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US3901705A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of using variable depth photopolymerization imaging systems

Assignee: EIDP Inc
•
Filing: 1973-09-06
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Granted: 1975-08-26
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Expires: 1993-09-06
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Abstract

Abstract Variable depth, positive, contour images are produced on substrates by coating the substrate with a photopolymerizable coating composition containing (1) a non-gaseous, ethylenically unsaturated compound capable of polymerization by free-radical initiated chain propagation, (2) an organic light-sensitive freeradical generating system, and (3) a photodissociable nitroso dimer having a dissociation constant of about 10 2 to 10 10 and a dissociation half-life of at least about 30 seconds in solution at 25*C. These images are produced by exposing the photopolymerizable coating to light having wavelengths both above and below 3400A through a transparent film of variable optical density to light having a wavelength of less than about 3400A, and developing a positive polymeric image by removing the nonpolymerized portion of the polymer coating.

Inventors

  • 👤 Jose Francisco Pazos

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 05:21
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/031; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/118

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 164 words
METHOD OF MAKING A VARIABLE DEPTH POSITIVE, CONTOUR, IMAGE ON A SUBSTRATE WHICH COMPRISES COATING THE SUBSTRATE WITH A PHOTOPOLYMERIZABLE COATING COMPOSITION CONTAINING (1) A NON-GASEOUS ETHYLENICALLY UNSATURATED COMPOUND CAPABLE OF ADDITION POLYMERIZATION BY FREE-RADICAL INITIATED CHAIN PROPAGATION, (2) 0.001 TI 1.0 PART BY WEIGHT PER PART OF POLYMERIZABLE COMPOUND OF AN ORGANIC LIGHT-SENSITIVE FREE-RADICAL GENERATING SYSTEM, AND (3) 0.1 TO 10 PERCENT BY WEIGHT BASED ON THE COATING COMPOSITION OF A PHOTODISSOCIABLE NITROSO DIMER HAVING A DISSOCIATION CONSTANT OF 10**-2 TO 10**10 AND A DISSOCIATION HALF-LIFE OF AT LEAST 30 SECONDS IN SOLUTION AT 25*C EXPOSING THE PHOTO-POLYNERIZABLE COATING TO LIGHT HAVING WAVELENGTHS BOTH ABOVE 3400A WHICH EFFECT POLYMERIZATION AND BELOW 3400A WHICH DIISOCIATE NITROSO DIMER TO NITROSO MONOMER, THROUGH A TRANSPARENT FILM OF VARIABLE OPTICAL DENSITY TO LIGHT HAVING A WAVELENGTH OF LESS THAN 3400A AND TRANSPARENT TO LIGHT HAVING A WAVELENGTH ABOVE 3400A, AND DEVELOPING A VARIABLE DEPTH, POSITIVE, POLYMERIC, CONTOUR IMAGE BY REMOVING THE NONPOLYMERIZED PORTION OF THE POLYMER COATING
Claim 2
Dependent Claim 164 words
METHOD OF MAKING A VARIABLE DEPTH POSITIVE, CONTOUR, IMAGE ON A SUBSTRATE WHICH COMPRISES COATING THE SUBSTRATE WITH A PHOTOPOLYMERIZABLE COATING COMPOSITION CONTAINING (1) A NON-GASEOUS ETHYLENICALLY UNSATURATED COMPOUND CAPABLE OF ADDITION POLYMERIZATION BY FREE-RADICAL INITIATED CHAIN PROPAGATION, (2) 0.001 TI 1.0 PART BY WEIGHT PER PART OF POLYMERIZABLE COMPOUND OF AN ORGANIC LIGHT-SENSITIVE FREE-RADICAL GENERATING SYSTEM, AND (3) 0.1 TO 10 PERCENT BY WEIGHT BASED ON THE COATING COMPOSITION OF A PHOTODISSOCIABLE NITROSO DIMER HAVING A DISSOCIATION CONSTANT OF 10**-2 TO 10**10 AND A DISSOCIATION HALF-LIFE OF AT LEAST 30 SECONDS IN SOLUTION AT 25*C EXPOSING THE PHOTO-POLYNERIZABLE COATING TO LIGHT HAVING WAVELENGTHS BOTH ABOVE 3400A WHICH EFFECT POLYMERIZATION AND BELOW 3400A WHICH DIISOCIATE NITROSO DIMER TO NITROSO MONOMER, THROUGH A TRANSPARENT FILM OF VARIABLE OPTICAL DENSITY TO LIGHT HAVING A WAVELENGTH OF LESS THAN 3400A AND TRANSPARENT TO LIGHT HAVING A WAVELENGTH ABOVE 3400A, AND DEVELOPING A VARIABLE DEPTH, POSITIVE, POLYMERIC, CONTOUR IMAGE BY REMOVING THE NONPOLYMERIZED PORTION OF THE POLYMER COATING
Claim 3
Dependent Claim 22 words
The method of claim 1 in which the polymerizable compound is an unsaturated ester of a polyol and an Alpha -methylenecarboxylic acid.
Claim 4
Dependent Claim 14 words
The method of claim 2 in which the polymerizable compound is an acrylic ester.
Claim 5
Dependent Claim 31 words
The method of claim 3 in which the coating composition contains 0.01 to 0.7 part by weight per part of polymerizable compound of a benzoin ether as the free-radical generating system.
Claim 6
Dependent Claim 15 words
The method of claim 4 in which the free-radical generating system is benzoin methyl ether.
Claim 7
Dependent Claim 25 words
The method of claim 4 in which the coating composition contains 0.2 to 2 percent by weight based on the coating composition of 2,4-dimethyl-2-nitroso-3-pentanone dimer.
Claim 8
Dependent Claim 25 words
The method of claim 4 in which the coating composition contains 0.2 to 2 percent by weight based on the coating composition of nitrosocyclohexane dimer.
Claim 9
Dependent Claim 25 words
The method of claim 4 in which the coating composition contains 0.2 to 2 percent by weight based on the coating composition of 1-nitroso-3-methylcyclohexane dimer.
Claim 10
Dependent Claim 25 words
The method of claim 4 in which the coating composition contains 0.2 to 2 percent by weight based on the coating composition of 2-nitroso-3-methylbutane dimer.

References Cited (Backward Citations)

US2760863A Cited
US2927022A Cited
US3060022A Cited
US3060023A Cited
US3060026A Cited
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US3661588A Cited
US3740224A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-08-25 1979-02-24 1979-08-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-08-25 1983-02-24 1983-08-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-08-25 1987-02-24 1987-08-26 $7700.00 Window Closed / Lapsed

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