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Adhesive-coating glass fibers and the resulting coated fibers

Assignee: Rhone Poulenc Textile SA
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Filing: 1977-08-02
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Granted: 1979-06-05
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Expires: 1997-08-02
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Abstract

Abstract A new process of adhesive-coating which makes it possible to increase the adhesion of glass fibers to rubbers based on natural rubber. The fibers are impregnated by means of a composition consisting or consisting essentially of a solution containing a resorcinol/formaldehyde resin, a natural latex, a latex based on vinylpyridine and, preferably, ammonium hydroxide, and while passing through the coating bath they are subjected to vibratory movements communicated directly to the fibers. The glass fibers adhesive-coated in this way are of great interest to the rubber industry in the manufacture of tires, conveyors, conveyor belts, hoses and the like.

Inventors

  • 👤 Paul Bourrain
  • 👤 Pierre Giroud

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 17:00
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/04; C08J5/06; C08J5/08; C03; C03C; C03C25/00; C03C25/10; C03C25/24; C03C25/26; C03C25/27; C09; C09J; C09J109/00; C09J109/10; C08J2321/00; C08L; C08L2666/00; C08L2666/02; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2933; Y10T428/294; Y10T428/2956; Y10T428/2964

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 185 words
A process for adhesive-coating glass fibers, characterised in that the glass fibers are impregnated by means of a composition consisting essentially of a solution A produced from: ______________________________________ softened water 433 parts by weight resorcinol 36.6 parts by weight sodium hydroxide 1 to 3.50 parts by weight 40% strength formaldehyde 21.3 to 50.0 parts by weight ______________________________________ and a latex solution B consisting essentially of: ______________________________________ softened water 0 to 292 parts by weight 60% strength natural latex 213 to 428 parts by weight 40% strength latex based on vinylpyridine 640 to 960 parts by weight ______________________________________ in which: the total weight of solids relative to the bath varies between about 30 and 35%; the formaldehyde/resorcinol molar ratio varies between 0.85 and 2; the dry weight of latex relative to the resorcinol/formaldehyde resin varies between about 8.5/1 and 11/1; the final pH is 9.6±0.2; and the proportion by weight of dry resorcinol/formaldehyde resin relative to the amount of all the products varies between 10 and 12% and in that the fibers passing through the bath are subjected to vibratory movements communicated directly to the fibers.
Claim 2
Dependent Claim 185 words
A process for adhesive-coating glass fibers, characterised in that the glass fibers are impregnated by means of a composition consisting essentially of a solution A produced from: ______________________________________ softened water 433 parts by weight resorcinol 36.6 parts by weight sodium hydroxide 1 to 3.50 parts by weight 40% strength formaldehyde 21.3 to 50.0 parts by weight ______________________________________ and a latex solution B consisting essentially of: ______________________________________ softened water 0 to 292 parts by weight 60% strength natural latex 213 to 428 parts by weight 40% strength latex based on vinylpyridine 640 to 960 parts by weight ______________________________________ in which: the total weight of solids relative to the bath varies between about 30 and 35%; the formaldehyde/resorcinol molar ratio varies between 0.85 and 2; the dry weight of latex relative to the resorcinol/formaldehyde resin varies between about 8.5/1 and 11/1; the final pH is 9.6±0.2; and the proportion by weight of dry resorcinol/formaldehyde resin relative to the amount of all the products varies between 10 and 12% and in that the fibers passing through the bath are subjected to vibratory movements communicated directly to the fibers.
Claim 3
Dependent Claim 100 words
A process for adhesive-coating for glass fibers as defined in claim 1, wherein the adhesive-coating composition consists essentially of a resin A composed of: ______________________________________ softened water 433 parts by weight resorcinol 36.6 parts by weight sodium hydroxide 1 to 3.50 parts by weight 40% strength formaldehyde 21.3 to 50.0 parts by weight ______________________________________ and a latex solution C consisting essentially of: ______________________________________ softened water 0 to 292 parts by weight 60% strength natural latex 213 to 428 parts by weight ammonium hydroxide 2.6 to 10.5 parts by weight latex based on vinylpyridine 640 to 960 parts by weight. ______________________________________
Claim 4
Dependent Claim 14 words
Glass fibers adhesive-coated by means of an adhesive-coating composition as defined in claim 1.
Claim 5
Dependent Claim 14 words
Glass fibers adhesive-coated by means of an adhesive-coating composition as defined in claim 2.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-06-04 1982-12-04 1983-06-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-06-04 1986-12-04 1987-06-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-06-04 1990-12-04 1991-06-05 $7700.00 Window Closed / Lapsed

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