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US4154615A Expired / Lapsed US ⏱️ 0.0 years remaining

Color diffusion transfer unit with polymeric quaternary nitrogen mordant

Assignee: Konica Minolta Inc
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Filing: 1977-06-22
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Granted: 1979-05-15
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Expires: 1997-06-22
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Abstract

Abstract A color diffusion transfer photographic unit is disclosed which contains a silver halide photosensitive element having a support and at least one silver halide emulsion layer thereon and an image receiving element having a support and an image receiving layer thereon wherein the unit contains a polymer having a first monomer which contains a tertiary nitrogen atom wherein at least 5 mole % of said first monomer is grafted and/or graft-copolymerized with a second monomer which is a vinyl monomer having a tertiary or quaternary nitrogen.

Inventors

  • 👤 Yuzuru Sato
  • 👤 Masao Asano
  • 👤 Masao Ishihara
  • 👤 Sadatugu Terada

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 17:33
CPC Classifications
G; G03; G03C; G03C8/00; G03C8/42; G03C8/52; G03C8/56; C; C08; C08F; C08F291/00; C08F291/02; Y; Y10; Y10S; Y10S430/00; Y10S430/142

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 337 words
A color diffusion transfer photographic unit containing a silver halide photosensitive element having a support and at least one silver halide emulsion layer thereon, and an image receiving element having a support and an image-receiving layer thereon, said unit comprising a polymer having a first monomer having a tertiary nitrogen atom represented by the following formulae ##STR9## wherein R 1 represents hydrogen or methyl group, R 2 and R 3 individually represent lower alkyl, phenyl or aralkyl, and R 2 and R 3 may, together, form a 5- or 6-membered heterocyclic ring with the nitrogen wherein said ring may have at least one substituent; and A represents a simple bond or a bond group comprising at least two members selected from the group consisting of hydrogen, carbon, nitrogen and oxygen; A 1 , Z 1 and Z 2 are atoms necessary to complete a 5- or 6-membered heterocyclic ring containing the nitrogen wherein said ring may have at least one substituent; at least 5 mole % of said first monomer having said tertiary nitrogen grafted and/or graft-copolymerized with a second monomer, represented by the following formulae ##STR10## wherein R 4 and R 7 individually represent hydrogen, halogen, and methyl; R 5 and R 8 individually represent lower alkyl, phenyl and aralkyl and R 5 and R 6 as well as R 8 and R 10 may cooperatively form a 5- or 6-membered heterocyclic ring containing the nitrogen wherein said ring may have at least one substituent; R 6 and R 9 individually represent lower alkyl and aralkyl; R 10 represents hydrogen, lower alkyl and aralkyl; and B and B' individually represent a single bond, or a bond group comprising at least two members selected from hydrogen, carbon, nitrogen and oxygen; B 1 , Z 3 and Z 4 , as well as B' 1 , Z 5 and Z 6 are atoms necessary to complete a 5- or 6-membered heterocyclic ring containing the nitrogen, wherein said ring may have at least one substituent; and X is anion.
Claim 2
Dependent Claim 337 words
A color diffusion transfer photographic unit containing a silver halide photosensitive element having a support and at least one silver halide emulsion layer thereon, and an image receiving element having a support and an image-receiving layer thereon, said unit comprising a polymer having a first monomer having a tertiary nitrogen atom represented by the following formulae ##STR9## wherein R 1 represents hydrogen or methyl group, R 2 and R 3 individually represent lower alkyl, phenyl or aralkyl, and R 2 and R 3 may, together, form a 5- or 6-membered heterocyclic ring with the nitrogen wherein said ring may have at least one substituent; and A represents a simple bond or a bond group comprising at least two members selected from the group consisting of hydrogen, carbon, nitrogen and oxygen; A 1 , Z 1 and Z 2 are atoms necessary to complete a 5- or 6-membered heterocyclic ring containing the nitrogen wherein said ring may have at least one substituent; at least 5 mole % of said first monomer having said tertiary nitrogen grafted and/or graft-copolymerized with a second monomer, represented by the following formulae ##STR10## wherein R 4 and R 7 individually represent hydrogen, halogen, and methyl; R 5 and R 8 individually represent lower alkyl, phenyl and aralkyl and R 5 and R 6 as well as R 8 and R 10 may cooperatively form a 5- or 6-membered heterocyclic ring containing the nitrogen wherein said ring may have at least one substituent; R 6 and R 9 individually represent lower alkyl and aralkyl; R 10 represents hydrogen, lower alkyl and aralkyl; and B and B' individually represent a single bond, or a bond group comprising at least two members selected from hydrogen, carbon, nitrogen and oxygen; B 1 , Z 3 and Z 4 , as well as B' 1 , Z 5 and Z 6 are atoms necessary to complete a 5- or 6-membered heterocyclic ring containing the nitrogen, wherein said ring may have at least one substituent; and X is anion.
Claim 3
Dependent Claim 26 words
The color diffusion transfer photographic unit as claimed in claim 1 wherein the polymer has been graft-copolymerized with the second monomer having a tertiary nitrogen atom.
Claim 4
Dependent Claim 32 words
The color diffusion transfer photographic unit as claimed in claim 1 wherein the polymer has been graft-copolymerized with said second monomer having quatenary nitrogen at the tertiary nitrogen of said first monomer.
Claim 5
Dependent Claim 34 words
The color diffusion transfer photographic unit as claimed in claim 1 wherein the polymer has been copolymerized with a mixture of said second monomer containing tertiary nitrogen and said second monomer containing quaternary nitrogen.
Claim 6
Dependent Claim 20 words
A color diffusion transfer photographic unit as claimed in claim 1 wherein the polymer is present in the image-receiving element.
Claim 7
Dependent Claim 22 words
A color diffusion transfer photographic unit as claimed in claim 5 wherein the image-receiving element comprises an image-receiving layer containing said polymer.
Claim 8
Dependent Claim 21 words
A color diffusion transfer photographic unit as claimed in claim 6 wherein said image-receiving layer has a dry thickness of 3-10μ.
Claim 9
Dependent Claim 25 words
The color diffusion transfer photographic unit as claimed in claim 7 wherein the amount of the polymer in the image-receiving layer is 10-100% by weight.
Claim 10
Dependent Claim 29 words
The color diffusion transfer photographic unit as claimed in claim 6 wherein the unit further comprises said image-receiving element having thereon said photographic element having therein said processing sheet.
Claim 11
Dependent Claim 32 words
A color diffusion transfer photographic unit as claimed in claim 1 wherein the unit further comprises the image-receiving element having thereon the photographic element having thereon a processing sheet containing said polymer.
Claim 12
Dependent Claim 22 words
A color diffusion transfer photographic unit as claimed in claim 10 wherein the processing sheet comprises a scavenger layer containing said polymer.
Claim 13
Dependent Claim 21 words
The color diffusion transfer photographic unit as claimed in claim 11 wherein said scavenger layer has a dry thickness of 0.5-10μ.
Claim 14
Dependent Claim 25 words
The color diffusion transfer photographic unit as claimed in claim 12 wherein the amount of the polymer in the scavenger layer is 10-100% by weight.

References Cited (Backward Citations)

US3756814A Cited
US3930864A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-05-14 1982-11-13 1983-05-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-05-14 1986-11-13 1987-05-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-05-14 1990-11-13 1991-05-15 $7700.00 Window Closed / Lapsed

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