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US4072694A
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US
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Dioxolane derivatives and use as photoinitiators
Assignee: Lee Pharmaceuticals Inc
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Filing: 1975-09-15
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Granted: 1978-02-07
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Expires: 1995-09-15
Abstract
Abstract Dioxolane compounds useful to initiate photopolymerization and polymerizable compositions of matter containing such compounds.
Inventors
- 👤 Alan J. Brattesani
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 08:40
CPC Classifications
C; C08; C08F; C08F2/00; C08F2/46; C08F2/48; C08F2/50; C07; C07D; C07D317/00; C07D317/08; C07D317/10; C07D317/14; C07D317/26; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/124
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
185 words
Compounds having the general formula: ##STR3## wherein R 1 and R 2 are each organic radicals selected from the group consisting of vinyl, hydroperoxy, alkyl or alkenyl groups of up to about 16 carbon atom length, cycloaliphatic groups of lower than 210 molecular weight, phenyl, naphthyl, phenoxy, benzoyl, naphthoxyl, phenylcarboxy, and substituted aliphatic groups of up to 200 molecular weight, and Ar 1 and Ar 2 are each selected from the group consisting of phenyl, naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphythyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that when Ar 1 and Ar 2 are phenyl or lower alkyl-substituted phenyl and one of R 1 and R 2 is lower alkyl, the other may not be lower alkyl, cycloalkyl or phenyl.
Claim 2
Dependent Claim
185 words
Compounds having the general formula: ##STR3## wherein R 1 and R 2 are each organic radicals selected from the group consisting of vinyl, hydroperoxy, alkyl or alkenyl groups of up to about 16 carbon atom length, cycloaliphatic groups of lower than 210 molecular weight, phenyl, naphthyl, phenoxy, benzoyl, naphthoxyl, phenylcarboxy, and substituted aliphatic groups of up to 200 molecular weight, and Ar 1 and Ar 2 are each selected from the group consisting of phenyl, naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphythyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that when Ar 1 and Ar 2 are phenyl or lower alkyl-substituted phenyl and one of R 1 and R 2 is lower alkyl, the other may not be lower alkyl, cycloalkyl or phenyl.
Claim 3
Dependent Claim
29 words
Compounds according to claim 1 in which Ar 1 and Ar 2 are each selected from the group consisting of non-sterically hindered substituted phenyl and non-sterically hindered substituted naphthyl.
Claim 4
Dependent Claim
24 words
Compounds according to claim 1 in which R 1 and R 2 are each selected from the group consisting of phenyl and methyl groups.
Claim 5
Dependent Claim
16 words
Compounds according to claim 1 in which Ar 1 and Ar 2 are each phenyl groups.
Claim 6
Dependent Claim
158 words
Compounds having the general formula: ##STR4## wherein R 1 is an organic radical selected from the group consisting of vinyl, hydroperoxy, alkyl or alkenyl groups of up to about 16 carbon atom length, cycloaliphatic groups of lower than 210 molecular weight, phenyl, naphthyl, phenoxy, benzoyl, naphthoxyl, phenylcarboxy, and substituted aliphatic groups of up to 200 molecular weight, and Ar 1 and Ar 2 are each selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphythyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 1 or Ar 2 is not lower alkyl-substituted phenyl.
Claim 7
Dependent Claim
158 words
Compounds having the general formula: ##STR4## wherein R 1 is an organic radical selected from the group consisting of vinyl, hydroperoxy, alkyl or alkenyl groups of up to about 16 carbon atom length, cycloaliphatic groups of lower than 210 molecular weight, phenyl, naphthyl, phenoxy, benzoyl, naphthoxyl, phenylcarboxy, and substituted aliphatic groups of up to 200 molecular weight, and Ar 1 and Ar 2 are each selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphythyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 1 or Ar 2 is not lower alkyl-substituted phenyl.
Claim 8
Dependent Claim
29 words
Compounds according to claim 5 in which Ar 1 and Ar 2 are each selected from the group consisting of non-sterically hindered substituted phenyl and non-sterically hindered substituted naphthyl.
Claim 9
Dependent Claim
20 words
Compounds according to claim 5 in which R 1 is selected from the group consisting of phenyl and methyl groups.
Claim 10
Dependent Claim
100 words
Compounds having the general formula: ##STR5## wherein Ar 1 is selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphthyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 1 is not lower alkyl-substituted phenyl.
Claim 11
Dependent Claim
100 words
Compounds having the general formula: ##STR5## wherein Ar 1 is selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphthyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 1 is not lower alkyl-substituted phenyl.
Claim 12
Dependent Claim
25 words
Compounds according to claim 8 in which Ar 1 is selected from the group consisting of non-sterically hindered substituted phenyl and non-sterically hindered substituted naphthyl.
Claim 13
Dependent Claim
100 words
Compounds having the general formula: ##STR6## wherein Ar 2 is selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphthyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 2 is not lower alkyl-substituted phenyl.
Claim 14
Dependent Claim
100 words
Compounds having the general formula: ##STR6## wherein Ar 2 is selected from the group consisting of naphthyl, non-sterically hindered substituted phenyl, and non-sterically hindered substituted naphthyl in which each substituent is a radical selected from the group consisting of amino, nitro, chloro-, bromo-, iodo-, fluoro-, lower alkylamino-, anilino-, di- lower alkylamino-, diphenylamino, lower alkoxy, carboxy, hydroxy, sulfonyl, acetyl, propionyl, aldehydro, acetoxy, propionoxy, amido, lower alkylamido, vinyl, lower alkenyl, lower alkynyl, lower alkyl, phenyl, benzyl, naphthyl, cyclohexyl, cyclopentyl, lower alkyl amido, di- lower alkyl amido, phenyl amido, and diphenyl amido with the proviso that Ar 2 is not lower alkyl-substituted phenyl.
Claim 15
Dependent Claim
25 words
Compounds according to claim 10 in which Ar 2 is selected from the group consisting of non-sterically hindered substituted phenyl and non-sterically hindered substituted naphthyl.
References Cited (Backward Citations)
US3344148A
Cited
US3944509A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-02-06 | 1981-08-08 | 1982-02-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-02-06 | 1985-08-08 | 1986-02-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-02-06 | 1989-08-08 | 1990-02-07 | $7700.00 | Window Closed / Lapsed |