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US4011386A
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Process for producing polymers or copolymers of norbornene-carboxylic acid amides
Assignee: JSR Corp
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Filing: 1974-09-04
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Granted: 1977-03-08
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Expires: 1994-09-04
Abstract
Abstract Novel polymers or copolymers of norbornene-carboxylic acid amides can be obtained by contacting, in the presence or absence of an inert solvent, (I) at least one compound selected from the group consisting of 5-norbornene-2-carboxylic acid amide, 5-norbornene-2,3-dicarboxylic acid diamide and substituted derivatives thereof, or (II) a mixture of the said compound (I) with at least one compound selected from the group consisting of norbornenes having at least one substituent selected from the group consisting of ester groups, nitrile groups, esterified hydroxyl groups, acid imide groups, halogens and acid anhydride groups and cyclic olefins, with a catalyst composed of (a) at least one compound selected from the group consisting of compounds of W, Mo and Re and (b) at least one compound selected from the group consisting of compounds of elements of Groups IA, IIA, IIB, IIIA, IVA and IVB of the Deming Periodic Table, said compounds having at least one element-carbon bond or element-hydrogen bond.
Inventors
- 👤 Shuichi Matsumoto
- 👤 Ryuichi Nakamura
- 👤 Seiji Fukuhara
- 👤 Kazuo Suzuki
- 👤 Koei Komatsu
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 18:39
CPC Classifications
C; C08; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
194 words
A polymer obtained by ring-opening polymerization of (I) at least one compound selected from the group consisting of monomers represented by the formula, ##STR14## wherein R 1 and R 2 are independently a hydrogen atom or a saturated or unsaturated hydrocarbon group having 1 to 10 carbon atoms; X is a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or a group of the formula; (CH.sub.2).sub.m CONR.sup.3 R.sup.4 wherein R 3 and R 4 are independently a hydrogen atom or a saturated or unsaturated hydrocarbon group having 1 to 10 carbon atoms; R 1 R 2 , R 3 and R 4 may be the same or different; R 5 , R 6 and R 7 are independently a hydrogen atom or a saturated or unsaturated hydrocarbon group having 1 to 10 carbon atoms; A and B are independently an alkyl group having 1 to 10 carbon atoms or a cycloalkyl, aralkyl or aryl group having up to 20 carbon atoms, and may be the same or different; Z is an alkylene group having 1 to 10 carbon atoms; and n and m are independently an integer of 0 to 10.
Claim 2
Dependent Claim
194 words
A polymer obtained by ring-opening polymerization of (I) at least one compound selected from the group consisting of monomers represented by the formula, ##STR14## wherein R 1 and R 2 are independently a hydrogen atom or a saturated or unsaturated hydrocarbon group having 1 to 10 carbon atoms; X is a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or a group of the formula; (CH.sub.2).sub.m CONR.sup.3 R.sup.4 wherein R 3 and R 4 are independently a hydrogen atom or a saturated or unsaturated hydrocarbon group having 1 to 10 carbon atoms; R 1 R 2 , R 3 and R 4 may be the same or different; R 5 , R 6 and R 7 are independently a hydrogen atom or a saturated or unsaturated hydrocarbon group having 1 to 10 carbon atoms; A and B are independently an alkyl group having 1 to 10 carbon atoms or a cycloalkyl, aralkyl or aryl group having up to 20 carbon atoms, and may be the same or different; Z is an alkylene group having 1 to 10 carbon atoms; and n and m are independently an integer of 0 to 10.
Claim 3
Dependent Claim
80 words
A polymer according to claim 1, wherein the ring-opening polymerization is effected by contacting the starting monomer or monomers with a catalyst composed of (a) at least one compound selected from the group consisting of compounds of W, Mo and Re and (b) at least one compound selected from the group consisting of compounds of elements of Groups IA, IIA, IIB, IIIA, IVA and IVB of the Deming Periodic Table, said compounds having at least one element-carbon or element-hydrogen bond.
Claim 4
Dependent Claim
62 words
A polymer according to claim 1, wherein the starting monomer (I) is selected from the group consisting of N,N-dimethyl-5-norbornene-2-carboxylic acid amide, N,N-diethyl-5-norbornene-2-carboxylic acid amide, N,N-dicyclohexyl-5-norbornene-2-carboxylic acid amide, N,N-dimethyl-2-methyl-5-norbornene-2-carboxylic acid amide, N,N-diethyl-3-phenyl-5-norbornene-2-carboxylic acid amide, N,N-di-n-propyl-2-octyl-5-norbornene-2-carboxylic acid amide, N,N-di-t-butyl-3-cyclohexyl-5-norbornene-2-carboxylic acid amide, N,N-di-n-octyl-3-methyl-5-norbornene-2-carboxylic acid amide, N,N,N',N'-tetramethyl-5-norbornene-2,3-dicarboxylic acid diamide, 4,7-dimethyl-4,7-diazatricyclo[8.2.1.0 2 ,9 ] tridec-11-ene-3,8-dione, 4-methyl-4-azatricyclo[6.2.1.0 2 ,7 ]undec-9-ene-3-one, N,N-dimethyl-2-methyl-3-methoxycarbonylbicyclo[2.2.1]hept-5-ene-2-carboxylic acid amide, and N.N-diethyl-3-cyanobicyclo [2.2.1]hept-5-ene-2-carboxylic acid amide.
Claim 5
Dependent Claim
24 words
A polymer according to claim 1, wherein the starting monomer is at least one member selected from the group consisting of 5-norbornene-2-carboxylic acid amide.
Claim 6
Dependent Claim
58 words
A polymer according to claim 4, wherein the starting monomer is at least one member selected from the group consisting of N,N-dimethyl-5-norbornene-2-carboxylic acid amide, N,N-diethyl-5-norbornene-2-carboxylic acid amide, N,N-dicyclohexyl-5-norbornene-2-carboxylic acid amide, N,N-dimethyl-2-methyl-5-norbornene-2-carboxylic acid amide, N,N-diethyl-3-phenyl-5-norbornene-2-carboxylic acid amide, N,N-di-n-propyl-2-octyl-5-norbornene-2-carboxylic acid amide, N,N-di-t-butyl-3-cyclohexyl-5-norbornene-2-carboxylic acid amide, N,N-di-n-octyl-3-methyl-5-norbornene-2-carboxylic acid amide, 4-methyl-4-azatricyclo[6.2.1.0 2 ,7 ]undec-9-ene-3-one, N,N dimethyl-2-methyl-3-methoxycarbonybicyclo [2.2.1]hept-5-ene-2-carboxylic acid amide and N,N-diethyl-3-cyanobicyclo[2.2.1]hept-5-ene-2-carboxylic acid amide.
Claim 7
Dependent Claim
14 words
A polymer according to claim 1, wherein the starting monomer is N,N-dimethyl-5-norbornene-2-carboxylic acid amide.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-03-07 | 1980-09-06 | 1981-03-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-07 | 1984-09-06 | 1985-03-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-07 | 1988-09-06 | 1989-03-08 | $7700.00 | Window Closed / Lapsed |