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Method for making a monolithic ceramic capacitor with silver bearing electrodes

Assignee: Individual
•
Filing: 1974-08-05
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Granted: 1975-09-30
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Expires: 1994-08-05
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Abstract

Abstract In a method for making a monolithic ceramic capacitor, electroding paste is applied to plates of green ceramic. The paste contains palladium or silver or alloys or mixtures thereof and a substantial quantity of ceramic particles. The plates are stacked and the stack is immersed in a zirconia sand containing silver, and is fired at a temperature that sinters the ceramic material and melts the electroding metal. When the electroding metal is palladium, the surrounding silver vapor at firing diffuses into the metal forming a silver alloy therewith. The electroding metal may be silver or mixtures or alloys containing silver. In all cases the silver vapor atmosphere prevents substantial escape of silver from the electrodes.

Inventors

  • 👤 Maggio P Pechini

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 19:36
CPC Classifications
H; H01; H01G; H01G4/00; H01G4/30; H01G4/002; H01G4/018; H01G4/06; H01G4/08; H01G4/12; Y; Y10; Y10T; Y10T29/00; Y10T29/43; Y10T29/435

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 89 words
AA METHOD FOR MAKING A MONOLITHIC CERAMIC CAPACITOR HAVING SILVER BEARING ELECTRODES COMPRISNG: A. DEPOSITING ON PLATES OF A GREEN CERAMIC MATERIAL A FILM OF CONDUCTIVE ELECTRODING PASTE, SAID PASTE COMPRISING PARTICLES THAT ARE BY WEIGHT 50-80% METAL AND 50-20% CERAMIC MATERIAL, SAID METAL BEING SELECTED FROM THE GROUP CONSISTING OF PALLADIUM, SILVER, AND ALLOYS AND MIXTURES THEREOF, B. STACKING SAID PASTES, AND C. FIRING SAID STACK IN AN ATMOSPHERE CONTAINING SILVER VAPOR AT A SUFFICIENTLY HIGH TEMPERATURE TO SINTER SAID CERAMIC MATERIALS AND TO MELT SAID ELECTRODING METAL.
Claim 2
Dependent Claim 89 words
AA METHOD FOR MAKING A MONOLITHIC CERAMIC CAPACITOR HAVING SILVER BEARING ELECTRODES COMPRISNG: A. DEPOSITING ON PLATES OF A GREEN CERAMIC MATERIAL A FILM OF CONDUCTIVE ELECTRODING PASTE, SAID PASTE COMPRISING PARTICLES THAT ARE BY WEIGHT 50-80% METAL AND 50-20% CERAMIC MATERIAL, SAID METAL BEING SELECTED FROM THE GROUP CONSISTING OF PALLADIUM, SILVER, AND ALLOYS AND MIXTURES THEREOF, B. STACKING SAID PASTES, AND C. FIRING SAID STACK IN AN ATMOSPHERE CONTAINING SILVER VAPOR AT A SUFFICIENTLY HIGH TEMPERATURE TO SINTER SAID CERAMIC MATERIALS AND TO MELT SAID ELECTRODING METAL.
Claim 3
Dependent Claim 28 words
The method of claim 1 wherein said electroding metal is palladium, said silver vapor diffusing into said palladium during said firing and forming a molten silver palladium alloy.
Claim 4
Dependent Claim 16 words
The method of claim 2 wherein said green ceramic material comprises barium titanate and bismuth stannate.
Claim 5
Dependent Claim 17 words
The method of claim 1 wherein said firing is accomplished at a temperature from 1,800*C to 2,600*C.
Claim 6
Dependent Claim 24 words
The method of claim 1 wherein said silver vapor bearing environment at firing is produced by covering said stack with sand containing silver particles.
Claim 7
Dependent Claim 10 words
The method of claim 5 wherein said sand is zirconia.
Claim 8
Dependent Claim 19 words
The method of claim 5 wherein said silver loaded sand is comprised of about 3% silver and 97% zirconia.

References Cited (Backward Citations)

US3342655A Cited
US3615981A Cited
US3604082A Cited
US3784887A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-09-29 1979-03-31 1979-09-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-09-29 1983-03-31 1983-09-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-09-29 1987-03-31 1987-09-30 $7700.00 Window Closed / Lapsed

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