Patent US4089692A successfully refreshed from Google Patents.
US4089692A
Expired / Lapsed
US
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Settable composition containing aluminum phosphate and method for preparing same
Assignee: Ashland LLC
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Filing: 1975-06-18
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Granted: 1978-05-16
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Expires: 1995-06-18
Abstract
Abstract Settable composition comprising aluminum phosphate, solid organic carboxylic acid, water, and material containing an alkaline earth metal and an oxide, and being obtained by providing an admixture of the above constituents whereby the solid organic carboxylic acid and alkaline earth material are not precontacted with each other prior to contact of the material containing an alkaline earth material with the aluminum phosphate, and process for preparing same are provided.
Inventors
- 👤 Richard H. Toeniskoetter
- 👤 John J. Spiwak
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 07:07
CPC Classifications
C; C04; C04B; C04B28/00; C04B28/34; B; B22; B22C; B22C1/00; B22C1/16; B22C1/18
Claims Analysis
Total Claims: 36
Claim 1
Independent Claim
288 words
Process for preparing settable composition comprising: (A) providing aluminum phsophate; (B) providing solid organic carboxylic acid; (C) providing oxygen-containing alkaline earth compound; (D) providing water; and (E) admixing said aluminum phosphate, said solid organic carboxylic acid, said alkaline earth material, and water provided that said solid organic carboxylic acid and said alkaline earth material are not precontacted with each other prior to contact of the alkaline earth material with the aluminum phosphate; and (F) wherein said aluminum phosphate contains 0 to about 40 mole % of boron based upon the moles of aluminum and contains a mole ratio of phosphorus to total moles of aluminum and boron of at least about 2:1; (G) said solid organic carboxylic acid being soluble in aqueous solutions of the aluminum phosphate and containing at least two substituents selected from the group consisting of at lease two carboxylic acid groups; and at lease one carboxylic acid group, and at least one hydroxyl group, or keto tautomers thereof; (H) said alkaline earth metal compound contains alkaline earth metal and an oxide; and is capable of reacting with the aluminum phosphate; and (I) wherein the amount of aluminum phosphate is from about 50 to about 95% by weight based upon the total weight of aluminum phosphate and alkaline earth compound; the amount of alkaline earth compound is from about 50 to about 5% by weight based upon the total weight of aluminum phosphate and alkaline earth compound; the amount of water is from about 15 to about 50% by weight based upon the total weight of aluminum phosphate and water; and the amount of said acid is from about 0.5 to about 25% by weight based upon the total weight of aluminum phosphate, and acid.
Claim 2
Dependent Claim
288 words
Process for preparing settable composition comprising: (A) providing aluminum phsophate; (B) providing solid organic carboxylic acid; (C) providing oxygen-containing alkaline earth compound; (D) providing water; and (E) admixing said aluminum phosphate, said solid organic carboxylic acid, said alkaline earth material, and water provided that said solid organic carboxylic acid and said alkaline earth material are not precontacted with each other prior to contact of the alkaline earth material with the aluminum phosphate; and (F) wherein said aluminum phosphate contains 0 to about 40 mole % of boron based upon the moles of aluminum and contains a mole ratio of phosphorus to total moles of aluminum and boron of at least about 2:1; (G) said solid organic carboxylic acid being soluble in aqueous solutions of the aluminum phosphate and containing at least two substituents selected from the group consisting of at lease two carboxylic acid groups; and at lease one carboxylic acid group, and at least one hydroxyl group, or keto tautomers thereof; (H) said alkaline earth metal compound contains alkaline earth metal and an oxide; and is capable of reacting with the aluminum phosphate; and (I) wherein the amount of aluminum phosphate is from about 50 to about 95% by weight based upon the total weight of aluminum phosphate and alkaline earth compound; the amount of alkaline earth compound is from about 50 to about 5% by weight based upon the total weight of aluminum phosphate and alkaline earth compound; the amount of water is from about 15 to about 50% by weight based upon the total weight of aluminum phosphate and water; and the amount of said acid is from about 0.5 to about 25% by weight based upon the total weight of aluminum phosphate, and acid.
Claim 3
Dependent Claim
28 words
The process of claim 1 wherein said aluminum phosphate contains boron in an amount from about 3 to about 40 mole % based upon the moles of aluminum.
Claim 4
Dependent Claim
28 words
The process of claim 1 wherein said aluminum phosphate contains boron in an amount from about 5 to about 30 mole % based upon the moles of aluminum.
Claim 5
Dependent Claim
28 words
The process of claim 1 wherein said aluminum phosphate contains boron in an amount from about 10 to about 25 mole % based upon the moles of aluminum.
Claim 6
Dependent Claim
29 words
The process of claim 1 wherein the aluminum phosphate contains a mole ratio of phosphorus to total moles of aluminum and boron of from about 2.5:1 to about 3.5:1.
Claim 7
Dependent Claim
29 words
The process of claim 1 wherein the aluminum phosphate contains a mole ratio of phosphorus to total moles of aluminum and boron of from about 2.8:1 to about 3.2:1.
Claim 8
Dependent Claim
49 words
The process of claim 1 wherein said aluminum phosphate contains boron in an amount between about 10 and about 25 mole % based upon the moles of aluminum, and wherein the mole ratio of phosphorus to total moles of aluminum and boron is between about 2.8:1 to about 3.2:1.
Claim 9
Dependent Claim
61 words
The process of claim 1 wherein the amount of said aluminum phosphate is from about 65 to about 90% by weight based upon the total weight of aluminum phosphate and alkaline earth compound, and the amount of alkaline earth compound is from about 10 to about 35% by weight based upon the total weight of aluminum phosphate and alkaline earth compound.
Claim 10
Dependent Claim
18 words
The process of claim 1 wherein said solid organic carboxylic acid contains 2 to about 20 carbon atoms.
Claim 11
Dependent Claim
20 words
The process of claim 1 wherein said solid organic carboxylic acid contains from about 2 to about 10 carbon atoms.
Claim 12
Dependent Claim
19 words
The process of claim 1 wherein said organic carboxylic acid contains from about 2 to about 20 reactive groups.
Claim 13
Dependent Claim
32 words
The process of claim 1 wherein said organic carboxylic acid is selected from the group consisting of tartaric acid, gluconic acid, oxalic acid, citric acid, malonic acid, lactic acid, and mixtures thereof.
Claim 14
Dependent Claim
14 words
The process of claim 1 wherein said solid organic carboxylic acid is tartaric acid.
Claim 15
Dependent Claim
14 words
The process of claim 1 wherein said solid organic carboxylic acid is gluconic acid.
Claim 16
Dependent Claim
34 words
The process of claim 1 wherein the amount of organic carboxylic acid is from about 2 to about 15% by weight based upon the total weight of the aluminum phosphate and organic carboxylic acid.
Claim 17
Dependent Claim
47 words
The process of claim 1 wherein said alkaline earth compound includes a free alkaline earth metal oxide or a free alkaline earth metal hydroxide and wherein said oxide or hydroxide has a surface area no greater than about 8.5 m 2 /gram (measured by the BET procedure).
Claim 18
Dependent Claim
29 words
The process of claim 16 wherein said alkaline earth metal oxide of free alkaline earth metal hydroxide has a surface area no greater than about 3 m 2 /gram.
Claim 19
Dependent Claim
55 words
The process of claim 1 wherein said alkaline earth metal compound is a mixture of a free alkaline earth metal oxide and a material which contains the alkaline earth metal and oxide in combination with another constituent and wherein said alkaline earth compound has a surface area no greater than about 8.5 m 2 /gram.
Claim 20
Dependent Claim
14 words
The process of claim 18 wherein said alkaline earth metal oxide is magnesium oxide.
Claim 21
Dependent Claim
48 words
The process of claim 18 wherein said mixture contains from about 2 to about 8 parts by weight of the free alkaline earth metal oxide per part by weight of the material containing another constituent in combination with the free metal oxide and/or hydroxide and alkaline earth metal.
Claim 22
Dependent Claim
30 words
The process of claim 1 wherein the amount of water is from about 20 to about 40% by weight based upon the total weight of the aluminum phosphate and water.
Claim 23
Dependent Claim
279 words
A settable composition comprising: (A) aluminum phosphate containing 0 to about 40 mole % of boron based upon the moles of aluminum and containing a mole ratio of phosphorus to total moles of aluminum and boron of at least about 2:1; (B) solid organic carboxylic acid being soluble in aqueous solutions of the aluminum phosphate and containing at least two substituents selected from the group consisting of at least two carboxylic acid groups; and at least one carboxylic acid group and at least one hydroxyl group; or keto derivatives thereof; (C) oxygen-containing alkaline earth compound containing alkaline earth metal and an oxide; and being capable of reacting with said aluminum phosphate; and (D) water; and wherein the amount of the alkaline earth compound is from about 50 to about 5% by weight based upon the total weight of the aluminum phosphate and alkaline earth compound; the amount of the aluminum phosphate is from about 95 to about 50% by weight based upon the total weight of the aluminum phosphate and alkaline earth compound; the amount of water is from about 15 to about 50% by weight based upon the total weight of the aluminum phosphate and water; and the amount of the solid organic carboxylic acid is from about 0.5 to about 25% by weight based upon the total weight of aluminum phosphate and acid; and wherein said composition is obtained by providing an admixture of said aluminum phosphate, said solid organic carboxylic acid, said alkaline earth material, and said water wherein the solid organic carboxylic acid and alkaline earth material are not precontacted with each other prior to contact of the alkaline earth material with the aluminum phosphate.
Claim 24
Dependent Claim
279 words
A settable composition comprising: (A) aluminum phosphate containing 0 to about 40 mole % of boron based upon the moles of aluminum and containing a mole ratio of phosphorus to total moles of aluminum and boron of at least about 2:1; (B) solid organic carboxylic acid being soluble in aqueous solutions of the aluminum phosphate and containing at least two substituents selected from the group consisting of at least two carboxylic acid groups; and at least one carboxylic acid group and at least one hydroxyl group; or keto derivatives thereof; (C) oxygen-containing alkaline earth compound containing alkaline earth metal and an oxide; and being capable of reacting with said aluminum phosphate; and (D) water; and wherein the amount of the alkaline earth compound is from about 50 to about 5% by weight based upon the total weight of the aluminum phosphate and alkaline earth compound; the amount of the aluminum phosphate is from about 95 to about 50% by weight based upon the total weight of the aluminum phosphate and alkaline earth compound; the amount of water is from about 15 to about 50% by weight based upon the total weight of the aluminum phosphate and water; and the amount of the solid organic carboxylic acid is from about 0.5 to about 25% by weight based upon the total weight of aluminum phosphate and acid; and wherein said composition is obtained by providing an admixture of said aluminum phosphate, said solid organic carboxylic acid, said alkaline earth material, and said water wherein the solid organic carboxylic acid and alkaline earth material are not precontacted with each other prior to contact of the alkaline earth material with the aluminum phosphate.
Claim 25
Dependent Claim
31 words
Molding composition which comprises: (A) a major amount of aggregate; and (B) an effective bonding amount up to about 40% by weight of the aggregate of the composition of claim 22.
Claim 26
Dependent Claim
14 words
The process of claim 1 wherein said solid organic carboxylic acid is oxalic acid.
Claim 27
Dependent Claim
14 words
The process of claim 1 wherein said solid organic carboxylic acid is citric acid.
Claim 28
Dependent Claim
14 words
The process of claim 1 wherein said solid organic carboxylic acid is malonic acid.
Claim 29
Dependent Claim
14 words
The process of claim 1 wherein said solid organic carboxylic acid is lactic acid.
Claim 30
Dependent Claim
14 words
The process of claim 2 wherein said solid organic carboxylic acid is tartaric acid.
Claim 31
Dependent Claim
14 words
The process of claim 2 wherein said solid organic carboxylic acid is gluconic acid.
Claim 32
Dependent Claim
14 words
The process of claim 2 wherein said solid organic carboxylic acid is oxalic acid.
Claim 33
Dependent Claim
14 words
The process of claim 2 wherein said solid organic carboxylic acid is citric acid.
Claim 34
Dependent Claim
14 words
The process of claim 2 wherein said solid organic carboxylic acid is malonic acid.
Claim 35
Dependent Claim
14 words
The process of claim 2 wherein said solid organic carboxylic acid is lactic acid.
Claim 36
Dependent Claim
32 words
The process of claim 2 wherein said organic carboxylic acid is selected from the group consisting of tartaric acid, gluconic acid, oxalic acid, citric acid, malonic acid, lactic acid, and mixtures thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-05-15 | 1981-11-14 | 1982-05-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-05-15 | 1985-11-14 | 1986-05-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-05-15 | 1989-11-14 | 1990-05-16 | $7700.00 | Window Closed / Lapsed |