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Metathesis polymerized terpolymers

Assignee: Hercules LLC
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Filing: 1988-12-21
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Granted: —
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Expires: 2008-12-21
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Abstract

Abstract This invention teaches the preparation of crosslinked terpolymers of dicyclopentadiene, tricyclopentadiene and tetracyclododecene or alkyl/alkylene derivatives of tetra­cyclododecene, which have significantly higher glass transi­tion temperatures than that of dicyclopentadiene homopoly­mers, and which concomitantly exhibit significantly improved values of impact resistance over that known for copolymers of dicyclopentadiene.

Inventors

  • 👤 Douglas Robert Leach

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-10-29 23:53
CPC Classifications
C; C08; C08F; C08F279/00; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 85 words
A metathesis catalyst ring-opening copolymerizable composition comprising from about 20% to about 80% by weight, based on total terpolymer weight, or repeating units derived from dicyclopentadiene, from about 10% to about 50% by weight of repeating units derived from tricyclopentadiene, and from about 10% to about 50% by weight of repeating units derived from tetracyclododecene or derivatives of tetracyclododecene, having the general formula: wherein R₁-R₂ denote the same or different hydrogen atoms or lower alkyl and alkylene groups having from 1 to 10 carbon atoms.
Claim 2
Dependent Claim 85 words
A metathesis catalyst ring-opening copolymerizable composition comprising from about 20% to about 80% by weight, based on total terpolymer weight, or repeating units derived from dicyclopentadiene, from about 10% to about 50% by weight of repeating units derived from tricyclopentadiene, and from about 10% to about 50% by weight of repeating units derived from tetracyclododecene or derivatives of tetracyclododecene, having the general formula: wherein R₁-R₂ denote the same or different hydrogen atoms or lower alkyl and alkylene groups having from 1 to 10 carbon atoms.
Claim 3
Dependent Claim 82 words
A crosslinked terpolymer comprising from about 20% to about 80% by weight, based on total terpolymer weight, of repeating units derived from dicyclopentadiene, from about 10% to about 50% by weight of repeating units derived from tricyclopentadiene, and from about 10% to about 50% by weight of repeating units derived from tetracyclododecene or deriva­tives of tetracyclododecene, having the general formula: wherein R₁-R₂ denote the same or different hydrogen atoms or lower alkyl and alkylene groups having from 1 to 10 carbon atoms.
Claim 4
Dependent Claim 82 words
A crosslinked terpolymer comprising from about 20% to about 80% by weight, based on total terpolymer weight, of repeating units derived from dicyclopentadiene, from about 10% to about 50% by weight of repeating units derived from tricyclopentadiene, and from about 10% to about 50% by weight of repeating units derived from tetracyclododecene or deriva­tives of tetracyclododecene, having the general formula: wherein R₁-R₂ denote the same or different hydrogen atoms or lower alkyl and alkylene groups having from 1 to 10 carbon atoms.
Claim 5
Dependent Claim 57 words
A crosslinked terpolymer as claimed in claim 2 which comprises from about 20% to about 80% by weight of repeating units derived from dicyclopentadiene, from about 10% to about 40% by weight of repeating units derived from tricyclopentadiene, and from about 10% to about 40% by weight of repeating units derived from tetracyclododecene or deriva­tives of tetracyclododecene.
Claim 6
Dependent Claim 32 words
A crosslinked terpolymer as claimed in claim 2 which also comprises a hydrocarbon elastomer in an amount of from about 3% to about 10% by weight, based on the total terpolymer weight.
Claim 7
Dependent Claim 32 words
A crosslinked terpolymer as claimed in claim 3 which also comprises a hydrocarbon elastomer in an amount of from about 3% to about 10% by weight, based on the total terpolymer weight.
Claim 8
Dependent Claim 94 words
A process for producing a crosslinked terpolymer comprising reacting in the presence of a metathesis catalyst from about 20% to about 80% by weight, based on total ter­polymer weight, or repeating units derived from dicyclopenta­diene, from about 10% to about 50% by weight of repeating units derived from tricyclopentadiene, and from about 10% to about 50% by weight of repeating units derived from tetra­cyclododecene or derivatives of tetracyclododecene, having the general formula: wherein R₁-R₂ denote the same or different hydrogen atoms or lower alkyl and alkylene groups having from 1 to 10 carbon atoms.
Claim 9
Dependent Claim 94 words
A process for producing a crosslinked terpolymer comprising reacting in the presence of a metathesis catalyst from about 20% to about 80% by weight, based on total ter­polymer weight, or repeating units derived from dicyclopenta­diene, from about 10% to about 50% by weight of repeating units derived from tricyclopentadiene, and from about 10% to about 50% by weight of repeating units derived from tetra­cyclododecene or derivatives of tetracyclododecene, having the general formula: wherein R₁-R₂ denote the same or different hydrogen atoms or lower alkyl and alkylene groups having from 1 to 10 carbon atoms.

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