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Photographic elements having hydrophilic colloid layers containing compounds having activator precursors and hydrophobic developing agents uniformly loaded in latex polymer particles

Assignee: Eastman Kodak Co
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Filing: 1977-07-08
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Granted: 1979-01-09
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Expires: 1997-07-08
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Abstract

Abstract A photographic element is disclosed having coated on a support a hydrophilic colloid layer containing an activator precursor and loaded polymer particles of from 0.02 to 0.2 micron in average diameter. The polymer particles consist essentially of a hydrophobic polymer of which at least 2 percent by weight is comprised of ionizable repeating units, at least half being cationically ionizable, and a hydrophobic developing agent present in a weight ratio to the polymer of from about 1:4 to 3:1. Silver halide is present in the hydrophilic colloid layer or in an adjacent layer, and the activator precursor is present in a concentration of from 1 to 4 equivalent for each mole of silver halide. The photographic element is capable of being thermally processed.

Inventors

  • 👤 Tsang J. Chen
  • 👤 Donald F. McLaen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 12:44
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/42; G03C1/04; G03C1/053; G03C5/00; G03C5/26; G03C5/29; G03C5/30; Y; Y10; Y10S; Y10S430/00; Y10S430/156; Y10S430/16

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 237 words
A photographic element comprised of a support and, coated on the support, a hydrophilic colloid layer comprised of a hydrophilic colloid, and within the hydrophilic colloid, an activator precursor which is a compound of a protonated basic nitrogen-containing moiety and an acid anion, loaded polymer particles of from 0.02 to 0.2 micron in average diameter consisting essentially of a hydrophobic polymer of which at least 2 percent by weight is comprised of ionizable repeating units capable of forming hydrophilic homopolymers, at least half of said ionizable repeating units being cationically ionizable, and a hydrophobic developing agent loaded into and distributed through said particles, the weight ratio of said developing agent to said polymer being from about 1:4 to 3:1, in said hydrophilic colloid layer or in an adjacent hydrophilic colloid layer, radiation-sensitive silver halide grains, and said activator precursor being present in a concentration of from 1 to 4 equivalents for each mole of said radiation-sensitive silver halide, and wherein said ionizable repeating units of said hydrophobic polymer are cationically ionizable and are represented by the formula ##STR42## wherein, R and R 1 are independently chosen from among hydrogen, alkyl and aryl groups, L is a divalent linking group and Q + is a group of the formula ##STR43## where R 5 , R 6 and R 7 are independently chosen from the group consisting of alkyl, aryl, alkaryl and aralkyl, and X - is an anion.
Claim 2
Dependent Claim 237 words
A photographic element comprised of a support and, coated on the support, a hydrophilic colloid layer comprised of a hydrophilic colloid, and within the hydrophilic colloid, an activator precursor which is a compound of a protonated basic nitrogen-containing moiety and an acid anion, loaded polymer particles of from 0.02 to 0.2 micron in average diameter consisting essentially of a hydrophobic polymer of which at least 2 percent by weight is comprised of ionizable repeating units capable of forming hydrophilic homopolymers, at least half of said ionizable repeating units being cationically ionizable, and a hydrophobic developing agent loaded into and distributed through said particles, the weight ratio of said developing agent to said polymer being from about 1:4 to 3:1, in said hydrophilic colloid layer or in an adjacent hydrophilic colloid layer, radiation-sensitive silver halide grains, and said activator precursor being present in a concentration of from 1 to 4 equivalents for each mole of said radiation-sensitive silver halide, and wherein said ionizable repeating units of said hydrophobic polymer are cationically ionizable and are represented by the formula ##STR42## wherein, R and R 1 are independently chosen from among hydrogen, alkyl and aryl groups, L is a divalent linking group and Q + is a group of the formula ##STR43## where R 5 , R 6 and R 7 are independently chosen from the group consisting of alkyl, aryl, alkaryl and aralkyl, and X - is an anion.
Claim 3
Dependent Claim 24 words
A photograhic element according to claim 1 wherein the weight ratio of said developing agent to said polymer is from about 1:3 to 1:1.
Claim 4
Dependent Claim 21 words
A photographic element according to claim 1 wherein the loaded polymer particles are from 0.08 to 0.2 micron in average diameter.
Claim 5
Dependent Claim 13 words
A photographic element according to claim 1 wherein said hydrophilic colloid is gelatin.
Claim 6
Dependent Claim 18 words
A photographic element according to claim 1 wherein said hydrophobic developing agent is a hydrophobic reductone developing agent.
Claim 7
Dependent Claim 18 words
A photographic element according to claim 1 wherein said hydrophobic developing agent is a hydrophobic pyrazolidone developing agent.
Claim 8
Dependent Claim 18 words
A photographic element according to claim 1 wherein said hydrophobic developing agent is a hydrophobic aminophenol developing agent.
Claim 9
Dependent Claim 18 words
A photographic element according to claim 1 wherein said hydrophobic developing agent is a hydrophobic pyrroline developing agent.
Claim 10
Dependent Claim 15 words
A photographic element according to claim 1 wherein said activator precursor is an activator-stabilizer precursor.
Claim 11
Dependent Claim 47 words
A photographic element according to claim 1 wherein said activator precursor is an activator-stabilizer precursor and is represented by the formula: Q.sub.m A.sub.w wherein Q is a protonated basic nitrogen-containing moiety, A is a carboxylate anion and m and w are integers chosen to form neutral compound.
Claim 12
Dependent Claim 33 words
A photographic element according to claim 1 wherein said activator precursor is an activator-stabilizer precursor and is present in a concentration of from 1.2 to 2.0 equivalents per mole of said silver halide.
Claim 13
Dependent Claim 24 words
A photographic element according to claim 1 wherein said ionizable repeating units form from 2 to 30 percent by weight of said hydrophobic polymer.
Claim 14
Dependent Claim 24 words
A photographic element according to claim 1 wherein said ionizable repeating units form from 5 to 20 percent by weight of said hydrophobic polymer.
Claim 15
Dependent Claim 255 words
A photographic element comprised of a support and, coated on the support, a gelatino-silver halide emulsion layer comprised of from 1.2 to 2 equivalents per mole of silver halide of an activator-stabilizer precursor of the formula Q.sub.m A.sub.w wherein, Q is a protonated basic nitrogen-containing moiety, A is a carboxylate anion and m and w are integers chosen to form a neutral compound, and loaded polymer particles of from 0.08 to 0.2 micron in average diameter consisting essentially of a hydrophobic polymer of which from 5 to 20 percent by weight is comprised of ionizable repeating units, at least 50 percent of which on a mole basis are cationically ionizable repeating units of the formula ##STR44## wherein, R and R 1 are independently chosen from among hydrogen, alkyl of from 1 to 5 carbon atoms and aryl of from 6 to 10 carbon atoms, L is a divalent ##STR45## linking group where R 2 is a divalent alkylene group of from 1 to 5 carbon atoms and Q + is a group of the formula ##STR46## where R 5 , R 6 , R 7 are independently chosen from the group consisting of alkyl, aryl, alkaryl and aralkyl, where each said alkyl moiety contains from 1 to 5 carbon atoms and each said aryl moiety contains 6 to 10 carbon atoms, and X - is an anion, and a hydrophobic developing agent loaded into and distributed through said particles, the weight ratio of said developing agent to said polymer being from about 1:3 to 1:1.
Claim 16
Dependent Claim 255 words
A photographic element comprised of a support and, coated on the support, a gelatino-silver halide emulsion layer comprised of from 1.2 to 2 equivalents per mole of silver halide of an activator-stabilizer precursor of the formula Q.sub.m A.sub.w wherein, Q is a protonated basic nitrogen-containing moiety, A is a carboxylate anion and m and w are integers chosen to form a neutral compound, and loaded polymer particles of from 0.08 to 0.2 micron in average diameter consisting essentially of a hydrophobic polymer of which from 5 to 20 percent by weight is comprised of ionizable repeating units, at least 50 percent of which on a mole basis are cationically ionizable repeating units of the formula ##STR44## wherein, R and R 1 are independently chosen from among hydrogen, alkyl of from 1 to 5 carbon atoms and aryl of from 6 to 10 carbon atoms, L is a divalent ##STR45## linking group where R 2 is a divalent alkylene group of from 1 to 5 carbon atoms and Q + is a group of the formula ##STR46## where R 5 , R 6 , R 7 are independently chosen from the group consisting of alkyl, aryl, alkaryl and aralkyl, where each said alkyl moiety contains from 1 to 5 carbon atoms and each said aryl moiety contains 6 to 10 carbon atoms, and X - is an anion, and a hydrophobic developing agent loaded into and distributed through said particles, the weight ratio of said developing agent to said polymer being from about 1:3 to 1:1.
Claim 17
Dependent Claim 83 words
A photographic elmeent according to claim 14 wherein a minor portion of said ionizable repeating units are formed from a monomer of the formula ##STR47## wherein R 8 is hydrogen, chlorine or lower alkyl of from 1 to 5 carbon atoms, Q 1 is OM or an organic radical which together with the carbonyl group of the formula forms an ester or amide group terminating in a hydroxy, COOM or SO 3 M solubilizing group; and M is hydrogen, ammonium or alkali metal.
Claim 18
Dependent Claim 14 words
A photographic element according to claim 15 wherein R 8 is hydrogen or methyl.
Claim 19
Dependent Claim 25 words
A photographic element according to claim 14 wherein said cationically ionizable repeating unit is derived from a protonated ammonium ester of acrylic or methacrylic acid.
Claim 20
Dependent Claim 28 words
A photographic element according to claim 14 wherein Q is a thiazolium moiety and A is a carboxylate anion which is decarboxylatable at temperatures above about 80° C.
Claim 21
Dependent Claim 18 words
A photographic element according to claim 14 wherein Q is a thiazolium moiety and A is an alpha-sulfonylacetate.

References Cited (Backward Citations)

US2772163A Cited
US3301678A Cited
US3518088A Cited
US3531285A Cited
US3619195A Cited
US3816137A Cited
US4060420A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-01-08 1982-07-10 1983-01-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-01-08 1986-07-10 1987-01-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-01-08 1990-07-10 1991-01-09 $7700.00 Window Closed / Lapsed

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