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EP0308255A2 Expired / Lapsed EP ⏱️ 0.0 years remaining

Process for making a thermoplastic resin composition

Assignee: Sumitomo Chemical Co Ltd
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Filing: 1988-09-16
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Granted: —
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Expires: 2008-09-16
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Abstract

Abstract A process for making a thermoplastic resin composition which comprises melting and mixing 100 parts by weight of polyphenylene ether (A) and 0.01 - 5.0 parts by weight of at least one compound (B) which contains in its molecule both (a) carbon-carbon double bond or carbon-carbon triple bond and (b) carboxyl group, acid anhydride group, acid amide group, imide group, carboxylic acid ester group, epoxy group, amino group or hydroxyl group in the presence of 0.01 % or more and less than 0.1 % by weight of radical initiator based on the polyphenylene ether (A), said polyphenylene ether (A) being obtained by oxidation-polymerization of at least one phenol com­pound represented by the formula: wherein R₁, R₂, R₃, R₄ and R₅ represent a hydrogen atom, a halogen atom, a hydrocarbon or a substituted hydro­carbon group, with a proviso that at least one of them is a hydrogen atom, and said polyphenylene ether (A) having a reduced viscosity η sp/c of 0.40 - 0.58 deciliter/gram.

Inventors

  • 👤 Hiroomi Abe
  • 👤 Taichi Nishio
  • 👤 Yasurou Suzuki
  • 👤 Takashi Sanada

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-31 18:09
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/34; C08G65/48; C08G65/485; C08F; C08F283/00; C08F283/06; C08F283/08; C08L; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/126; C08L77/00; Y; Y10; Y10S; Y10S525/00; Y10S525/905

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 157 words
A process for making a polyphenylene ether composition which comprises melt-blending 100 parts by weight of a mixture comprising a polyphenylene ether (A) obtained by oxidation-polymerization of at least one phenol of the formula: wherein R₁, R₂, R₃, R₄ and R₅, which may be the same or different, each represent hydrogen, halogen or an optionally substituted hydrocarbon group with the proviso that at least one is hydrogen, and having a reduced viscosity η sp/c of 0.40 - 0.58 deciliter/gram and 0.01 - 5.0 parts by weight of at least one compound (B) which contains in its molecule both (a) at least one carbon-carbon double bond or carbon-carbon triple bond and (b) at least one carboxyl group, acid anhydride group, acid amide group, imide group, carboxylic acid ester group, epoxy group, amino group or hydroxyl group, in the presence of from 0.01% to less than 0.1% by weight of a radical initiator based on the polyphenylene ether (A).
Claim 2
Dependent Claim 157 words
A process for making a polyphenylene ether composition which comprises melt-blending 100 parts by weight of a mixture comprising a polyphenylene ether (A) obtained by oxidation-polymerization of at least one phenol of the formula: wherein R₁, R₂, R₃, R₄ and R₅, which may be the same or different, each represent hydrogen, halogen or an optionally substituted hydrocarbon group with the proviso that at least one is hydrogen, and having a reduced viscosity η sp/c of 0.40 - 0.58 deciliter/gram and 0.01 - 5.0 parts by weight of at least one compound (B) which contains in its molecule both (a) at least one carbon-carbon double bond or carbon-carbon triple bond and (b) at least one carboxyl group, acid anhydride group, acid amide group, imide group, carboxylic acid ester group, epoxy group, amino group or hydroxyl group, in the presence of from 0.01% to less than 0.1% by weight of a radical initiator based on the polyphenylene ether (A).
Claim 3
Dependent Claim 28 words
A process according to claim 1 wherein there is melt-blended a mixture which also contains 1 to 40 parts by weight of at least one rubber-like material (C).
Claim 4
Dependent Claim 31 words
A process according to claim 2 wherein said rubber-like material is at least one of saturated olefin rubber, styrene-grafted copolymer rubber, styrenic block copolymer rubber and hydrogenated styrenic block copolymer rubber.
Claim 5
Dependent Claim 32 words
A process according to claim 3 wherein the saturated olefin rubber is ethylene-propylene copolymer rubber or ethylene-propylene-non-conjugated diene terpolymer rubber with which 0.1 - 2.0% by weight of maleic anhydride is graft-polymerized.
Claim 6
Dependent Claim 53 words
A process for making a thermoplastic resin composition which comprises melt blending at a temperature of 240 to 350°C a mixture of 5 to 95 parts by weight of a polyamide and 95 to 5 parts by weight of a polyphenylene ether composition prepared in accordance with any one of the preceding claims.
Claim 7
Dependent Claim 21 words
A process according to claim 5 which comprises the additional step of shaping the thermoplastic composition to form a shaped article.

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