Preparation of carbodiimide in presence of phospholene catalysts

Claim 1

In a process for the preparation of a carbodiimide by heating the appropriate organic isocyanate in the presence of a catalyst, the improvement which comprises employing as said catalyst a polymer selected from the class consisting of (i) homopolymer of compounds of the formula ##STR4## wherein the broken lines in the phospholene nucleus indicate a double bond located between the carbon atom at position 3 and one of the carbon atoms at positions 2 and 4, the H atom is attached to whichever carbon atom at positions 2 and 4 is not part of said double bond, R is selected from the group consisting of halogen, lower-alkoxy, phenoxy, hydrocarbyl from 1 to 18 carbon atoms, inclusive, and halohydrocarbyl from 1 to 18 carbon atoms, inclusive, x is 0 to 3, C n H 2n and C n' H 2n' are each independently alkylene from 2 to 6 carbon atoms, and R 1 is selected from the class consisting of hydrogen, methyl, halo and cyano and (ii) copolymers of the compounds of the above formula with at least one acrylate selected from the class consisting of the lower-alkyl esters of acrylic, methacrylic, 2-haloacrylic and 2-cyanoacrylic acids.