US4224140A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for producing cracked distillate and hydrogen from heavy oil
Assignee: Eneos Corp
•
Filing: 1979-03-21
•
Granted: 1980-09-23
•
Expires: 1999-03-21
Abstract
Abstract A process for producing a cracked distillate and hydrogen from a heavy oil which comprises cracking the heavy oil in the presence of laterite or a laterite-containing catalyst while simultaneously depositing coke on said laterite or laterite-containing catalysts, reducing the laterite or laterite-containing catalyst on which the coke is deposited, and forming a hydrogen-rich gas by contacting the reduced laterite or laterite-containing catalyst with steam.
Inventors
- 👤 Kuniaki Fujimori
- 👤 Yoshihito Satomi
- 👤 Teruo Suzuka
- 👤 Shirou Aizawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 15:39
CPC Classifications
C; C10; C10G; C10G11/00; C10G11/02; C10G11/04; B; B01; B01J; B01J23/00; B01J23/70; B01J23/74; B01J23/745; B01J37/00; B01J37/0009; B01J37/0018; C10G11/14; C10G11/18; Y; Y02; Y02E; Y02E60/00; Y02E60/30; Y02E60/36
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
74 words
A process for producing a cracked distillate and hydrogen from a heavy oil which comprises cracking the heavy oil in the presence of laterite or a laterite-containing catalyst while simultaneously depositing coke on said laterite or laterite-containing catalyst, reducing the laterite or laterite-containing catalysts on which the coke is deposited while simultaneously burning the coke in a reducing atmosphere, and forming a hydrogen-rich gas by contacting the reduced laterite or laterite-containing catalyst with steam.
Claim 2
Dependent Claim
74 words
A process for producing a cracked distillate and hydrogen from a heavy oil which comprises cracking the heavy oil in the presence of laterite or a laterite-containing catalyst while simultaneously depositing coke on said laterite or laterite-containing catalyst, reducing the laterite or laterite-containing catalysts on which the coke is deposited while simultaneously burning the coke in a reducing atmosphere, and forming a hydrogen-rich gas by contacting the reduced laterite or laterite-containing catalyst with steam.
Claim 3
Dependent Claim
17 words
The process of claim 1, wherein said laterite contains about 30 to 60% by weight of iron.
Claim 4
Dependent Claim
30 words
The process of claim 1, wherein said cracking is conducted at a temperature of about 450° to 600° C. under a pressure of about 0 to 15 kg/cm 2 G.
Claim 5
Dependent Claim
30 words
The process of claim 1, wherein said coke is deposited on said catalyst in an amount of about 2% to 15% by weight based on the weight of the catalyst.
Claim 6
Dependent Claim
30 words
The process of claim 1, wherein said coke is deposited on said catalyst in an amount of about 2 to 8% by weight based on the weight of the catalyst.
Claim 7
Dependent Claim
23 words
The process of claim 1, wherein said catalyst having coke deposited thereon is reduced at a temperature of about 750° to 900° C.
Claim 8
Dependent Claim
37 words
The process of claim 1, wherein said reduced catalyst is contacted with steam at a temperature of about 600° to 950° C. under a pressure of about 0 to 15 kg/cm 2 G whereby hydrogen is formed.
Claim 9
Dependent Claim
166 words
A fluidized bed process for producing a cracked distillate and hydrogen from a heavy oil which comprises introducing said heavy oil into a first reaction zone containing a fluidized bed of laterite or a laterite-containing catalyst at a temperature of about 450° to 600° C. under a pressure of about 0 to 15 kg/cm 2 G and simultaneously depositing coke on said catalyst, removing the cracked distillate from said reaction zone and circulating said coke deposited laterite catalyst to a second reaction zone wherein said coke deposited laterite catalyst is fluidized and reduced at a temperature of about 750° to 950° C. under a pressure of about 0 to 15 kg/cm 2 G while simultaneously burning the coke in a reducing atmosphere, circulating said reduced laterite catalyst to a third reaction zone wherein said catalyst is fluidized and contacted with steam at a temperature of about 600° to 950° C. under a pressure of about 0 to 15 kg/cm 2 whereby a hydrogen-rich gas is formed.
Claim 10
Dependent Claim
166 words
A fluidized bed process for producing a cracked distillate and hydrogen from a heavy oil which comprises introducing said heavy oil into a first reaction zone containing a fluidized bed of laterite or a laterite-containing catalyst at a temperature of about 450° to 600° C. under a pressure of about 0 to 15 kg/cm 2 G and simultaneously depositing coke on said catalyst, removing the cracked distillate from said reaction zone and circulating said coke deposited laterite catalyst to a second reaction zone wherein said coke deposited laterite catalyst is fluidized and reduced at a temperature of about 750° to 950° C. under a pressure of about 0 to 15 kg/cm 2 G while simultaneously burning the coke in a reducing atmosphere, circulating said reduced laterite catalyst to a third reaction zone wherein said catalyst is fluidized and contacted with steam at a temperature of about 600° to 950° C. under a pressure of about 0 to 15 kg/cm 2 whereby a hydrogen-rich gas is formed.
Claim 11
Dependent Claim
29 words
The process of claim 8, wherein upon completion of the reaction in said third reaction zone, said oxidized laterite catalyst is recirculated to said first reaction zone for reuse.
Claim 12
Dependent Claim
20 words
The process of claim 9, wherein said laterite or laterite-containing catalyst contains about 30 to 60% by weight of iron.
Claim 13
Dependent Claim
42 words
The process of claim 1 or claim 8, wherein said laterite-containing catalyst is a mixture of laterite and up to about 30% by weight of at least one member selected from nickel ore, pyrite cinder, magnetite, alumina, limestone, dolomite and calcium hydroxide.
Claim 14
Dependent Claim
47 words
The process of claim 1 or claim 8, wherein said laterite or laterite-containing catalyst is prepared by pulverizing natural laterite or a laterite mixed material, granulating to form particles having an average particle size of about 60 to 500 microns and sintering at 900° C. or more.
Claim 15
Dependent Claim
44 words
The process of claim 1 or claim 8, wherein the reduction of said laterite or laterite-containing catalyst is carried out by introducing an oxygen-containing gas in an amount of about 0.1 to 0.7 mole per mole of carbon in the coke calculated as oxygen.
Claim 16
Dependent Claim
36 words
The process of claim 1 or claim 8, wherein when reducing said laterite or laterite-containing catalyst, sulfur compounds present in the coke are converted to iron sulfide which is then decomposed by steam when forming hydrogen.
Claim 17
Dependent Claim
26 words
The process of claim 9, wherein a part of said laterite or laterite-containing catalyst in the second reaction zone is circulated into the first reaction zone.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-09-23 | 1984-03-24 | 1984-09-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-09-23 | 1988-03-24 | 1988-09-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-09-23 | 1992-03-24 | 1992-09-23 | $7700.00 | Window Closed / Lapsed |