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US4072694A Expired / Lapsed US ⏱️ 0.0 years remaining

Dioxolane derivatives and use as photoinitiators

Assignee: Lee Pharmaceuticals Inc
•
Filing: 1975-09-15
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Granted: 1978-02-07
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Expires: 1995-09-15
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Abstract

Abstract Dioxolane compounds useful to initiate photopolymerization and polymerizable compositions of matter containing such compounds.

Inventors

  • 👤 Alan J. Brattesani

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 07:20
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; C07; C07D; C07D317/00; C07D317/08; C07D317/10; C07D317/14; C07D317/26; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/124

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 185 words
Compounds having the general formula: ##STR3## wherein R 1 and R 2 are each organic radicals selected from the group consisting of vinyl, hydroperoxy, alkyl or alkenyl groups of up to about 16 carbon atom length, cycloaliphatic groups of lower than 210 molecular weight, phenyl, naphthyl, phenoxy, benzoyl, naphthoxyl, phenylcarboxy, and substituted aliphatic groups of up to 200 molecular weight, and Ar 1 and Ar 2 are each selected from the group consisting of phenyl, naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphythyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that when Ar 1 and Ar 2 are phenyl or lower alkyl-substituted phenyl and one of R 1 and R 2 is lower alkyl, the other may not be lower alkyl, cycloalkyl or phenyl.
Claim 2
Dependent Claim 185 words
Compounds having the general formula: ##STR3## wherein R 1 and R 2 are each organic radicals selected from the group consisting of vinyl, hydroperoxy, alkyl or alkenyl groups of up to about 16 carbon atom length, cycloaliphatic groups of lower than 210 molecular weight, phenyl, naphthyl, phenoxy, benzoyl, naphthoxyl, phenylcarboxy, and substituted aliphatic groups of up to 200 molecular weight, and Ar 1 and Ar 2 are each selected from the group consisting of phenyl, naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphythyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that when Ar 1 and Ar 2 are phenyl or lower alkyl-substituted phenyl and one of R 1 and R 2 is lower alkyl, the other may not be lower alkyl, cycloalkyl or phenyl.
Claim 3
Dependent Claim 29 words
Compounds according to claim 1 in which Ar 1 and Ar 2 are each selected from the group consisting of non-sterically hindered substituted phenyl and non-sterically hindered substituted naphthyl.
Claim 4
Dependent Claim 24 words
Compounds according to claim 1 in which R 1 and R 2 are each selected from the group consisting of phenyl and methyl groups.
Claim 5
Dependent Claim 16 words
Compounds according to claim 1 in which Ar 1 and Ar 2 are each phenyl groups.
Claim 6
Dependent Claim 158 words
Compounds having the general formula: ##STR4## wherein R 1 is an organic radical selected from the group consisting of vinyl, hydroperoxy, alkyl or alkenyl groups of up to about 16 carbon atom length, cycloaliphatic groups of lower than 210 molecular weight, phenyl, naphthyl, phenoxy, benzoyl, naphthoxyl, phenylcarboxy, and substituted aliphatic groups of up to 200 molecular weight, and Ar 1 and Ar 2 are each selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphythyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 1 or Ar 2 is not lower alkyl-substituted phenyl.
Claim 7
Dependent Claim 158 words
Compounds having the general formula: ##STR4## wherein R 1 is an organic radical selected from the group consisting of vinyl, hydroperoxy, alkyl or alkenyl groups of up to about 16 carbon atom length, cycloaliphatic groups of lower than 210 molecular weight, phenyl, naphthyl, phenoxy, benzoyl, naphthoxyl, phenylcarboxy, and substituted aliphatic groups of up to 200 molecular weight, and Ar 1 and Ar 2 are each selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphythyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 1 or Ar 2 is not lower alkyl-substituted phenyl.
Claim 8
Dependent Claim 29 words
Compounds according to claim 5 in which Ar 1 and Ar 2 are each selected from the group consisting of non-sterically hindered substituted phenyl and non-sterically hindered substituted naphthyl.
Claim 9
Dependent Claim 20 words
Compounds according to claim 5 in which R 1 is selected from the group consisting of phenyl and methyl groups.
Claim 10
Dependent Claim 100 words
Compounds having the general formula: ##STR5## wherein Ar 1 is selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphthyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 1 is not lower alkyl-substituted phenyl.
Claim 11
Dependent Claim 100 words
Compounds having the general formula: ##STR5## wherein Ar 1 is selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphthyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 1 is not lower alkyl-substituted phenyl.
Claim 12
Dependent Claim 25 words
Compounds according to claim 8 in which Ar 1 is selected from the group consisting of non-sterically hindered substituted phenyl and non-sterically hindered substituted naphthyl.
Claim 13
Dependent Claim 100 words
Compounds having the general formula: ##STR6## wherein Ar 2 is selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphthyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 2 is not lower alkyl-substituted phenyl.
Claim 14
Dependent Claim 100 words
Compounds having the general formula: ##STR6## wherein Ar 2 is selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphthyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 2 is not lower alkyl-substituted phenyl.
Claim 15
Dependent Claim 25 words
Compounds according to claim 10 in which Ar 2 is selected from the group consisting of non-sterically hindered substituted phenyl and non-sterically hindered substituted naphthyl.

References Cited (Backward Citations)

US3344148A Cited
US3944509A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-02-06 1981-08-08 1982-02-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-02-06 1985-08-08 1986-02-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-02-06 1989-08-08 1990-02-07 $7700.00 Window Closed / Lapsed

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