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US3915641A Expired / Lapsed US ⏱️ 0.0 years remaining

NMR method for determination of enantiomeric compositions with chiral shift reagents

Assignee: Wisconsin Alumni Research Foundation
•
Filing: 1973-07-02
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Granted: 1975-10-28
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Expires: 1993-07-02
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Abstract

Abstract Optically active fluorinated compounds derived from d- or lcamphor and their corresponding europium and praseodymium chelates and their use as chiral NMR shift reagents.

Inventors

  • 👤 Harlan L Goering
  • 👤 John N Eikenberry
  • 👤 Gerald S Koermer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 05:07
CPC Classifications
C; C07; C07C; C07C49/00; C07C49/92; C07C45/00; C07C45/45; C07C45/455; C07C45/87; C07C45/88; C07C49/385; C07C49/457; C07C49/467; C07C49/473; C07C49/477; C07C49/487; C07C49/507; C07C49/513; C07F; C07F5/00; C07F5/003; G; G01; G01N; G01N24/00; G01N24/08; G01R; G01R33/00; G01R33/20; G01R33/28; G01R33/281; Y; Y10; Y10T; Y10T436/00; Y10T436/24

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 29 words
THE METHOD FOR DETERMINATION OF ENANTIOMERIC COMPOSITIONS BY NMR ANALYSIS COMPRISING THE STEPS OF ADDING TO AN ENANTIOMERIC COMPOSITION A CHIRAL SHIFT REAGENT IN THE FORM OF TRIS 3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-D-CAMPHORATO
Claim 2
Independent Claim 29 words
THE METHOD FOR DETERMINATION OF ENANTIOMERIC COMPOSITIONS BY NMR ANALYSIS COMPRISING THE STEPS OF ADDING TO AN ENANTIOMERIC COMPOSITION A CHIRAL SHIFT REAGENT IN THE FORM OF TRIS 3-(HEPTAFLUOROPROPYLHYDROXYMETHYLENE)-D-CAMPHORATO
Claim 3
Independent Claim 38 words
The method for determination of enantiomeric compositions by NMR analysis comprising the steps of adding to an enantiomeric composition a chiral shift reagent in the form of tris(3-(heptafluoropropylhydroxymethylene)-d-camphorato)praseodymium(III) and carrying out an NMR analysis of the resulting mixture.
Claim 4
Independent Claim 38 words
The method for determination of enantiomeric compositions by NMR analysis comprising the steps of adding to an enantiomeric composition a chiral shift reagent in the form of tris(3-(heptafluoropropylhydroxymethylene)-d-camphorato)praseodymium(III) and carrying out an NMR analysis of the resulting mixture.

References Cited (Backward Citations)

US3702831A Cited
US3673107A Cited
US3706537A Cited
US3716335A Cited
US3700410A Cited
US3846333A Cited
US3730687A Cited
US3756779A Cited
US3867418A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1978-10-27 1979-04-28 1979-10-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1982-10-27 1983-04-28 1983-10-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1986-10-27 1987-04-28 1987-10-28 $7700.00 Window Closed / Lapsed

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