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Fabric-backed teleblock copolymer composition with dulled surface useful in footwear uppers

Assignee: Phillips Petroleum Co
•
Filing: 1978-02-21
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Granted: 1979-09-18
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Expires: 1998-02-21
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Abstract

Abstract A laminate in which a fabric backing is adhered to a composition containing a radial teleblock copolymer having blocks of poly(conjugated diene) and poly(monovinylaromatic) and sufficient surface dulling agent to provide a suede-like surface. A laminate as described having high air permeability and suede-like surface is used as material for uppers of shoes.

Inventors

  • 👤 Roy W. Siedenstrang
  • 👤 Richard E. Elliott

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 06:31
CPC Classifications
B; B32; B32B; B32B25/00; B32B25/10; C; C09; C09J; C09J153/00; C09J153/02; D; D06; D06N; D06N3/00; D06N3/04; D06N3/10; B32B2307/00; B32B2307/40; B32B2307/408; B32B2307/70; B32B2307/724; B32B2437/00; B32B2437/02; Y; Y10; Y10S; Y10S525/00; Y10S525/901; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31725; Y10T428/3175; Y10T428/31786; Y10T428/31855; Y10T442/00; Y10T442/30; Y10T442/3854; Y10T442/387

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 88 words
A laminate comprising a composition adhered to a fabric backing said composition comprising: (a) a radial teleblock copolymer of the formula (AB) n Y wherein A represents a block of poly(monovinylaromatic), B represents a block of poly(conjugated diene), Y represents a residue of a polyfunctional coupling agent or polyfunctional initiator, and n is an integer having a value of 3 or more; and (b) a surface-dulling agent chosen from the group consisting of finely divided cellulosic materials, finely divided textile fibers, finely divided hydrocarbon polymers, and blowing agents.
Claim 2
Dependent Claim 88 words
A laminate comprising a composition adhered to a fabric backing said composition comprising: (a) a radial teleblock copolymer of the formula (AB) n Y wherein A represents a block of poly(monovinylaromatic), B represents a block of poly(conjugated diene), Y represents a residue of a polyfunctional coupling agent or polyfunctional initiator, and n is an integer having a value of 3 or more; and (b) a surface-dulling agent chosen from the group consisting of finely divided cellulosic materials, finely divided textile fibers, finely divided hydrocarbon polymers, and blowing agents.
Claim 3
Dependent Claim 48 words
A laminate of claim 1 wherein monomers suitable in the preparation of the A blocks are chosen from among styrene, 3-methylstyrene, 4-n-propylstyrene, 1-vinylnaphthalene, and 2-vinylnaphthalene, and monomers suitable in the preparation of the B blocks are chosen from the group consisting of 1,3-butadiene, isoprene, 1,3-pentadiene, 2,4-hexadiene, and 3-ethyl-1,3-pentadiene.
Claim 4
Dependent Claim 42 words
A laminate of claim 2 wherein the dulling agents are chosen from the group consisting of cotton floc, linen fibers, wood flour, synthetic fibers, high density polyethylene, low density polyethylene, crystalline polypropylene, ethylene-propylene copolymers, 2,2'-azobis(2-methylpropionitrile), N,N'-dinitrosopentamethyltetraamine, p,p' -oxybis(benzenesulfonyl hydrazide), urea, and azodicarbonamide.
Claim 5
Dependent Claim 27 words
A laminate of claim 1 also containing compatible additives chosen from the group consisting of plasticizers, extender oils, pigments, reinforcing agents, stabilizers, processing aids, and curing agents.
Claim 6
Dependent Claim 31 words
A laminate of claim 1 in which the fabric backing is chosen from the group consisting of woven and non-woven fabrics made from cotton, rayon, polyamides, polyesters, polyolefins, and mixtures thereof.
Claim 7
Dependent Claim 16 words
A laminate of claim 1 wherein the polymeric composition is thermally bonded to the fabric. poly(monovinylaromatic),
Claim 8
Dependent Claim 17 words
A laminate of claim 1 wherein the polymeric composition is adhered to the fabric with an adhesive.
Claim 9
Dependent Claim 10 words
Uppers for shoes prepared from a laminate of claim 1.
Claim 10
Dependent Claim 9 words
Leather-substitute fabric prepared from a laminate of claim 1.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1982-09-17 1983-03-19 1983-09-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1986-09-17 1987-03-19 1987-09-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1990-09-17 1991-03-19 1991-09-18 $7700.00 Window Closed / Lapsed

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