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US4059565A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing a branched polycarbonate or poly(ester-carbonate)

Assignee: Mitsubishi Gas Chemical Co Inc
•
Filing: 1976-06-09
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Granted: 1977-11-22
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Expires: 1996-06-09
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Abstract

Abstract A polyfunctional organic compound, as a crosslinking agent, is used for producing a branched polycarbonate or poly(ester-carbonate).

Inventors

  • 👤 Hiroyuki Yoshizaki
  • 👤 Hiromitsu Takanohashi
  • 👤 Yoshitaka Masuda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:53
CPC Classifications
C; C08; C08G; C08G64/00; C08G64/04; C08G64/06; C08G64/14; C08G63/00; C08G63/64

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 205 words
In a process for producing a branched polycarbonate or poly(ester-carbonate) by reacting a combination of a monomer component composed of an aromatic dihydroxy compound (A) or a mixture of an aromatic dihydroxy compound (A) and a dibasic acid derivative (B), and a polyfunctional organic compound (C), with a compound of the formula COM.sub.2 where M is selected from a class of chloro and phenoxy, the improvement which comprises using, as the polyfunctional organic compound (C), a member selected from the compounds I, II, and III of the formulas ##STR3## where Z is selected from the class of chloroformyl (--COCl) and chloroformyloxy (--OCOCl), X and Y are similar or dissimilar and selected from the class of --COC1, --OCOCl, --OH and --COOH, and X and Y attach to 2- and 4-positions, 3- and 4-positions, or 3- and 5-positions based on the Z; A is similar or dissimilar and selected from the class of --COCl and --COOH; and B is similar or dissimilar and selected from the class of --OCOCl and --OH, the quantity of compound (C) being sufficient and up to 2 mole % based on the moles of compound (A) to provide a branching structure and to permit the polymer to be dissolved in a solvent.
Claim 2
Dependent Claim 205 words
In a process for producing a branched polycarbonate or poly(ester-carbonate) by reacting a combination of a monomer component composed of an aromatic dihydroxy compound (A) or a mixture of an aromatic dihydroxy compound (A) and a dibasic acid derivative (B), and a polyfunctional organic compound (C), with a compound of the formula COM.sub.2 where M is selected from a class of chloro and phenoxy, the improvement which comprises using, as the polyfunctional organic compound (C), a member selected from the compounds I, II, and III of the formulas ##STR3## where Z is selected from the class of chloroformyl (--COCl) and chloroformyloxy (--OCOCl), X and Y are similar or dissimilar and selected from the class of --COC1, --OCOCl, --OH and --COOH, and X and Y attach to 2- and 4-positions, 3- and 4-positions, or 3- and 5-positions based on the Z; A is similar or dissimilar and selected from the class of --COCl and --COOH; and B is similar or dissimilar and selected from the class of --OCOCl and --OH, the quantity of compound (C) being sufficient and up to 2 mole % based on the moles of compound (A) to provide a branching structure and to permit the polymer to be dissolved in a solvent.
Claim 3
Dependent Claim 49 words
A process for producing a branched polycarbonate according to claim 1 in which the monomer component is an aromatic dihydroxy compound (A), and the polyfunctional organic compound (C) is used in an amount of 0.1 -- 2 mole % based on the moles of the aromatic dihydroxy compound (A).
Claim 4
Dependent Claim 55 words
A process for producing a branched poly(estercarbonate) according to claim 1 in which the monomer component is a mixture of an aromatic dihydroxy compound (A) and a dibasic acid derivative (B), and the polyfunctional organic compound (C) is used in an amount of 0.1 - 1 mole % based on the moles of the mixture.
Claim 5
Dependent Claim 28 words
A process according to claim 3 in which the dibasic acid derivative (B) is an aromatic dibasic acid chloride, an aliphatic dibasic acid chloride, or a mixture thereof.
Claim 6
Dependent Claim 42 words
A process according to claim 3 in which the dibasic acid derivative (B) is used in an amount of not more than 40 mole % based on the total moles of the dibasic acid derivative (B) and the aromatic dihydroxy compound (A).
Claim 7
Dependent Claim 19 words
A process according to claim 1 in which the aromatic dihydroxy compound (A) is a halogen unsubstituted aromatic compound.
Claim 8
Dependent Claim 26 words
A process according to claim 1 in which the aromatic dihydroxy compound (A) contains at least 1 mole % of a halogen substituted aromatic dihydroxy compound.

References Cited (Backward Citations)

US3030331A Cited
US3169121A Cited
US3094508A Cited
US3525712A Cited
US3635895A Cited
US3541049A Cited
US3816373A Cited
US3972852A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-11-21 1981-05-23 1981-11-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-11-21 1985-05-23 1985-11-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-11-21 1989-05-23 1989-11-22 $7700.00 Window Closed / Lapsed

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