc, bismuth, indium and tin.
Claim 7
Dependent Claim 31 words
A transparent article according to any one of the preceding claims, wherein the two dereflecting layers are of zince oxide, each having a thickness in the range 30 to 60 nm.
Claim 8
Dependent Claim 42 words
A transparent article according to any one of the preceding claims, wherein the base comprises a layer of glass, and the top comprises a layer of glass and a layer of plastic between the second dereflecting layer and the top glass layer.
Claim 9
Dependent Claim 23 words
A transparent article according to any one of the preceding claims, wherein the resistivity of the coated layers is less than 5 ohms/square.
Claim 10
Dependent Claim 30 words
A transparent article according to any one of the preceding claims, wherein the article has a transmittance for visible radiation is at least 72% and a emissivity less than 0.1.
Claim 11
Dependent Claim 25 words
A transparent article according to any one of the preceding claims, wherein the base includes an electrode for making electrical contact with the coated layers.
Claim 12
Dependent Claim 83 words
A process for making a transparent article according to any one of the preceding claims, comprising: depositing a first dereflecting layer on a transparent base by reactive sputtering of a metal; depositing a transparent metal layer by sputtering a metal selected from the group consisting of silver, copper, aluminum and gold; depositing a layer of titanium dioxide adjacent the metal layer by sputtering; depositing a second dereflecting layer by reactive sputtering of a metal; covering the sputtered layers with a top protective layer.
Claim 13
Dependent Claim 23 words
A process according to Claim 11, wherein the reactively sputtered metals are selected from the group consisting of zinc, bismuth, indium and tin.
Claim 14
Dependent Claim 47 words
A process according to claim 11 or claim 12 wherein the metal layer is silver, and further including the step of depositing on the silver layer a sacrificial metal layer by sputtering a metal selected from the group consisting of titanium, aluminum, zinc, bismuth, indium, and tin.
Claim 15
Dependent Claim 61 words
A process according to any one of claims 11 to 13, wherein: the first dereflecting layer is deposited on a first pass through a sputter coating system; the silver and the sacrificial metal layers are deposited on a second pass through a sputter coating system; and the second dereflecting layer is deposited on a third pass through the sputter coating system.

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