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US4128532A
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Polyetheresters which contain hydroxyl groups and the use thereof in the production of flame resistant synthetic resins
Assignee: Bayer AG
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Filing: 1977-11-21
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Granted: 1978-12-05
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Expires: 1997-11-21
Abstract
Abstract The instant invention is broadly directed to novel polyether esters and the use thereof in manufacturing polyurethane resins. The novel products are produced by esterifying an alkoxylated, halogenated bisphenol, a polycarboxylic acid and a dihydric alcohol.
Inventors
- 👤 Erich Eimers
- 👤 Rolf Dhein
- 👤 Rolf Wiedermann
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 13:01
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/42; C08G18/46; C08G18/4607; C08G18/4205; C08G18/4208; C08G18/4222; C08G18/67; C08G18/68; C08G18/683; C08G63/00; C08G63/68; C08G63/682; C08G63/6824
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
193 words
A liquid polyetherester which contains hydroxyl groups and has an acid number of from 0 to 5, a hydroxyl number of from 100 to 300 and a viscosity of from 10 to 200 poises at 25° C. obtained by the esterification of: (a) a bis-hydroxyalkyl ether of halogenated 2,2-diphenylolpropane corresponding to the general formula: ##STR6## wherein n = 0 or 1; R 1 through R 6 may be the same or different and represent H, or C 1 -C 4 alkyl; and R 7 through R 10 may be the same or different and represent H, C 1 -C 4 alkyl or halogen, at least one of the groups R 7 -R 10 being a halogen atom; and (b) a polycarboxylic acid selected from the group consisting of saturated, unsaturated, aromatic polycarboxylic acids and mixtures thereof; (c) in the presence of an excess of a dihydric alcohol corresponding to the following formula: ##STR7## wherein X 1 through X 8 are the same or different and represent H, or C 1 -C 4 alkyl; m = 1-10, and A represents O or S, and the reaction temperature is from 120° C. to 200° C.
Claim 2
Dependent Claim
193 words
A liquid polyetherester which contains hydroxyl groups and has an acid number of from 0 to 5, a hydroxyl number of from 100 to 300 and a viscosity of from 10 to 200 poises at 25° C. obtained by the esterification of: (a) a bis-hydroxyalkyl ether of halogenated 2,2-diphenylolpropane corresponding to the general formula: ##STR6## wherein n = 0 or 1; R 1 through R 6 may be the same or different and represent H, or C 1 -C 4 alkyl; and R 7 through R 10 may be the same or different and represent H, C 1 -C 4 alkyl or halogen, at least one of the groups R 7 -R 10 being a halogen atom; and (b) a polycarboxylic acid selected from the group consisting of saturated, unsaturated, aromatic polycarboxylic acids and mixtures thereof; (c) in the presence of an excess of a dihydric alcohol corresponding to the following formula: ##STR7## wherein X 1 through X 8 are the same or different and represent H, or C 1 -C 4 alkyl; m = 1-10, and A represents O or S, and the reaction temperature is from 120° C. to 200° C.
Claim 3
Dependent Claim
91 words
The polyetherester of claim 1 wherein said polyetherester has an acid number of from 0 to 1, and a hydroxyl number of from 150 to 250, and wherein (A) R 1 through R 6 represent H, CH 3 or C 2 H 5 , (b) r 7 through R 10 represents H, Br, Cl, CH 3 or C 2 H 5 , and at least one of R 7 through R 10 represents Br, and (C) X 1 through X 8 represent H, CH 3 or C 2 H 5 .
Claim 4
Dependent Claim
21 words
The polyetherester of claim 1 wherein the esterification is conducted by heating to a temperature of from 140° to 170° C.
Claim 5
Dependent Claim
86 words
The polyetherester of claim 1, obtained by adding an alkylene oxide, to a solution of a bisphenol which is halogenated in the nucleus in said dihydric alcohol in the presence of one of the known alkoxylation catalysts at a temperature of from 80 to 180° C. until practically all the phenolic hydroxyl groups have been etherified, and then esterifying the resulting mixture of bisphenol ethers which are halogenated in the nucleus and dihydric alcohol by heating with polycarboxylic acids to a temperature of from 120°-200° C.
Claim 6
Dependent Claim
56 words
The polyetherester of claim 4, wherein said alkylene oxide is selected from the group consisting of propylene oxide and ethylene oxide, wherein the etherification is conducted at a temperature of from 110° to 140° C., wherein the esterification is conducted at a temperature of from 140° to 170° C. in the presence of an esterification catalyst.
Claim 7
Dependent Claim
47 words
The polyetherester of claim 2 which has a bromine content of from 20 to 30%, and is obtained by esterification of 1 mol of bis-β-hydroxyethyl tetrabromobisphenol with from 2 to 2.5 mol of adipic acid in the presence of from 3.0 to 3.5 mol of diethylene glycol.
Claim 8
Dependent Claim
47 words
The polyetherester of claim 2 which has a bromine content of from 20 to 30%, and is obtained by esterification of 1 mol of bis-β-hydroxyethyl tetrabromobisphenol with from 1.25 to 2.0 mol of adipic acid in the presence of from 2.5 to 3.0 mol of triethylene glycol.
Claim 9
Dependent Claim
41 words
In a process for producing a polyurethane by reacting a polyisocyanate with an active hydrogen containing material in the presence of a urethane forming catalyst, the improvement which comprises using as said active hydrogen containing material the polyetherester of claim 1.
Claim 10
Dependent Claim
40 words
In a process for producing a polyisocyanurate by polymerizing a polyisocyanate with an active hydrogen containing material in the presence of a trimerizing catalyst, the improvement which comprises using as said active hydrogen containing material the polyetherester of claim 1.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-12-04 | 1982-06-05 | 1982-12-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-12-04 | 1986-06-05 | 1986-12-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-12-04 | 1990-06-05 | 1990-12-05 | $7700.00 | Window Closed / Lapsed |