Patent US4160049A successfully refreshed from Google Patents.
US4160049A
Expired / Lapsed
US
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Bright electroless plating process producing two-layer nickel coatings on dielectric substrates
Assignee: MacDermid Enthone Inc
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Filing: 1977-11-07
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Granted: 1979-07-03
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Expires: 1997-11-07
Abstract
Abstract An adherent, bright metallic nickel coating is applied to the surface of a plastic or other dielectric part (or to a metal part) by an electroless process comprising, after suitable pretreatment of said surface, the deposition of a primary electroless nickel possessing special properties followed by a secondary electroless nickel of bright appearance with complete elimination of any subsequent electroplating process usually required to achieve this brightness. The nickel coating may be limited to selected surface areas of a coated part by mechanically removing portions of the primary coat prior to immersion of the part in a secondary electroless nickel bath.
Inventors
- 👤 Harold Narcus
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 10:46
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/31; C23C18/32; C23C18/34; C23C18/36; H; H05; H05K; H05K3/00; H05K3/22; H05K3/24; H05K3/244
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
148 words
Method of producing adherent, decorative, two-layer nickel coatings on dielectric substrates comprising, activating the substrate surface, electrolessly depositing a first dull nickel alloy layer thereon comprising 6-12% phosphorus, balance essentially nickel, in a first electroless coating bath, the layer being dense and levelled, and subsequently producing a second nickel-phosphorus alloy layer of self building brightness over the first layer by electroless coating in a second, different electroless coating bath, the second bath also producing a 6-12% phosphorus, balance essentially nickel, composition, and wherein the coating rates in both the first and second baths are controlled to be 0.0006"- 0.0008" per hour with the first layer coating step being long enough to produce an adherent 0.000010" - 0.00015" thickness (i.e., 2500-37,500 Angstroms) first layer and the second layer coating being carried out long enough to produce a second coating layer which is even thicker than the first coating layer.
Claim 2
Dependent Claim
148 words
Method of producing adherent, decorative, two-layer nickel coatings on dielectric substrates comprising, activating the substrate surface, electrolessly depositing a first dull nickel alloy layer thereon comprising 6-12% phosphorus, balance essentially nickel, in a first electroless coating bath, the layer being dense and levelled, and subsequently producing a second nickel-phosphorus alloy layer of self building brightness over the first layer by electroless coating in a second, different electroless coating bath, the second bath also producing a 6-12% phosphorus, balance essentially nickel, composition, and wherein the coating rates in both the first and second baths are controlled to be 0.0006"- 0.0008" per hour with the first layer coating step being long enough to produce an adherent 0.000010" - 0.00015" thickness (i.e., 2500-37,500 Angstroms) first layer and the second layer coating being carried out long enough to produce a second coating layer which is even thicker than the first coating layer.
Claim 3
Dependent Claim
33 words
The method of claim 1 wherein the two coating baths contain MH 2 OP 2 . H 2 O where M is selected from the class consisting of alkali metal and ammonium ions.
Claim 4
Dependent Claim
18 words
The method of claim 1 wherein both the primary and secondary baths have the same nickel compound source.
Claim 5
Dependent Claim
13 words
The method of claim 3 wherein nickel sulfate comprises said common nickel source.
Claim 6
Dependent Claim
87 words
Method of nickel coating in accordance with claim 1 comprising, etching and activating the substrate surfaces in a single step, acceleration treatment of the substrate surfaces, immersing of the substrates in a primary nickel solution maintained at 25°-30° C. and pH of 8.5-9.0 for 5-15 minutes to produce a foundation nickel coating therein, and then immersing the substrate without rinsing or neutralization, or taking into a secondary, different, nickel solution maintained at 70°-90° C. and 4.5-5.5 pH to produce a self building brightening of the substrate surfaces.
Claim 7
Dependent Claim
24 words
Method of nickel coating in accordance with claim 5 wherein the secondary nickel treatment is supplemented by deposition of at least one additional metal.
Claim 8
Dependent Claim
30 words
Method of nickel coating in accordance with claim 5 wherein a portion of the foundation coating is removed prior to the said second immersion of the substrates into nickel solution.
Claim 9
Dependent Claim
43 words
Method in accordance with claim 5 wherein said primary nickel solution comprises nickel sulfate and sodium hypophosphite and a basic mixture including glacial acetic acid and ammonium hydroxide and said secondary nickel solution comprises nickel sulphate, sodium hypophosphite and a weak acid mixture.
Claim 10
Dependent Claim
62 words
Nickel coating method in accordance with claim 1 wherein the second bath is carried out at lower temperature than the first bath, wherein the coating steps are controlled so that the second layer is thicker than the first coating layer and wherein the pH of said first bath is controlled to be 8.0-10.0 and that of the second bath to be 4.0-6.0.
Claim 11
Dependent Claim
31 words
The method of claim 9 wherein the first bath is maintained at under 50° C. and the second bath above 50° C. and substantially above the temperature of the first bath.
Claim 12
Dependent Claim
45 words
Nickel coating method in accordance with claim 1 wherein selected area portions of the first coating layer are removed by machining prior to exposure of the first-layer-coated substrate to the second bath wherey the second coating layer is not produced in the machined surface areas.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1982-07-02 | 1983-01-01 | 1983-07-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1986-07-02 | 1987-01-01 | 1987-07-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1990-07-02 | 1991-01-01 | 1991-07-03 | $7700.00 | Window Closed / Lapsed |