US3907741A — Nonaqueous dispersions of thermosetting film form…

Claim 1

Independent Claim 15 words

A PROCESS FOR PREPARING A NONAQUEOUS DISPERSION OF A THERMOSETTING FILM-FORMING POLYMER COMPRISING IN COMBINATION

Claim 2

Dependent Claim 15 words

A PROCESS FOR PREPARING A NONAQUEOUS DISPERSION OF A THERMOSETTING FILM-FORMING POLYMER COMPRISING IN COMBINATION

Claim 3

Dependent Claim 39 words

DISSOLVING AN ALKYLATED CONDENSATION PRODUCT OF AN AMINE AND AN ALDEHYDE HAVING A MINERAL SPIRITS TOLERANCE AT 60 PERCENT SOLIDS IN BUTANOL OF AT LEAST ABOUT 400 IN AN ALIPHATIC HYDROCARBON SOLVENT WHICH DISTILLS AT TEMPERATURES ABOVE ABOUT 85*C.

Claim 4

Dependent Claim 39 words

DISSOLVING AN ALKYLATED CONDENSATION PRODUCT OF AN AMINE AND AN ALDEHYDE HAVING A MINERAL SPIRITS TOLERANCE AT 60 PERCENT SOLIDS IN BUTANOL OF AT LEAST ABOUT 400 IN AN ALIPHATIC HYDROCARBON SOLVENT WHICH DISTILLS AT TEMPERATURES ABOVE ABOUT 85*C.

Claim 5

Dependent Claim 67 words

ADDING TO SAID SOLUTION A FIRST ACTIVE ETHENIC MONOMER HAVING A FUNCTIONAL EPOXY GROUP AND A SECOND ACTIVE ETHENIC MONOMER IN RELATIVE QUANTITIES SUCH THAT THE EPOXY FUNCTIONAL ACTIVE ETHENIC MONOMERS CONSTITUTE BETWEEN ABOUT 5 AND ABOUT 40 WEIGHT PERCENT OF THE TOTAL OF ETHENIC MONOMERS ADDED, SAID ACTIVE ETHENIC MONOMERS BEING READILY POLYMERIZABLE BY FREE RADICAL INITIATED POLYMERIZATION AND BEING FREE OF FUNCTIONAL HYDROXY GROUPS, AND

Claim 6

Dependent Claim 67 words

ADDING TO SAID SOLUTION A FIRST ACTIVE ETHENIC MONOMER HAVING A FUNCTIONAL EPOXY GROUP AND A SECOND ACTIVE ETHENIC MONOMER IN RELATIVE QUANTITIES SUCH THAT THE EPOXY FUNCTIONAL ACTIVE ETHENIC MONOMERS CONSTITUTE BETWEEN ABOUT 5 AND ABOUT 40 WEIGHT PERCENT OF THE TOTAL OF ETHENIC MONOMERS ADDED, SAID ACTIVE ETHENIC MONOMERS BEING READILY POLYMERIZABLE BY FREE RADICAL INITIATED POLYMERIZATION AND BEING FREE OF FUNCTIONAL HYDROXY GROUPS, AND

Claim 7

Dependent Claim 67 words

adding to said solution a first active ethenic moNomer having a functional epoxy group and a second active ethenic monomer in relative quantities such that the epoxy functional active ethenic monomers constitute between about 5 and about 40 weight percent of the total of ethenic monomers added, said active ethenic monomers being readily polymerizable by free radical initiated polymerization and being free of functional hydroxy groups, and

Claim 8

Dependent Claim 67 words

adding to said solution a first active ethenic moNomer having a functional epoxy group and a second active ethenic monomer in relative quantities such that the epoxy functional active ethenic monomers constitute between about 5 and about 40 weight percent of the total of ethenic monomers added, said active ethenic monomers being readily polymerizable by free radical initiated polymerization and being free of functional hydroxy groups, and

Claim 9

Dependent Claim 43 words

The process of claim 1 in which said aliphatic hydrocarbon solvent is an aliphatic hydrocarbon distillation product having a distillation range of about 100*-150*C. and in which the copolymerizing step is carried out at the refluxing temperature of the solution and resultant dispersion.

Claim 10

Dependent Claim 113 words

heating the resultant solution of alkylated condensation product to its reflux temperature above 80*C., maintaining said solution at reflux temperature and under agitation; and incrementally adding to said solution a first active ethenic monomer having a functional epoxy group and a second active ethenic monomer in relative quantities such that the epoxy functional active ethenic monomers constitute between about 5 and about 40 weight percent of the total of ethenic monomers added, said active ethenic monomers having less than about 12 carbon atoms per molecule, being polymerizable by free radical initiated polymerization, being free of functional hydroxy groups, and including less than 3 weight percent of ethenic monomers having functional carboxy groups, and

Claim 11

Dependent Claim 113 words

heating the resultant solution of alkylated condensation product to its reflux temperature above 80*C., maintaining said solution at reflux temperature and under agitation; and incrementally adding to said solution a first active ethenic monomer having a functional epoxy group and a second active ethenic monomer in relative quantities such that the epoxy functional active ethenic monomers constitute between about 5 and about 40 weight percent of the total of ethenic monomers added, said active ethenic monomers having less than about 12 carbon atoms per molecule, being polymerizable by free radical initiated polymerization, being free of functional hydroxy groups, and including less than 3 weight percent of ethenic monomers having functional carboxy groups, and

Claim 12

Dependent Claim 29 words

The process of claim 1 in which the alkylated condensation product is prepared by a condensation reaction of an amine and an aldehyde in the presence of an alkanol.

Claim 13

Dependent Claim 92 words

copolymerizing said active ethenic monomers in the presence of said alkylated condensation product and a free radical initiator while maintaining the solution of said alkylated condensation product containing said active ethenic monomers under agitation and at its reflux temperature above 80*C. until said active ethenic monomers form a polymeric material that is insoluble in said aliphatic hydrocarbon solvent and dispersed uniformly through said aliphatic hydrocarbon solvent in a quantity such that said alkylated condensation product constitutes about 10 to about 50 weight percent oF the total polymeric solids within the resultant dispersion.

Claim 14

Dependent Claim 92 words

copolymerizing said active ethenic monomers in the presence of said alkylated condensation product and a free radical initiator while maintaining the solution of said alkylated condensation product containing said active ethenic monomers under agitation and at its reflux temperature above 80*C. until said active ethenic monomers form a polymeric material that is insoluble in said aliphatic hydrocarbon solvent and dispersed uniformly through said aliphatic hydrocarbon solvent in a quantity such that said alkylated condensation product constitutes about 10 to about 50 weight percent oF the total polymeric solids within the resultant dispersion.

Claim 15

Dependent Claim 79 words

copolymerizing said active ethenic monomers in the presence of said alkylated condensation product and a free radical initiator while maintaining said solution at a temperature above about 80*C. and under agitation until said active ethenic monomers form a polymeric material that is insoluble in said solvent and dispersed through said aliphatic hydrocarbon solvent in a quantity such that said alkylated condensation product constitutes about 10 to about 50 weight percent of the total polymeric solids within the resultant dispersion.

Claim 16

Dependent Claim 79 words

copolymerizing said active ethenic monomers in the presence of said alkylated condensation product and a free radical initiator while maintaining said solution at a temperature above about 80*C. and under agitation until said active ethenic monomers form a polymeric material that is insoluble in said solvent and dispersed through said aliphatic hydrocarbon solvent in a quantity such that said alkylated condensation product constitutes about 10 to about 50 weight percent of the total polymeric solids within the resultant dispersion.

Claim 17

Dependent Claim 79 words

COPOLYMERIZING SAID ACTIVE ETHENIC MONOMERS IN THE PRESENCE OF SAID ALKYLATED CONDENSATION PRODUCT AND A FREE RADICAL INITIATOR WHILE MAINTAINING SAID SOLUTION AT A TEMPERATURE ABOVE ABOUT 80*C. AND UNDER AGITATION UNTIL SAID ACTIVE ETHENIC MONOMERS FORM A POLYMERIC MATERIAL THAT IS INSOLUBLE IN SAID SOLVENT AND DISPERSED THROUGH SAID ALIPHATIC HYDROCARBON SOLVENT IN A QUANTITY SUCH THAT SAID ALKYLATED CONDENSATION PRODUCT CONSTITUTES ABOUT 10 TO ABOUT 50 WEIGHT PERCENT OF THE TOTAL POLYMERIC SOLIDS WITHIN THE RESULTANT DISPERSION.

Claim 18

Dependent Claim 79 words

COPOLYMERIZING SAID ACTIVE ETHENIC MONOMERS IN THE PRESENCE OF SAID ALKYLATED CONDENSATION PRODUCT AND A FREE RADICAL INITIATOR WHILE MAINTAINING SAID SOLUTION AT A TEMPERATURE ABOVE ABOUT 80*C. AND UNDER AGITATION UNTIL SAID ACTIVE ETHENIC MONOMERS FORM A POLYMERIC MATERIAL THAT IS INSOLUBLE IN SAID SOLVENT AND DISPERSED THROUGH SAID ALIPHATIC HYDROCARBON SOLVENT IN A QUANTITY SUCH THAT SAID ALKYLATED CONDENSATION PRODUCT CONSTITUTES ABOUT 10 TO ABOUT 50 WEIGHT PERCENT OF THE TOTAL POLYMERIC SOLIDS WITHIN THE RESULTANT DISPERSION.

Claim 19

Dependent Claim 56 words

The process of claim 1 in which said active ethenic monomers are dissolved in a nonaqueous solvent and the resultant solution is incrementally added to said solution of said alkylated condensation product while said solution of said alkylated condensation product is maintained under agitation and at its refluxing temperature, said refluxing temperature being at least 80*C.

Claim 20

Dependent Claim 18 words

The process of claim 1 in which said active ethenic monomers have less than about 12 carbon atoms.

Claim 21

Dependent Claim 18 words

The process of claim 1 in which said second active ethenic monomer is an acrylate, methacrylate or acrylonitrile.

Claim 22

Dependent Claim 20 words

The process of claim 1 in which said second active ethenic monomer is an epoxy acrylate or an epoxy methacrylate.

Claim 23

Dependent Claim 15 words

A process for preparing a nonaqueous dispersion of a thermosetting film-forming polymer comprising in combination

Claim 24

Dependent Claim 15 words

A process for preparing a nonaqueous dispersion of a thermosetting film-forming polymer comprising in combination

Annuity Stage	Window Opens	Payment Deadline	Surcharge Period Until	Estimated Fee	Status
3.5 Years (Year 4)	1978-09-22	1979-03-24	1979-09-23	$2000.00	Window Closed / Lapsed
7.5 Years (Year 8)	1982-09-22	1983-03-24	1983-09-23	$3760.00	Window Closed / Lapsed
11.5 Years (Year 12)	1986-09-22	1987-03-24	1987-09-23	$7700.00	Window Closed / Lapsed

Nonaqueous dispersions of thermosetting film forming polymers

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