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EP0249941A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Method for producing fine patterns

Assignee: Tosoh Corp
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Filing: 1987-06-16
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Granted: —
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Expires: 2007-06-16
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Abstract

Abstract A method for producing fine patterns is disclosed, comprising spin-coating a photosensitive resin solution as an upper layer, which comprises a diazonium salt as a photobleachable agent, water and/or an organic solvent, and a polymer, on a photoresist layer as a lower layer and then light-exposing both the upper layer and the lower layer, wherein the polymer in the upper layer has a structural unit shown by formula (I): wherein R₁, R₂, and R₃ each represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, or a nitrile group; R₄ represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, a hydroxyl group, or a carboxyl group; and X represents a hydrogen atom, an alkali metal, an alkaline earth metal, or an ammonium group. According to another embodiment of this invention, a method for producing fine patterns is disclosed, comprising spin-coating a photosensitive resin solution as an upper layer, which comprises a diazonium salt as a photobleachable agent, water and/or an organic solvent, and a polymer, on a photoresist layer as a lower layer, wherein a counter anion of the diazonium salt is a functional group of the polymer in the photosensitive resin. According to this invention, a light of low contrast can be increased to one of high contrast without requiring complicated steps, and patterns of less than 1 µm can be produced with good precision.

Inventors

  • 👤 Masazumi Hasegawa
  • 👤 Masaaki Todoko
  • 👤 Mitsutoshi Fukuda

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-29 03:39
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/016; G03F7/021; G03F7/09; G03F7/091; G03F7/095

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 140 words
A method for producing fine patterns by spin-coating a photosensitive resin solution as an upper layer, which comprises a diazonium salt as a photobleachable agent, at least one of water and an organic solvent, and a polymer, on a resist layer as a lower layer and then light-exposing both the upper layer and the lower layer, wherein the polymer in the upper layer has a structural unit represented by formula (I): wherein R₁, R₂, and R₃ each represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, or a nitrile group; R₄ represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, a hydroxyl group, or a carboxyl group; and X represents a hydrogen atom, an alkali metal, an alkaline earth metal, or an ammonium group.
Claim 2
Independent Claim 140 words
A method for producing fine patterns by spin-coating a photosensitive resin solution as an upper layer, which comprises a diazonium salt as a photobleachable agent, at least one of water and an organic solvent, and a polymer, on a resist layer as a lower layer and then light-exposing both the upper layer and the lower layer, wherein the polymer in the upper layer has a structural unit represented by formula (I): wherein R₁, R₂, and R₃ each represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, or a nitrile group; R₄ represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, a hydroxyl group, or a carboxyl group; and X represents a hydrogen atom, an alkali metal, an alkaline earth metal, or an ammonium group.
Claim 3
Dependent Claim 29 words
A method for producing fine patterns as claimed in claim 1, wherein the polymer in the upper layer is a copolymer containing the structural unit shown by formula (I).
Claim 4
Dependent Claim 37 words
A method for producing fine patterns as claimed in claim 2, wherein the proportion of a comonomer having the structural unit shown by formula (I) in the polymer in the upper layer is at least 50 mol%.
Claim 5
Independent Claim 75 words
A method for producing fine patterns by spin-coating a photosensitive resin solution as an upper layer, which comprises a diazonium salt as a photobleachable agent, at least one of water and an organic solvent, and a polymer, on a resist layer as a lower layer and then light-exposing both the upper layer and the lower layer, wherein a counter anion of the diazonium salt is a functional group of the polymer in the photosensitive resin.
Claim 6
Independent Claim 75 words
A method for producing fine patterns by spin-coating a photosensitive resin solution as an upper layer, which comprises a diazonium salt as a photobleachable agent, at least one of water and an organic solvent, and a polymer, on a resist layer as a lower layer and then light-exposing both the upper layer and the lower layer, wherein a counter anion of the diazonium salt is a functional group of the polymer in the photosensitive resin.
Claim 7
Dependent Claim 26 words
A method for producing fine patterns as claimed in claim 4, wherein the functional group of the polymer in the photosensitive resin is a sulfonic group.
Claim 8
Dependent Claim 96 words
A method for producing fine patterns as claimed in claim 4, wherein the polymer in the photosensitive resin has a structural unit represented by formula (I): wherein R₁, R₂, and R₃ each represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, or a nitrile group; R₄ represents a h ydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, a hydroxyl group, or a carboxyl group; and X represents a hydrogen atom, an alkali metal, an alkaline earth metal, or an ammonium group.
Claim 9
Dependent Claim 29 words
A method for producing fine patterns as claimed in claim 6, wherein the polymer in the photosensitive resin is a copolymer containing the structural unit shown by formula (I).
Claim 10
Dependent Claim 37 words
A method for producing fine patterns as claimed in claim 7, wherein the proportion of a comonomer having the structural unit shown by formula (I) in the polymer in the photosensitive resin is at least 50 mol%.
Claim 11
Dependent Claim 53 words
A method for producing fine patterns as claimed in claim 4, wherein in the polymer of the photosensitive resin, the proportion of the free functional group in the polymer is at least 30% of both the functional group which can be a counter anion of the diazonium salt and the free functional group.

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