Patent US2952964A successfully refreshed from Google Patents.
Patent US4059565A successfully refreshed from Google Patents.
US4059565A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for producing a branched polycarbonate or poly(ester-carbonate)
Assignee: Mitsubishi Gas Chemical Co Inc
•
Filing: 1976-06-09
•
Granted: 1977-11-22
•
Expires: 1996-06-09
Abstract
Abstract A polyfunctional organic compound, as a crosslinking agent, is used for producing a branched polycarbonate or poly(ester-carbonate).
Inventors
- 👤 Hiroyuki Yoshizaki
- 👤 Hiromitsu Takanohashi
- 👤 Yoshitaka Masuda
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 23:28
CPC Classifications
C; C08; C08G; C08G64/00; C08G64/04; C08G64/06; C08G64/14; C08G63/00; C08G63/64
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
205 words
In a process for producing a branched polycarbonate or poly(ester-carbonate) by reacting a combination of a monomer component composed of an aromatic dihydroxy compound (A) or a mixture of an aromatic dihydroxy compound (A) and a dibasic acid derivative (B), and a polyfunctional organic compound (C), with a compound of the formula COM.sub.2 where M is selected from a class of chloro and phenoxy, the improvement which comprises using, as the polyfunctional organic compound (C), a member selected from the compounds I, II, and III of the formulas ##STR3## where Z is selected from the class of chloroformyl (--COCl) and chloroformyloxy (--OCOCl), X and Y are similar or dissimilar and selected from the class of --COC1, --OCOCl, --OH and --COOH, and X and Y attach to 2- and 4-positions, 3- and 4-positions, or 3- and 5-positions based on the Z; A is similar or dissimilar and selected from the class of --COCl and --COOH; and B is similar or dissimilar and selected from the class of --OCOCl and --OH, the quantity of compound (C) being sufficient and up to 2 mole % based on the moles of compound (A) to provide a branching structure and to permit the polymer to be dissolved in a solvent.
Claim 2
Dependent Claim
205 words
In a process for producing a branched polycarbonate or poly(ester-carbonate) by reacting a combination of a monomer component composed of an aromatic dihydroxy compound (A) or a mixture of an aromatic dihydroxy compound (A) and a dibasic acid derivative (B), and a polyfunctional organic compound (C), with a compound of the formula COM.sub.2 where M is selected from a class of chloro and phenoxy, the improvement which comprises using, as the polyfunctional organic compound (C), a member selected from the compounds I, II, and III of the formulas ##STR3## where Z is selected from the class of chloroformyl (--COCl) and chloroformyloxy (--OCOCl), X and Y are similar or dissimilar and selected from the class of --COC1, --OCOCl, --OH and --COOH, and X and Y attach to 2- and 4-positions, 3- and 4-positions, or 3- and 5-positions based on the Z; A is similar or dissimilar and selected from the class of --COCl and --COOH; and B is similar or dissimilar and selected from the class of --OCOCl and --OH, the quantity of compound (C) being sufficient and up to 2 mole % based on the moles of compound (A) to provide a branching structure and to permit the polymer to be dissolved in a solvent.
Claim 3
Dependent Claim
49 words
A process for producing a branched polycarbonate according to claim 1 in which the monomer component is an aromatic dihydroxy compound (A), and the polyfunctional organic compound (C) is used in an amount of 0.1 -- 2 mole % based on the moles of the aromatic dihydroxy compound (A).
Claim 4
Dependent Claim
55 words
A process for producing a branched poly(estercarbonate) according to claim 1 in which the monomer component is a mixture of an aromatic dihydroxy compound (A) and a dibasic acid derivative (B), and the polyfunctional organic compound (C) is used in an amount of 0.1 - 1 mole % based on the moles of the mixture.
Claim 5
Dependent Claim
28 words
A process according to claim 3 in which the dibasic acid derivative (B) is an aromatic dibasic acid chloride, an aliphatic dibasic acid chloride, or a mixture thereof.
Claim 6
Dependent Claim
42 words
A process according to claim 3 in which the dibasic acid derivative (B) is used in an amount of not more than 40 mole % based on the total moles of the dibasic acid derivative (B) and the aromatic dihydroxy compound (A).
Claim 7
Dependent Claim
19 words
A process according to claim 1 in which the aromatic dihydroxy compound (A) is a halogen unsubstituted aromatic compound.
Claim 8
Dependent Claim
26 words
A process according to claim 1 in which the aromatic dihydroxy compound (A) contains at least 1 mole % of a halogen substituted aromatic dihydroxy compound.
References Cited (Backward Citations)
US3030331A
Cited
US3169121A
Cited
US3094508A
Cited
US3525712A
Cited
US3635895A
Cited
US3541049A
Cited
US3816373A
Cited
US3972852A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-11-21 | 1981-05-23 | 1981-11-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-11-21 | 1985-05-23 | 1985-11-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-11-21 | 1989-05-23 | 1989-11-22 | $7700.00 | Window Closed / Lapsed |