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Copolymer blends

Assignee: Standard Oil Co
•
Filing: 1977-08-18
•
Granted: 1979-07-03
•
Expires: 1997-08-18
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Abstract

Abstract Blends of a copolymer of methyl methacrylate and styrene with an acrylonitrile-styrene copolymer have improved optical, mechanical and gas barrier properties as well as improved processability.

Inventors

  • 👤 Irving Rosen

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 22:50
CPC Classifications
C; C08; C08L; C08L33/00; C08L33/18; C08L33/20; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/14; C08L33/04; C08L33/06; C08L33/10; C08L33/12; C08L51/00; C08L51/04; C08L55/00; C08L55/02; C08L25/12

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 224 words
A blend of from 2 to 60% by weight of I. a copolymer of from about 50 to 70% by weight of methyl methacrylate and correspondingly from about 50 to 30% by weight of styrene, and from 98 to 40% by weight of Ii. a copolymer prepared by the polymerization of 100 parts by weight of (A) more than 50% by weight of at least one nitrile having the structure ##STR5## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, (B) less than 50% by weight based on the combined weights of (A) plus (B) of styrene, in the presence of from 0 to 40 parts by weight of (C) a rubbery polymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and optionally at least one comonomer selected from the group consisting of styrene, a nitrile monomer having the structure ##STR6## wherein R has the foregoing designation, and an ester having the structure ##STR7## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, said rubbery polymer containing from 50 to 100% by weight of polymerized conjugated diene and from 0 to 50% by weight of comonomer.
Claim 2
Dependent Claim 224 words
A blend of from 2 to 60% by weight of I. a copolymer of from about 50 to 70% by weight of methyl methacrylate and correspondingly from about 50 to 30% by weight of styrene, and from 98 to 40% by weight of Ii. a copolymer prepared by the polymerization of 100 parts by weight of (A) more than 50% by weight of at least one nitrile having the structure ##STR5## wherein R is hydrogen, a lower alkyl group having from 1 to 4 carbon atoms, or a halogen, (B) less than 50% by weight based on the combined weights of (A) plus (B) of styrene, in the presence of from 0 to 40 parts by weight of (C) a rubbery polymer of a conjugated diene monomer selected from the group consisting of butadiene and isoprene and optionally at least one comonomer selected from the group consisting of styrene, a nitrile monomer having the structure ##STR6## wherein R has the foregoing designation, and an ester having the structure ##STR7## wherein R 1 is hydrogen, an alkyl group having from 1 to 4 carbon atoms, or a halogen, and R 2 is an alkyl group having from 1 to 6 carbon atoms, said rubbery polymer containing from 50 to 100% by weight of polymerized conjugated diene and from 0 to 50% by weight of comonomer.
Claim 3
Dependent Claim 9 words
The blend of claim 1 wherein II(A) is acrylonitrile.
Claim 4
Dependent Claim 11 words
The blend of claim 2 wherein II(C) is a butadiene-styrene rubber.
Claim 5
Dependent Claim 27 words
The blend of claim 1 wherein II(A) is present in from 70 to 90% by weight and II(B) is present in from 10 to 30% by weight.
Claim 6
Dependent Claim 9 words
The blend of claim 4 wherein II(A) is acrylonitrile.
Claim 7
Dependent Claim 11 words
The blend of claim 5 wherein II(C) is a butadiene-styrene rubber.

References Cited (Backward Citations)

US3988391A Cited
US4025581A Cited
US3985827A Cited
US3917748A Cited
US3922321A Cited
US4021509A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-07-02 1983-01-01 1983-07-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-07-02 1987-01-01 1987-07-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-07-02 1991-01-01 1991-07-03 $7700.00 Window Closed / Lapsed

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