Patent US4026720A successfully refreshed from Google Patents.
US4026720A
Expired / Lapsed
US
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Coating composition for acrylics
Assignee: Daicel Corp
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Filing: 1975-05-08
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Granted: 1977-05-31
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Expires: 1995-05-08
Abstract
Abstract A coating composition comprises (1) a partially hydrolyzed siloxane compound, (2) one or more of alkali metal and zinc salts of naphthenic acid, (3) acetic acid, and (4) other organic solvents. This composition contains these components in appropriate proportions. The composition is coated on the surface of an acrylic resin object and is cured. The coated acrylic object possesses excellent properties such as surface hardness, mar resistance, solvent resistance and stress-crazing resistance.
Inventors
- 👤 Tadayoshi Ikeda
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 10:46
CPC Classifications
C; C09; C09D; C09D183/00; C09D183/04; C08; C08J; C08J7/00; C08J7/04; C08J7/0427; C08J7/043; C08J7/046; C08K; C08K5/00; C08K5/04; C08K5/09; C08J2333/00; C08J2483/00
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
220 words
A coating solution, consisting essentially of a. from 10 to 40 percent by weight, based on the total weight of the coating composition, of a partially hydrolyzed siloxane substance obtained by hydrolyzing in water, at 50° to 80° C., for one to 10 hours, a substance selected from the group consisting of 1. a hydrocarbon trialkoxy silane having the formula R'Si(OR") 3 , wherein R' is selected from the group consisting of alkyl having one to 4 carbon atoms, phenyl and vinyl, and R" is alkyl having one to 4 carbon atoms, and 2. co-condensation products of (1) and from 1 to 40 weight percent of phenyl or vinyl trialkoxy silane wherein alkoxy has one to 4 carbon atoms, b. from 0.05 to 5 percent by weight, based on the weight of component (a), of one or a mixture of salts selected from the group consisting of alkali metal salts of naphthenic acid and zinc salts of naphthenic acid, c. from 5 to 30 percent by weight, based on the total weight of the coating composition, of acetic acid, and d. the balance is one or a mixture of inert organic solvents for components (a) and (b), said inert solvent or solvents being present in an amount sufficient, in combination with component (c), to completely dissolve components (a) and (b).
Claim 2
Dependent Claim
220 words
A coating solution, consisting essentially of a. from 10 to 40 percent by weight, based on the total weight of the coating composition, of a partially hydrolyzed siloxane substance obtained by hydrolyzing in water, at 50° to 80° C., for one to 10 hours, a substance selected from the group consisting of 1. a hydrocarbon trialkoxy silane having the formula R'Si(OR") 3 , wherein R' is selected from the group consisting of alkyl having one to 4 carbon atoms, phenyl and vinyl, and R" is alkyl having one to 4 carbon atoms, and 2. co-condensation products of (1) and from 1 to 40 weight percent of phenyl or vinyl trialkoxy silane wherein alkoxy has one to 4 carbon atoms, b. from 0.05 to 5 percent by weight, based on the weight of component (a), of one or a mixture of salts selected from the group consisting of alkali metal salts of naphthenic acid and zinc salts of naphthenic acid, c. from 5 to 30 percent by weight, based on the total weight of the coating composition, of acetic acid, and d. the balance is one or a mixture of inert organic solvents for components (a) and (b), said inert solvent or solvents being present in an amount sufficient, in combination with component (c), to completely dissolve components (a) and (b).
Claim 3
Dependent Claim
20 words
A coating composition as set forth in claim 1, wherein said solvents (d) are alcohols, ketones, ether, or aromatic hydrocarbons.
Claim 4
Dependent Claim
17 words
A coating composition as set forth in claim 1 having a viscosity of 10 to 30 centipoises.
Claim 5
Dependent Claim
23 words
A coating composition as set forth in claim 1 in which Component (a) is methyl triethoxy silane and Component (b) is sodium naphthenate.
Claim 6
Dependent Claim
31 words
A coating composition as set forth in claim 1 wherein component (a) consists of (1) and component (b) consists of one or a mixture of alkali metal salts of naphthenic acid.
References Cited (Backward Citations)
US3476827A
Cited
US3894881A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-30 | 1980-11-29 | 1981-05-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-30 | 1984-11-29 | 1985-05-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-30 | 1988-11-29 | 1989-05-31 | $7700.00 | Window Closed / Lapsed |