Patent US4234752A successfully refreshed from Google Patents.
US4234752A
Expired / Lapsed
US
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Dehydration of alcohols
Assignee: Phillips Petroleum Co
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Filing: 1979-09-28
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Granted: 1980-11-18
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Expires: 1999-09-28
Abstract
Abstract An alcohol which can be straight chain or branch-chain and can contain from 2 to about 20 carbon atoms per molecule is dehydrated in the presence of gamma-alumina, which may be base-treated, employing an inert carrier gas. 3-Methyl-1-butanol was dehydrated over gamma-alumina employing nitrogen as the carrier gas to obtain yields well in excess of 90 percent with correspondingly high selectivities. 3-Methyl-1-butene having a 97.7 weight percent purity was obtained with base-treated gamma-alumina.
Inventors
- 👤 Yulin Wu
- 👤 Stanley J. Marwil
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 14:59
CPC Classifications
C; C07; C07C; C07C1/00; C07C1/20; C07C1/24; C07C2521/00; C07C2521/02; C07C2521/04
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
37 words
A process for the conversion of an alcohol to an olefin which comprises subjecting said alcohol under dehydration reaction conditions of temperature and pressure to the presence of gamma-alumina in the presence of an inert carrier gas.
Claim 2
Dependent Claim
37 words
A process for the conversion of an alcohol to an olefin which comprises subjecting said alcohol under dehydration reaction conditions of temperature and pressure to the presence of gamma-alumina in the presence of an inert carrier gas.
Claim 3
Dependent Claim
12 words
A process according to claim 1 wherein the gamma-alumina has been base-treated.
Claim 4
Dependent Claim
31 words
A process according to claim 1 wherein the alcohol is at least one alcohol selected from straight chain and branched-chain alcohols having from 2 to about 20 carbon atoms per molecule.
Claim 5
Dependent Claim
27 words
A process according to claim 1 wherein the alcohol is at least one of the following: ethanol, n-propanol, 2-methyl-2-propanol, 3-methyl-1-butanol, 3-methyl-2-butanol, 2,4-dimethyl-1-hexanol, n-octanol, 2,11-dimethyl-2-dodecanol, n-hexadecanol and n-eicosanol.
Claim 6
Dependent Claim
31 words
A process according to claim 1 wherein the reaction conditions include a temperature of from about 200° to about 500° C. and a pressure from about 50 to about 3500 kPa.
Claim 7
Dependent Claim
20 words
A process according to claim 1 wherein 3-methyl-1-butanol is dehydrated to produce 3-methyl-1-butene and nitrogen is the inert carrier gas.
References Cited (Backward Citations)
US1909356A
Cited
US2297062A
Cited
US2377026A
Cited
US2636057A
Cited
US2786802A
Cited
US2949493A
Cited
US3600455A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1983-11-18 | 1984-05-19 | 1984-11-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1987-11-18 | 1988-05-19 | 1988-11-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1991-11-18 | 1992-05-19 | 1992-11-18 | $7700.00 | Window Closed / Lapsed |