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US3948739A Expired / Lapsed US ⏱️ 0.0 years remaining

Coating compositions hardenable by ionization beams

Assignee: BASF Farben und Fasern AG
•
Filing: 1973-10-09
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Granted: 1976-04-06
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Expires: 1993-10-09
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Abstract

Abstract Coating compositions hardenable by ionizing radiation comprising as binding agents a mixture of A. at least 1 unsaturated olefin compound containing urethane groups, and B. at least 1 further unsaturated olefin compound that may be copolymerized, Characterized in that the unsaturated olefin compound (A) containing the urethane groups is a reaction product of A. a compound of the general formula ##EQU1## WHERE N IS 1 OR 2, WHERE R stands for a straigt chain or branched alkyl group of valence n, Where R 1 is hydrogen, methyl or the group ##EQU2## where R 3 is a monovalent alkyl residue and WHERE R 2 is hydrogen or methyl, and B. a compound containing at least 1 isocyanate group where the mixture of (A) and (B) may contain conventional additives of the lacquer industry.

Inventors

  • 👤 Dinkar Chaudhari
  • 👤 Ernst Haring
  • 👤 Arnold Dobbelstein
  • 👤 Wilfried Hoselmann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 17:41
CPC Classifications
C; C08; C08F; C08F20/00; C08F20/02; C08F20/10; C08F20/20; C08F20/34

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 120 words
In coating compositions hardenable by ionizing radiation comprising as binding agents a mixture of A. at least 1 unsaturated olefin compound containing urethane groups, and B. at least 1 further unsaturated olefin compound that may be copolymerized, the improvement comprising said unsaturated olefin compound (A) containing the urethane groups consisting essentially of a reaction product of a. a compound of the general formula ##EQU13## wherein n is 1 or 2, where R stands for a straight chain or branched alkyl group of valence n, where R 1 is hydrogen, methyl or the group ##EQU14## where R 3 is a monovalent alkyl group and where R 2 is hydrogen or methyl. and b. a compound containing at least 1 isocyanate group.
Claim 2
Dependent Claim 120 words
In coating compositions hardenable by ionizing radiation comprising as binding agents a mixture of A. at least 1 unsaturated olefin compound containing urethane groups, and B. at least 1 further unsaturated olefin compound that may be copolymerized, the improvement comprising said unsaturated olefin compound (A) containing the urethane groups consisting essentially of a reaction product of a. a compound of the general formula ##EQU13## wherein n is 1 or 2, where R stands for a straight chain or branched alkyl group of valence n, where R 1 is hydrogen, methyl or the group ##EQU14## where R 3 is a monovalent alkyl group and where R 2 is hydrogen or methyl. and b. a compound containing at least 1 isocyanate group.
Claim 3
Dependent Claim 44 words
The compositions of claim 1, wherein the term R in the general formula for component (A) (a) denotes a branched alkyl group with at least 4 carbon atoms and contains a tertiary carbon atom in the α position to the carboxylic acid ester group.
Claim 4
Dependent Claim 45 words
the composition of claim 1, wherein copolymerizable component (B) is selected from the group consisting of esters of acrylic acid with monovalent alcohols, esters of acrylic acid with multivalent alcohols, esters of methacrylic acid with monovalent alcohols and esters of methacrylic acid with multivalent alcohols.
Claim 5
Dependent Claim 31 words
The composition of claim 1, wherein copolymerizing component (B) is selected from the group consisting of esters of acrylic acid with divalent alcohols, and esters of methacrylic acid with divalent alcohols.
Claim 6
Dependent Claim 29 words
The composition of claim 1, wherein said compound containing at least 1 isocyanate group (b) is selected from the group consisting of hexa-methylene-diisocyanate, isophorone-diisocyanate, 2,4-toluylene-diisocyanate, 2,6-toluylene-diisocyanate, and 2,2,4- trimethyl-hexane-diisocyanate.
Claim 7
Independent Claim 126 words
A method of coating a substrate comprising hardening by ionizing radiation coating compositions comprising as binding agents a mixture of A. at least 1 unsaturated olefin compound containing urethane groups, and B. at least 1 further unsaturated olefin compound that may be copolymerized, the improvement comprising said unsaturated olefin compound (A) containing the urethane groups consisting essentially of a reaction product of a. a compound of the general formula ##EQU15## wherein n is 1 or 2, where R stands for a straight chain or branched alkyl group of valence n, where R 1 is hydrogen, methyl or the group ##EQU16## where R 3 is a monovalent alkyl group and where R 2 is hydrogen or methyl, and b. a compound containing at least 1 isocyanate group.
Claim 8
Independent Claim 126 words
A method of coating a substrate comprising hardening by ionizing radiation coating compositions comprising as binding agents a mixture of A. at least 1 unsaturated olefin compound containing urethane groups, and B. at least 1 further unsaturated olefin compound that may be copolymerized, the improvement comprising said unsaturated olefin compound (A) containing the urethane groups consisting essentially of a reaction product of a. a compound of the general formula ##EQU15## wherein n is 1 or 2, where R stands for a straight chain or branched alkyl group of valence n, where R 1 is hydrogen, methyl or the group ##EQU16## where R 3 is a monovalent alkyl group and where R 2 is hydrogen or methyl, and b. a compound containing at least 1 isocyanate group.

References Cited (Backward Citations)

US3224989A Cited
US3418295A Cited
GB1159551A Cited
GB1159552A Cited
US3448089A Cited
US3507821A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-04-06 1979-10-06 1980-04-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-04-06 1983-10-06 1984-04-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-04-06 1987-10-06 1988-04-06 $7700.00 Window Closed / Lapsed

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