Patent US4246366A successfully refreshed from Google Patents.
US4246366A
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Mixtures of glycidylated hydantoins and polyhydric phenols and the use thereof for the preparation of plastics
Assignee: BASF Corp
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Filing: 1979-06-11
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Granted: 1981-01-20
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Expires: 1999-06-11
Abstract
Abstract Mixtures of approximately equivalent amounts of (a) a glycidylated hydantoin and (b) a mononuclear phenol with 2 or 3 phenolic hydroxyl groups, at least one of the components (a) or (b) being trifunctional. They additionally contain a curing accelerator and on heating form mechanically good and flexible plastics which are stable to hydrolysis and can be used as building materials and foams, for the finishing and coating of textile material and for the preparation of water-permeable membranes.
Inventors
- 👤 Rolf Schmid
- 👤 Andre Schmitter
- 👤 Ferdinand Gutekunst
- 👤 Friedrich Lohse
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 08:55
CPC Classifications
B; B01; B01D; B01D71/00; B01D71/06; B01D71/58; B01D71/62; C; C08; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/22; C08G59/26; C08G59/32; C08G59/3236; C08G59/3245; C08G59/40; C08G59/62; C08G59/621
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
99 words
A mixture of a curable epoxide resin, a curing agent for the resin and a curing accelerator, which comprises (a) as the resin, a N-glycidyl compound of a mononuclear or binuclear hydantoin, which has two glycidyl groups in the molecule or a binuclear hydantoin, which has three glycidyl groups in the molecule and is free from ester groups, and (b) as the curing agent, a mononuclear phenol with two or three phenolic hydroxyl groups, at least one of the components (a) or (b) being tri-functional and there being 0.5 to 1.1 equivalents of (b) per 1 equivalent of (a).
Claim 2
Dependent Claim
99 words
A mixture of a curable epoxide resin, a curing agent for the resin and a curing accelerator, which comprises (a) as the resin, a N-glycidyl compound of a mononuclear or binuclear hydantoin, which has two glycidyl groups in the molecule or a binuclear hydantoin, which has three glycidyl groups in the molecule and is free from ester groups, and (b) as the curing agent, a mononuclear phenol with two or three phenolic hydroxyl groups, at least one of the components (a) or (b) being tri-functional and there being 0.5 to 1.1 equivalents of (b) per 1 equivalent of (a).
Claim 3
Dependent Claim
27 words
A mixture according to claim 1, which contains, as the curing accelerator (c), a tertiary amine, an imidazole, an alkali metal alcoholate or a quaternary ammonium salt.
Claim 4
Dependent Claim
91 words
A mixture according to either of claim 1 or 2, which contains, as component (a), a hydantoin of the formula I, II, III or V ##STR2## in which R 1 and R 2 independently of one another are methyl or ethyl or together are tetramethylene or pentamethylene, R 3 is hydrogen or methyl and R 4 is an alkylene group having 1 to 12 carbon atoms, especially a methylene group, or a mixture of hydantoins of the said formulae, and contains, as component (b), a compound with 3 phenolic hydroxyl groups.
Claim 5
Dependent Claim
13 words
A mixture according to claim 3, which contains a trisphenol as component (b).
Claim 6
Dependent Claim
12 words
A mixture according to claim 4, which contains pyrogallol as the trisphenol.
Claim 7
Dependent Claim
58 words
A mixture according to either of claim 1 or 2, which contains, as component (a), a hydantoin of the formula IV ##STR3## in which R 1 and R 2 independently of one another are methyl or ethyl or together are tetramethylene or pentamethylene, and contains, as component (b), a mononuclear compound with 2 or 3 phenolic hydroxyl groups.
Claim 8
Dependent Claim
28 words
A mixture according to any one of claims 1 to 6, in which there is 0.9 to 1.0 equivalent of component (b) per one equivalent of component (a).
Claim 9
Dependent Claim
55 words
A mixture according to claim 6, which comprises, as component (a), a hydantoin of the formula IV, in which R 1 and R 2 are each methyl, as component (b) 1 equivalent of 1,3-dihydroxybenzene per 1 equivalent of (a), and, as component (c), 0.01 g of tetramethylammonium chloride per 100 g of (a) and (b).
Claim 10
Dependent Claim
51 words
A mixture according to claim 6, which comprises, as component (a), a hydantoin of the formula IV, in which R 1 and R 2 are each methyl, as component (b), 0,9 equivalent of 1,2,3-trihydroxybenzene per 1 equivalent of (a), and 0.1 g of 1-methylimidazole per 100 g of (a) and (b).
Claim 11
Dependent Claim
55 words
A mixture according to claim 3, which comprises, as component (a), a hydantoin of the formula I, in which R 1 and R 2 are each methyl, as component (b) 1 equivalent of 1,2,3-trihydroxybenzene per 1 equivalent of (a), and as component (c), 0.01 g of tetramethylammonium chloride per 100 g of (a) and (b).
Claim 12
Dependent Claim
59 words
A mixture according to claim 3, which comprises, as component (a), a hydantoin of the formula III, in which R 1 and R 2 are each methyl and R 4 is methylene, as component (b) 0.9 equivalent of 1,2,3-trihydroxybenzene per 1 equivalent of (a), and as component (c) 0.1 g of 1-methylimidazole per 100 g of (a) and (b).
Claim 13
Dependent Claim
12 words
A mixture according to claim 1, which additionally contains a blowing agent.
Claim 14
Dependent Claim
32 words
A process for the preparation of a cured product, which comprises allowing a mixture according to any one of claims 1 to 7 to react at a temperature of above 120° C.
Claim 15
Dependent Claim
23 words
A process according to claim 13, wherein, by casting, a film is prepared which after curing can be used as an osmosis membrane.
Claim 16
Dependent Claim
22 words
A plastic based on epoxide resin, which has been prepared from a mixture according to any one of claims 1 to 11.
Claim 17
Dependent Claim
11 words
A plastic according to claim 15, which forms an osmosis membrane.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-01-20 | 1984-07-21 | 1985-01-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-01-20 | 1988-07-21 | 1989-01-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-01-20 | 1992-07-21 | 1993-01-20 | $7700.00 | Window Closed / Lapsed |