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Hair conditioning composition and method of using the same

Assignee: L'Oréal SA
•
Filing: 1978-02-27
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Granted: 1980-05-06
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Expires: 1998-02-27
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Abstract

Abstract A cosmetic composition for the hair comprises in combination at least one crosslinked polyamino-amide and at least one cationic polymer having recurring units of the formula <IMAGE> wherein R3 and R4 each independently represent alkyl having 1-3 carbon atoms, R1 and R2 each independently represent alkyl having 1-3 carbon atoms or hydroxy alkyl having 1-3 carbon atoms, or when R2=R4=CH3 and R1=R3, R1 and R3 can represent alkyl having 4-8 carbon atoms, or when R2=R4=R1=CH3, R3 can represent benzyl, cyclohexyl or alkyl having 4-12 carbon atoms, X(-) is an anion, A and B each independently represent linear or branched alkylene having 2-20 carbon atoms in the chain, or A represents -(CH2)n-Z-(CH2)n-, -CH2-C6H4-CH2- or -CH2-CH(OH)-CH2-, n being 2 or 3 and Z representing -O- or -NH-CO-NH-.

Inventors

  • 👤 Jean-Francois Grollier
  • 👤 Chantal Fourcadier

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 19:13
CPC Classifications
A; A61; A61Q; A61Q5/00; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/73; A61K8/731; A61K8/81; A61K8/817; A61K8/8182; A61K8/84; A61K8/88; A61K2800/00; A61K2800/40; A61K2800/54; A61K2800/542; A61K2800/5426; A61K2800/59; A61K2800/594; A61Q5/02; A61Q5/06; A61Q5/065; A61Q5/10; Y; Y10; Y10S; Y10S424/00; Y10S424/02

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 276 words
A cosmetic composition in lotion, cream, gel or emulsion form for conditioning the hair comprising (1) in combination at least one crosslinked polyaminoamide and at least one cationic polymer having recurring units of the formula ##STR14## wherein R 3 and R 4 each independently represent alkyl having 1-3 carbon atoms, R 1 and R 2 each independently represent alkyl having 1-3 carbon atoms or hydroxyalkyl having 1-3 carbon atoms, or when R 2 =R 4 =CH 3 and R 1 =R 3 , R 1 and R 3 can represent alkyl having 4-8 carbon atoms, or when R 2 =R 4 =R 1 =CH 3 , R 3 can represent benzyl, cyclohexyl or alkyl having 4-12 carbon atoms, A and B, each independently, represent linear or branched alkylene having 2-20 carbon atoms in the chain, --(CH 2 ) n --(CH 2 ) n --, --CH 2 --C 6 H 4 --CH 2 -- or --CH 2 --CH(OH)--CH 2 --, n being a whole number equal to 2 or 3, X.sup.⊖ is an anion and Z represents either --O-- or --NH--CO--NH--, wherein said crosslinked polyamino-amide is present in an amount of 0.1 to 5 weight percent and said quaternized polymer is present in an amount of 0.1 to 10 weight percent, based on the total weight of said composition, and (2) an effective amount of at least one of (i)-(iv), defined below, to provide said lotion, cream, gel or emulsion: (i) water, alcohol or mixtures thereof; (ii) soap or C 12 -C 18 natural or synthetic alcohols with emulsifiers; (iii) thickening agent; or (iv) mixtures of oils, waxes, or both with fatty alcohols and polyethoxylated fatty alcohols.
Claim 2
Dependent Claim 276 words
A cosmetic composition in lotion, cream, gel or emulsion form for conditioning the hair comprising (1) in combination at least one crosslinked polyaminoamide and at least one cationic polymer having recurring units of the formula ##STR14## wherein R 3 and R 4 each independently represent alkyl having 1-3 carbon atoms, R 1 and R 2 each independently represent alkyl having 1-3 carbon atoms or hydroxyalkyl having 1-3 carbon atoms, or when R 2 =R 4 =CH 3 and R 1 =R 3 , R 1 and R 3 can represent alkyl having 4-8 carbon atoms, or when R 2 =R 4 =R 1 =CH 3 , R 3 can represent benzyl, cyclohexyl or alkyl having 4-12 carbon atoms, A and B, each independently, represent linear or branched alkylene having 2-20 carbon atoms in the chain, --(CH 2 ) n --(CH 2 ) n --, --CH 2 --C 6 H 4 --CH 2 -- or --CH 2 --CH(OH)--CH 2 --, n being a whole number equal to 2 or 3, X.sup.⊖ is an anion and Z represents either --O-- or --NH--CO--NH--, wherein said crosslinked polyamino-amide is present in an amount of 0.1 to 5 weight percent and said quaternized polymer is present in an amount of 0.1 to 10 weight percent, based on the total weight of said composition, and (2) an effective amount of at least one of (i)-(iv), defined below, to provide said lotion, cream, gel or emulsion: (i) water, alcohol or mixtures thereof; (ii) soap or C 12 -C 18 natural or synthetic alcohols with emulsifiers; (iii) thickening agent; or (iv) mixtures of oils, waxes, or both with fatty alcohols and polyethoxylated fatty alcohols.
Claim 3
Dependent Claim 26 words
The composition of claim 1 wherein the crosslinked polyamino-amide is obtained by crosslinking a polyamino-amide resulting from the polycondensation of an acid derivative on a polyamine.
Claim 4
Dependent Claim 34 words
The composition of claim 2 wherein the acid derivative is selected from the group consisting of organic dicarboxylic acids, ethylenically unsaturated aliphatic mono- and di-carboxylic acids, the esters of said acids and mixtures thereof.
Claim 5
Dependent Claim 14 words
The composition of claim 3 wherein said organic dicarboxylic acid has 3-10 carbon atoms.
Claim 6
Dependent Claim 30 words
The composition of claim 4 wherein said organic dicarboxylic acid is selected from the group consisting of adipic acid, 2,2,4-trimethyl adipic acid, 2,4,4-trimethyl adipic acid, diglycolic acid and terephthalic acid.
Claim 7
Dependent Claim 28 words
The composition of claim 3 wherein said ethylenically unsaturated aliphatic mono- or di-carboxylic acid is selected from the group consisting of acrylic acid, methacrylic acid and itaconic acid.
Claim 8
Dependent Claim 26 words
The composition of claim 2 wherein said polyamino-amide is obtained from a polyamine which is a polyalkylene polyamine having both bis-primary and mono- or di-secondary amines.
Claim 9
Dependent Claim 22 words
The composition of claim 7 wherein said polyamine is selected from the group consisting of diethylenetriamine, dipropylenetriamine, triethylene tetramine and mixtures thereof.
Claim 10
Dependent Claim 53 words
The composition of claim 7 wherein the poly-condensation is carried out on a mixture of said polyalkylene polyamines having both bis-primary and mono- or di-secondary amines with a second polyamine, at a rate of 0 to 40 mole percent of the said second polyamine, said second polyamine being a bis-primary or bis-secondary amine.
Claim 11
Dependent Claim 21 words
The composition of claim 9 wherein said second polyamine is selected from the group consisting of ethylenediamine, hexamethylene diamine and piperazine.
Claim 12
Dependent Claim 63 words
The composition of claim 1 wherein said polyamino-amide is crosslinked by a crosslinking agent selected from the group consisting of: (a) epihalohydrin, diepoxide, dianhydride, unsaturated anhydride, bis-unsaturated derivative, bis-halohydrin, bis-azetidinium, bis-haloacyl derivative of a diamine and alkyl bis-halide; (b) oligomer obtained from the crosslinking agent in (a); (c) quaternization product of the crosslinking agent in (a) and (b) having alkylatable tertiary amine groups.
Claim 13
Dependent Claim 25 words
The composition of claim 11 wherein said crosslinked polyamino-amide is obtained with 0.025 to 0.35 molecule of crosslinking agent per amine group of said polyamino-amide.
Claim 14
Dependent Claim 25 words
The composition of claim 12 wherein said crosslinked polyamino-amide is obtained with less than 0.2 molecule of crosslinking agent per amine group of said polyamino-amide.
Claim 15
Dependent Claim 180 words
The composition of claim 1 wherein said polyamino-amide is crosslinked by a crosslinking agent selected from the group consisting of: (1) epichlorohydrin, (2) diglycidyl ether, (3) N,N'-bis-epoxypropyl piperazine, (4) the dianhydride of butanetetracarboxylic acid, (5) the dianhydride of pyromellic acid, (6) divinyl sulfone, (7) methylene bis-acrylamide, (8) N,N'-bis-epoxypropyl piperazine quaternized with 1-2 moles of dimethyl sulfate, (9) piperazine bis-acrylamide, (10) bis-unsaturated oligomer obtained by the reaction of an excess of piperazine bis-acrylamide on piperazine, (11) a bis-halohydrin oligomer obtained by the reaction of excess epichlorohydrin on piperazine, (12) the oligomer of (11) quaternized with dimethyl sulfate, (13)1,3-bis-piperazinyl-2-propanol quaternized with epichlorohydrin, (14) piperazine bis-chloracetamide, (15) piperazine bis omega-bromo-undecanamide, (16) a bifunctional alkylating agent of the formula ##STR15## wherein x 1 represents a whole number between 0 and 7, A 1 represents ##STR16## where R' 3 represents Cl or Br, R' 1 and R' 2 each independently represent alkyl or hydroxyalkyl having 1-4 carbon atoms, and B 1 represent alkylene having 2-6 carbon atoms, ##STR17## where y 1 is a whole number between 1 4 , and (17) bis-epoxypropyl dimethyl ammonium bromide.
Claim 16
Dependent Claim 11 words
The composition of claim 1 in the form of a lotion.
Claim 17
Dependent Claim 22 words
The composition of claim 15 wherein said lotion contains a mixture of water and alcohol and said alcohol is ethanol or isopropanol.
Claim 18
Dependent Claim 16 words
The composition of claim 1 in the form of a cream, a gel or an emulsion
Claim 19
Dependent Claim 32 words
The composition of claim 1 which also contains from 0.2 to 2 weight percent of a phosphoric ester of a C 12 -C 18 saturated or unsaturated fatty alcohol, oxyethylenated or not.
Claim 20
Dependent Claim 20 words
A process for conditioning the hair comprising applying to said hair an effective amount of the composition of claim 1.

References Cited (Backward Citations)

US2271378A Cited
US2882185A Cited
US2926154A Cited
US2926116A Cited
GB1035296A Cited
US3560610A Cited
US3560609A Cited
US3912808A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1983-05-06 1983-11-05 1984-05-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1987-05-06 1987-11-05 1988-05-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1991-05-06 1991-11-05 1992-05-06 $7700.00 Window Closed / Lapsed

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