Patent US4154812A successfully refreshed from Google Patents.
US4154812A
Expired / Lapsed
US
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Process for preparing alumina
Assignee: WR Grace and Co Conn
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Filing: 1977-03-25
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Granted: 1979-05-15
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Expires: 1997-03-25
Abstract
Abstract An alumina composition comprising a microcrystalline boehmite-pseudoboehmite intermediate having from about 70 to about 85 weight percent of the total amount of Al2O3 present in crystalline form. The composition is prepared by adding aluminum sulfate and sodium aluminate solutions to a mixture of water and aluminum sulfate solution to precipitate alumina and adjusting the pH to a pH higher than the precipitation pH. The reactant concentrations, and rates of addition, temperatures, and pH's in the precipitation are specifically controlled to form the boehmite-pseudoboehmite intermediate.
Inventors
- 👤 Moises G. Sanchez
- 👤 Norman R. Laine
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 05:30
CPC Classifications
B; B01; B01J; B01J21/00; B01J21/02; B01J21/04; B01J35/00; B01J35/60; C; C01; C01F; C01F7/00; C01F7/02; C01F7/021; C01F7/34; B01J35/61; B01J35/615; B01J35/63; B01J35/635; B01J35/64; B01J35/647; B01J35/66; B01J35/67; C01P; C01P2002/00; C01P2002/60; C01P2004/00; C01P2004/30; C01P2004/32; C01P2004/60; C01P2004/61; C01P2006/00; C01P2006/10; C01P2006/11; C01P2006/12; C01P2006/14; C01P2006/16; C01P2006/17; C01P2006/21; C01P2006/22
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
220 words
A process for preparing alumina comprising (a) adding an aqueous aluminum sulfate solution having an Al 2 O 3 concentration of about 5 to 9 weight percent and a temperature of about 130° to about 160° F. to water at a temperature of about 140° to about 170° F., said solution being added in an amount sufficient to adjust the pH of the mixture to about 2 to about 5; (b) simultaneously adding to the mixture a further amount of the aluminum sulfate solution having an Al 2 O 3 concentration of about 5 to about 9 weight percent and a temperature of about 130° to about 160° F. and an aqueous sodium aluminate solution having an Al 2 O 3 concentration of about 18 to about 22 weight percent and a temperature of about 130° to about 160° F. to precipitate alumina and form an alumina slurry; (c) maintaining the pH of the slurry from about 7 to about 8, the temperature of the slurry from about 140° to about 180° F., and a rate of addition of the aluminum sulfate solution and of the sodium aluminate solution during the precipitation to form a boehmite-pseudoboehmite intermediate; (d) adjusting the pH of the slurry to about 9.5 to about 10.5; and (e) filtering the slurry and washing the filter cake.
Claim 2
Dependent Claim
220 words
A process for preparing alumina comprising (a) adding an aqueous aluminum sulfate solution having an Al 2 O 3 concentration of about 5 to 9 weight percent and a temperature of about 130° to about 160° F. to water at a temperature of about 140° to about 170° F., said solution being added in an amount sufficient to adjust the pH of the mixture to about 2 to about 5; (b) simultaneously adding to the mixture a further amount of the aluminum sulfate solution having an Al 2 O 3 concentration of about 5 to about 9 weight percent and a temperature of about 130° to about 160° F. and an aqueous sodium aluminate solution having an Al 2 O 3 concentration of about 18 to about 22 weight percent and a temperature of about 130° to about 160° F. to precipitate alumina and form an alumina slurry; (c) maintaining the pH of the slurry from about 7 to about 8, the temperature of the slurry from about 140° to about 180° F., and a rate of addition of the aluminum sulfate solution and of the sodium aluminate solution during the precipitation to form a boehmite-pseudoboehmite intermediate; (d) adjusting the pH of the slurry to about 9.5 to about 10.5; and (e) filtering the slurry and washing the filter cake.
Claim 3
Dependent Claim
27 words
The process of claim 1 in which the aluminum sulfate solution has a SO 4 .sup.═ /Al 2 O 3 molar ratio in excess of about 1.2.
Claim 4
Dependent Claim
32 words
The process of claim 1 in which the amount of aluminum sulfate solution added in step (a) is sufficient to adjust the pH of the mixture to about 3 to about 4.
Claim 5
Dependent Claim
19 words
The process of claim 3 in which the pH is adjusted in step (d) by adding sodium aluminate solution.
Claim 6
Dependent Claim
47 words
The process of claim 4 in which the amount of sodium aluminate solution added in step (d) is sufficient to adjust the pH of the mixture from about 9.6 to about 10.0 and the mixture is aged at this pH for about 6 to about 12 minutes.
Claim 7
Dependent Claim
36 words
The process of claim 1 wherein step (b) is conducted in from about 48 to about 52 minutes and the temperature of the slurry is maintained in step (c) from about 155° to about 165° F.
Claim 8
Dependent Claim
20 words
The process of claim 1 further comprising the step of (f) reslurrying the filter cake and drying the resulting slurry.
Claim 9
Dependent Claim
28 words
The process of claim 7 in which the slurry is spray dried and is acidified to a pH of about 7 or lower before it is spray dried.
Claim 10
Dependent Claim
22 words
The process of claim 7 in which the dried product has a water content of about 18 to about 33 weight percent.
Claim 11
Dependent Claim
22 words
The process of claim 9 in which the dried product has a water content of about 20 to about 28 weight percent.
Claim 12
Dependent Claim
76 words
The process of claim 1 wherein the amount of aluminum sulfate solution added in step (a) is sufficient to adjust the pH of the mixture to about 3.0 to about 4.0, step (b) is conducted in about 48 to about 52 minutes, the temperature of the slurry is maintained in step (c) from about 155° to about 165° F., and the pH of the slurry is adjusted in step (d) to about 9.6 to about 10.5.
Claim 13
Dependent Claim
17 words
The process of claim 1 wherein step (b) is conducted in about 15 to about 70 minutes.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-05-14 | 1982-11-13 | 1983-05-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-05-14 | 1986-11-13 | 1987-05-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-05-14 | 1990-11-13 | 1991-05-15 | $7700.00 | Window Closed / Lapsed |