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US4023924A
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Concentrated aqueous dye compositions containing a low molecular weight amide and their use for dyeing paper
Assignee: Sandoz AG
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Filing: 1973-05-23
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Granted: 1977-05-17
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Expires: 1993-05-23
Abstract
Abstract Concentrated, liquid preparations of metal-free direct azo dyes which contain in each instance 1 part by weight of dye, 1 to 8 parts by weight of water, and 0.5 to 5 or preferably 0.5 to 2 parts by weight of an amide are useful for dyeing paper in the stock and for dyeing paper sheet.
Inventors
- 👤 Alfred Frei
- 👤 Georg Schoefberger
- 👤 August Schweizer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 17:17
CPC Classifications
C; C09; C09B; C09B43/00; C09B43/12; B; B32; B32B; B32B15/00; B32B15/04; B32B15/08; C09B31/00; C09B31/02; C09B31/025; C09B33/00; C09B33/02; C09B33/08; C09B33/10; C09B35/00; C09B35/02; C09B35/039; C09B35/08; C09B35/38; C09B35/44; C09B35/46; C09B43/136; C09B43/14; C09B43/16; C09B67/00; C09B67/0071; C09B67/0072; C09B67/0073; D; D21; D21H; D21H21/00; D21H21/14; D21H21/28
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
204 words
In a process for producing colored paper comprising incorporating into paper stock an effective amount of a dye composition and forming paper from said paper stock said effective amount being an amount sufficient to impart the desired color to the paper, the improvement wherein the dye composition is a concentrated, liquid dye composition comprising (i) 1 part by weight of a dye or a mixture thereof, (ii) 0.5-5 parts by weight of urea and (iii) 1 to 8 parts by weight of water, wherein said dye is a dye of the formula R.sub.11 --N= N--R.sub.13 --A--R.sub.14 --N=N--R.sub.12 or K.sub.1 --N=N--B--N=N--K.sub.2, or a salt thereof, wherein each of R 11 and R 12 is independently ##STR21## wherein R 21 is hydrogen, methyl or methoxy, and n is 1 or 2, ##STR22## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, ##STR23## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, A is --NH--, --NH--CO--NH--, trans--NH--CO-- CH=CH--CO--NH-- or ##STR24## wherein R 24 is hydrogen, phenyl or 3-sulfophenyl, each of K 1 and K 2 is independently ##STR25## wherein R 25 is --NH 2 or --OH, and ##STR26## wherein each R 26 is hydrogen, methyl or methoxy.
Claim 2
Dependent Claim
204 words
In a process for producing colored paper comprising incorporating into paper stock an effective amount of a dye composition and forming paper from said paper stock said effective amount being an amount sufficient to impart the desired color to the paper, the improvement wherein the dye composition is a concentrated, liquid dye composition comprising (i) 1 part by weight of a dye or a mixture thereof, (ii) 0.5-5 parts by weight of urea and (iii) 1 to 8 parts by weight of water, wherein said dye is a dye of the formula R.sub.11 --N= N--R.sub.13 --A--R.sub.14 --N=N--R.sub.12 or K.sub.1 --N=N--B--N=N--K.sub.2, or a salt thereof, wherein each of R 11 and R 12 is independently ##STR21## wherein R 21 is hydrogen, methyl or methoxy, and n is 1 or 2, ##STR22## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, ##STR23## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, A is --NH--, --NH--CO--NH--, trans--NH--CO-- CH=CH--CO--NH-- or ##STR24## wherein R 24 is hydrogen, phenyl or 3-sulfophenyl, each of K 1 and K 2 is independently ##STR25## wherein R 25 is --NH 2 or --OH, and ##STR26## wherein each R 26 is hydrogen, methyl or methoxy.
Claim 3
Dependent Claim
46 words
A process according to claim 1 wherein said concentrated, liquid dye composition consists essentially of (i) 1 part by weight of a dye or a mixture thereof, (ii) 0.5 to 5 parts by weight of urea and (iii) 1 to 8 parts by weight of water.
Claim 4
Dependent Claim
19 words
A process according to claim 2 wherein said dye composition comprises 0.5 to 2 parts by weight of urea.
Claim 5
Dependent Claim
94 words
A process according to claim 2 wherein said dye is a dye of the formula R.sub.11 --N=N--R.sub.13 --A--R.sub.14 --N=N--R.sub.12 or a salt thereof, wherein each of R 11 and R 12 is independently ##STR27## wherein R 21 is hydrogen, methyl or methoxy, and n is 1 or 2, ##STR28## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, ##STR29## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, A is --NH--, --NH--CO--NH--, trans---NH--CO-- CH=CH--CO--NH-- or ##STR30## wherein R 24 is hydrogen, phenyl or 3-sulfophenyl.
Claim 6
Dependent Claim
51 words
A process according to claim 2 wherein said dye is a dye of the formula K.sub.1 --N=N--B--N=N--K.sub.2, or a salt thereof, wherein each of K 1 and K 2 is independently ##STR31## wherein R 25 is --NH 2 or --OH, and ##STR32## wherein each R 26 is hydrogen, methyl or methoxy.
Claim 7
Dependent Claim
94 words
A process according to claim 1 wherein said dye is a dye of the formula R.sub.11 --N=N--R.sub.13 --A--R.sub.14 --N=N--R.sub.12 or a salt thereof, wherein each of R 11 and R 12 is independently ##STR33## wherein R 21 is hydrogen, methyl or methoxy, and n is 1 or 2, ##STR34## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, ##STR35## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, A is --NH--, --NH--CO--NH--, trans---NH--CO-- CH=CH--CO--NH-- or ##STR36## wherein R 24 is hydrogen, phenyl or 3-sulfophenyl.
Claim 8
Dependent Claim
10 words
A process according to claim 6 wherein A is --NH--CO--NH--.
Claim 9
Dependent Claim
20 words
A process according to claim 7 wherein said dye is the dye of the formula ##STR37## or a salt thereof.
Claim 10
Dependent Claim
21 words
A process according to claim 8 wherein said direct disazo, substantive, direct disazo dye is the dye of the formula ##STR38##
Claim 11
Dependent Claim
20 words
A process according to claim 7 wherein said dye is the dye of the formula ##STR39## or a salt thereof.
Claim 12
Dependent Claim
20 words
A process according to claim 7 wherein said dye is the dye of the formula ##STR40## or a salt thereof.
Claim 13
Dependent Claim
20 words
A process according to claim 7 wherein said dye is the dye of the formula ##STR41## or a salt thereof.
Claim 14
Dependent Claim
51 words
A process according to claim 1 wherein said dye is a dye of the formula K.sub.1 --N=N--B--N=N--K.sub.2, or a salt thereof, wherein each of K 1 and K 2 is independently ##STR42## wherein R 25 is --NH 2 or --OH, and ##STR43## wherein each R 26 is hydrogen, methyl or methoxy.
Claim 15
Dependent Claim
20 words
A process according to claim 13 wherein said dye is the dye of the formula ##STR44## or a salt thereof.
Claim 16
Dependent Claim
196 words
In a process for producing colored paper comprising treating paper sheet with an effective amount of a dye composition, said effective amount being an amount sufficient to impart the desired color to the paper, the improvement wherein said dye composition is a concentrated, liquid dye composition comprising (i) 1 part by weight of a dye or a mixture thereof, (ii) 0.5-5 parts by weight of urea and (iii) 1 to 8 parts by weight of water, wherein said dye is a dye of the formula R.sub.11 --N=N--R.sub.13 --A--R.sub.14 --N=N--R.sub.12 or K.sub.1 --N=N--B--N=N--K.sub.2, or a salt thereof, wherein each of R 11 and R 12 is independently ##STR45## wherein R 21 is hydrogen, methyl or methoxy, and n is 1 or 2, ##STR46## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, ##STR47## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, A is --NH--, --NH--CO--NH--, trans--NH--CO-- CH=CH--CO--NH-- or ##STR48## wherein R 24 is hydrogen, phenyl or 3-sulfophenyl each of K 1 and K 2 is independently ##STR49## wherein R 25 is --NH 2 or --OH, and ##STR50## wherein each R 26 is hydrogen, methyl or methoxy.
Claim 17
Dependent Claim
196 words
In a process for producing colored paper comprising treating paper sheet with an effective amount of a dye composition, said effective amount being an amount sufficient to impart the desired color to the paper, the improvement wherein said dye composition is a concentrated, liquid dye composition comprising (i) 1 part by weight of a dye or a mixture thereof, (ii) 0.5-5 parts by weight of urea and (iii) 1 to 8 parts by weight of water, wherein said dye is a dye of the formula R.sub.11 --N=N--R.sub.13 --A--R.sub.14 --N=N--R.sub.12 or K.sub.1 --N=N--B--N=N--K.sub.2, or a salt thereof, wherein each of R 11 and R 12 is independently ##STR45## wherein R 21 is hydrogen, methyl or methoxy, and n is 1 or 2, ##STR46## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, ##STR47## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, A is --NH--, --NH--CO--NH--, trans--NH--CO-- CH=CH--CO--NH-- or ##STR48## wherein R 24 is hydrogen, phenyl or 3-sulfophenyl each of K 1 and K 2 is independently ##STR49## wherein R 25 is --NH 2 or --OH, and ##STR50## wherein each R 26 is hydrogen, methyl or methoxy.
Claim 18
Dependent Claim
46 words
A process according to claim 15 wherein said concentrated, liquid dye composition consists essentially of (i) 1 part by weight of a dye or a mixture thereof, (ii) 0.5 to 5 parts by weight of urea and (iii) 1 to 8 parts by weight of water.
Claim 19
Dependent Claim
94 words
A process according to claim 15 wherein said dye is a dye of the formula R.sub.11 --N=N--R.sub.13 --A--R.sub.14 --N=N--R.sub.12, or a salt thereof, wherein each of R 11 and R 12 is independently ##STR51## wherein R 21 is hydrogen, methyl or methoxy, and n is 1 or 2, ##STR52## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, ##STR53## wherein R 22 is hydrogen or methoxy, and R 23 is hydrogen or methyl, A is --NH--, --NH--CO--NH--, trans--NH--CO-- CH=CH--CO--NH-- or ##STR54## wherein R 24 is hydrogen, phenyl or 3-sulfophenyl.
Claim 20
Dependent Claim
51 words
A process according to claim 15 wherein said dye is a dye of the formula K.sub.1 --N=N--B--N=N--K.sub.2, or a salt thereof, wherein each of K 1 and K 2 is independently ##STR55## wherein R 25 is --NH 2 or --OH, and ##STR56## wherein each R 26 is hydrogen, methyl or methoxy.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-16 | 1980-11-15 | 1981-05-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-16 | 1984-11-15 | 1985-05-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-16 | 1988-11-15 | 1989-05-17 | $7700.00 | Window Closed / Lapsed |