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US4248751A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for producing a silicone elastomer emulsion and use thereof

Assignee: Dow Silicones Corp
•
Filing: 1979-08-31
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Granted: 1981-02-03
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Expires: 1999-08-31
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Abstract

Abstract A latex of crosslinked silicone is prepared by emulsifying a vinyl endblocked polydiorganosiloxane and an organosilicon compound having silicon-bonded hydrogen atoms with water and surfactant, adding a platinum catalyst and then heating the emulsion to form the latex. Colloidal silica can be added to the latex to provide a product which is tougher. The water in the latex can be evaporated to provide an elastomer film. Coating the latex on a substrate, such as a textile or paper, provides an elastomeric coated substrate, which provides water repellency, insulation and release properties to the substrate.

Inventors

  • 👤 David N. Willing

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 03:04
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/02; C08J3/03; C08J2383/00; C08J2383/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 46 words
A process for producing a silicone elastomer emulsion comprising emulsifying (A) a vinyl endblocked polydiorganosiloxane, and (B) an organosilicon compound having silicon-bonded hydrogen atoms using water and surfactant to form an emulsion, adding a platinum catalyst, and heating the emulsion forming a latex of crosslinked silicone.
Claim 2
Dependent Claim 46 words
A process for producing a silicone elastomer emulsion comprising emulsifying (A) a vinyl endblocked polydiorganosiloxane, and (B) an organosilicon compound having silicon-bonded hydrogen atoms using water and surfactant to form an emulsion, adding a platinum catalyst, and heating the emulsion forming a latex of crosslinked silicone.
Claim 3
Dependent Claim 11 words
A crosslinked silicone latex produced by the method of claim 1.
Claim 4
Dependent Claim 20 words
The process in accordance with claim 1 in which a colloidal silica is added to the latex of crosslinked silicone.
Claim 5
Dependent Claim 11 words
A crosslinked silicone latex produced by the method of claim 3.
Claim 6
Dependent Claim 280 words
The process in accordance with claim 1 in which the vinyl endblocked polydiorganosiloxane (A) is a polydiorganosiloxane terminated by triorganosiloxy groups and having two vinyl radicals per molecule, no silicon atom having more than one vinyl radical bonded thereto, the remaining organic radicals being selected from the group consisting of methyl, ethyl, phenyl and 3,3,3-trifluoropropyl radicals, at least 50 percent of the organic radicals being methyl radicals, and said polydiorganosiloxane having a viscosity of from 0.1 to 100 Pa·s at 25° C., and the organo-silicon compound (B) is a mixture of silicon compounds providing from 0.75 to 1.50 silicon-bonded hydrogen atoms per vinyl radical of (A), said mixture (B) consisting essentially of (1) an organosiloxane compound containing two silicon-bonded hydrogen atoms per molecule and the organic radicals being selected from the group consisting of alkyl radicals having from 1 to 12 carbon atoms inclusive, phenyl and 3,3,3-trifluoropropyl, no silicon atom having bonded thereto more than one silicon-bonded hydrogen atom, and said organosiloxane compound (1) having no more than 500 silicon atoms per molecule, and (2) an organosiloxane compound containing at least 3 silicon-bonded hydrogen atoms per molecule, the organic radicals being selected from the group consisting of alkyl radicals having from 1 to 12 carbon atoms inclusive, phenyl and 3,3,3-trifluoropropyl radicals, no silicon atom having bonded thereto more than one silicon-bonded hydrogen atom and said organosiloxane compound (2) having no more than 75 silicon atoms per molecule, said mixture (B) being such that at least 10 percent of the silicon-bonded hydrogen atoms are derived from (1) and at least 10 percent of the silicon-bonded hydrogen atoms are derived from (2), (1) and (2) composing 100 weight percent of mixture (B).
Claim 7
Dependent Claim 11 words
A crosslinked silicone latex produced by the method of claim 5.
Claim 8
Dependent Claim 20 words
The process in accordance with claim 5 in which a colloidal silica is added to the latex of crosslinked silicone.
Claim 9
Dependent Claim 31 words
A process in which a crosslinked silicone latex is produced in accordance with claim 1 and thereafter the water is evaporated from the crosslinked silicone latex to form an elastomeric film.
Claim 10
Dependent Claim 20 words
The process in accordance with claim 8 in which the latex is coated on a substrate before evaporating the water.
Claim 11
Dependent Claim 31 words
A process in which a crosslinked silicone latex is produced in accordance with claim 5 and thereafter the water is evaporated from the crosslinked silicone latex to form an elastomeric film.
Claim 12
Dependent Claim 20 words
The process in accordance with claim 10 in which the latex is coated on a substrate before evaporating the water.
Claim 13
Dependent Claim 31 words
A process in which a crosslinked silicone latex is produced in accordance with claim 7 and thereafter the water is evaporated from the crosslinked silicone latex to form an elastomeric film.
Claim 14
Dependent Claim 20 words
The process in accordance with claim 12 in which the latex is coated on a substrate before evaporating the water.
Claim 15
Dependent Claim 14 words
The process in accordance with claim 13 in which the substrate is a textile.
Claim 16
Dependent Claim 13 words
The process in accordance with claim 14 in which the substrate is paper.

References Cited (Backward Citations)

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GB981824A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-02-03 1984-08-04 1985-02-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-02-03 1988-08-04 1989-02-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-02-03 1992-08-04 1993-02-03 $7700.00 Window Closed / Lapsed

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