Patent US4255553A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4255553A Expired / Lapsed US ⏱️ 0.0 years remaining

Powder coating composition

Assignee: Toyobo Co Ltd
•
Filing: 1979-06-04
•
Granted: 1981-03-10
•
Expires: 1999-06-04
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A powder coating composition comprising: (a) a compound having at least two epoxy groups in the molecule; (b) a compound having at least two carboxyl groups in the molecule; and (c) a compound of the formula: ##STR1## wherein m and n are each an integer of 1-10 5 provided that m≦n; R 1 is a residue of a mono or polybasic carboxylic acid; R 2 , R 3 , R 4 and R 5 are, the same or different, each an unsubstituted or substituted C 1-30 alkyl, C 6-10 cycloalkylalkyl, C 5-8 cycloalkyl, C 6-20 aryl or C 7-30 aralkyl or at least two of them many form together with nitrogen atom a saturated or unsaturated heterocyclic group, said composition being able to be thermoset at low temperature and form a paint film having excellent surface smoothness without browning of the film.

Inventors

  • 👤 Yutaka Mizumura
  • 👤 Iori Naito
  • 👤 Hideo Miyake

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 02:16
CPC Classifications
C; C09; C09D; C09D163/00; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/42; C08G59/68; C08G59/686

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 289 words
A powder coating composition which comprises: (a) a compound having at least two epoxy groups in the molecule; (b) a polyester or acrylic resin having a molecular weight of 1,000 to 7,000 and an acid value of not less than 20 having at least two carboxyl groups; and (c) a compound of the formula: ##STR4## wherein m and n are each an integer of from 1 to 10 5 provided that m≦n; R 1 is a residue of a mono or polybasic carboxylic acid (the number of the carboxyl groups n=1 to 10 5 ); and R 2 , R 3 , R 4 , and R 5 are, the same or different, each being an alkyl group having 1 to 30 carbon atoms substituted with a halogen, nitro group, an alkoxy group having 1 to 4 carbon atoms or furyl; a cycloalkylalkyl group having 6 to 10 carbon atoms; a cycloalkyl group having 5 to 8 carbon atoms substituted with a halogen, nitro group, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or furyl; an aryl group having 6 to 20 carbon atoms, or a substituted aryl group having 6 to 20 carbon atoms substituted with a halogen, nitro group, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or furyl; or an aralkyl group having 7 to 30 carbon atoms substituted with a halogen, nitro group, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or furyl; or at least two of R 2 to R 5 forming, together with the nitrogen atom, a saturated or unsaturated heterocyclic group.
Claim 2
Dependent Claim 289 words
A powder coating composition which comprises: (a) a compound having at least two epoxy groups in the molecule; (b) a polyester or acrylic resin having a molecular weight of 1,000 to 7,000 and an acid value of not less than 20 having at least two carboxyl groups; and (c) a compound of the formula: ##STR4## wherein m and n are each an integer of from 1 to 10 5 provided that m≦n; R 1 is a residue of a mono or polybasic carboxylic acid (the number of the carboxyl groups n=1 to 10 5 ); and R 2 , R 3 , R 4 , and R 5 are, the same or different, each being an alkyl group having 1 to 30 carbon atoms substituted with a halogen, nitro group, an alkoxy group having 1 to 4 carbon atoms or furyl; a cycloalkylalkyl group having 6 to 10 carbon atoms; a cycloalkyl group having 5 to 8 carbon atoms substituted with a halogen, nitro group, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or furyl; an aryl group having 6 to 20 carbon atoms, or a substituted aryl group having 6 to 20 carbon atoms substituted with a halogen, nitro group, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or furyl; or an aralkyl group having 7 to 30 carbon atoms substituted with a halogen, nitro group, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms or furyl; or at least two of R 2 to R 5 forming, together with the nitrogen atom, a saturated or unsaturated heterocyclic group.
Claim 3
Dependent Claim 31 words
A powder coating composition according to claim 1, wherein R 1 of the compound of the formula [I] is a residue of a carboxylic acid having 1 to 10 carboxyl groups.
Claim 4
Dependent Claim 31 words
A powder coating composition according to claim 2, wherein R 1 of the compound of the formula [I] is a residue of a carboxylic acid having 1 to 4 carbon atoms.
Claim 5
Dependent Claim 32 words
A powder coating composition according to claim 3, wherein R 1 of the compound of the formula [I] is a residue of an aromatic dicarboxylic acid having 8 to 22 carbon atoms.
Claim 6
Dependent Claim 31 words
A powder coating composition according to claim 3, wherein R 1 of the compound of the formula [I] is a residue of acetic acid, propionic acid, trimellitic acid or benzoic acid.
Claim 7
Dependent Claim 60 words
A powder coating composition according to any one of claims 1, 2, 3, 4 or 5, wherein R 2 , R 3 , R 4 and R 5 of the compound of the formula [I] are, the same or different, each an alkyl group having 1 to 30 carbon atoms or an aralkyl group having 7 to 30 carbon atoms.
Claim 8
Dependent Claim 37 words
A powder coating composition according to claim 6, wherein R 2 , R 3 , R 4 and R 5 of the compound of the formula [I] are, the same or different, each methyl, ethyl or benzyl.
Claim 9
Dependent Claim 38 words
A powder coating composition according to claim 6, wherein the compound having at least two epoxy groups is a polyepoxy compound having a molecular weight of 200 to 5,000 and an epoxy equivalent of not more than 2,500.
Claim 10
Dependent Claim 34 words
A powder coating composition according to claim 8, wherein the compound having at least two epoxy groups is a reaction product of an aromatic polyhydroxy compound having 6 to 27 carbon atoms and epichlorohydrin.
Claim 11
Dependent Claim 34 words
A powder coating composition according to claim 8, wherein the compound having at least two epoxy groups is a condensation product of an aromatic polycarboxylic acid having 8 to 22 carbon atoms and epichlorohydrin.
Claim 12
Dependent Claim 35 words
A powder coating composition according to claim 8, wherein the compound having at least two epoxy groups is a reaction product of a hydroxy-substituted aromatic carboxylic acid having 7 to 28 carbon atoms and epichlorohidrin.
Claim 13
Dependent Claim 22 words
A powder coating composition according to claim 8, wherein the compound having at least two epoxy groups is a nitrogen-containing epoxy compound.
Claim 14
Dependent Claim 28 words
A powder coating composition according to claim 8, wherein the compound having at least two carboxyl groups is an aliphatic dicarboxylic acid having 4 to 36 carbon atoms.
Claim 15
Dependent Claim 37 words
A powder coating composition according to claim 1, wherein the composition contains 0.01 to 10% by weight of the compound of the formula [I] based on the amount of the compound having at least two epoxy groups.
Claim 16
Dependent Claim 45 words
A powder coating composition according to claim 1, wherein the ratio of the epoxy compound to the carboxyl groups-containing compound in the composition is selected so that the ratio of the epoxy groups to the carboxyl groups becomes within the range of 0.5<epoxy groups/carboxyl groups<2.0.

References Cited (Backward Citations)

US2712535A Cited
US2928807A Cited
US2928809A Cited
US3555111A Cited
US3989679A Cited
US4026862A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-03-09 1984-09-08 1985-03-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-03-09 1988-09-08 1989-03-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-03-09 1992-09-08 1993-03-10 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag