Patent US4262114A successfully refreshed from Google Patents.
US4262114A
Expired / Lapsed
US
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Segmented thermoplastic copolyesters
Assignee: Akzona Inc
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Filing: 1976-12-20
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Granted: 1981-04-14
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Expires: 1996-12-20
Abstract
Abstract This invention relates to polyester polyether segmented copolymers wherein the polyether segment contains a certain amount of heterocyclic ring repeat units, for example, the hydantoin ring. These polyester polyether segmented copolymers are useful in the production of fibers, films or other extrusion moldings where elastomeric properties are desirable.
Inventors
- 👤 Kenneth B. Wagener
- 👤 David A. Johnson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 22:03
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/68; C08G63/685; C08G63/6854; C08G63/6856
Claims Analysis
Total Claims: 35
Claim 1
Independent Claim
187 words
A segmented thermoplastic copolyester consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head to tail through ester linkages, said long-chain ester units comprising from 40-70% by weight of the copolyester and being represented by the formula ##STR8## and said short-chain ester units being represented by the formula ##STR9## where L in said long-chain unit is a divalent radical remaining after removal of terminal hydroxyl groups from a poly(oxyalkylene) glycol having at least one thermally stable hydantoin ring per molecule, each of said rings attached to said chain through amide or imide linkages and giving said radical, L, a carbon to nitrogen ratio between about 3/1 and about 350/1, and a number average molecular weight of between 200 and 8,000; R is a divalent radical remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight of less than 300; and E in said short-chain unit is a divalent radical remaining after removal of hydroxyl groups from a low molecular weight diol having 2 to 15 carbon atoms per molecule and a molecular weight less than about 250.
Claim 2
Dependent Claim
187 words
A segmented thermoplastic copolyester consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head to tail through ester linkages, said long-chain ester units comprising from 40-70% by weight of the copolyester and being represented by the formula ##STR8## and said short-chain ester units being represented by the formula ##STR9## where L in said long-chain unit is a divalent radical remaining after removal of terminal hydroxyl groups from a poly(oxyalkylene) glycol having at least one thermally stable hydantoin ring per molecule, each of said rings attached to said chain through amide or imide linkages and giving said radical, L, a carbon to nitrogen ratio between about 3/1 and about 350/1, and a number average molecular weight of between 200 and 8,000; R is a divalent radical remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight of less than 300; and E in said short-chain unit is a divalent radical remaining after removal of hydroxyl groups from a low molecular weight diol having 2 to 15 carbon atoms per molecule and a molecular weight less than about 250.
Claim 3
Dependent Claim
17 words
The segmented thermoplastic copolyester of claim 1 wherein substantially all of the dicarboxylic acid is terephthalic acid.
Claim 4
Dependent Claim
21 words
The segmented thermoplastic copolyester of claim 1 wherein the dicarboxylic acid is about 70-100% terephthalic acid and about 0-30% isophthalic acid.
Claim 5
Dependent Claim
21 words
The segmented thermoplastic copolyester of claim 1 wherein the dicarboxylic acid is about 70-100% terephthalic acid and about 0-30% phthalic acid.
Claim 6
Dependent Claim
23 words
The segmented thermoplastic copolyester of claim 1 wherein substantially all of the diol having molecular weight less than about 250 is 1,4-butane diol.
Claim 7
Dependent Claim
20 words
The segmented copolyester of claim 1 wherein the poly(oxyalkylene) glycol is poly(oxethylene) glycol having a molecular weight of about 400-2500.
Claim 8
Dependent Claim
53 words
The segmented copolyester of claim 1 wherein the dicarboxylic acid is 70-100 mole % terephthalic acid, 0-30 mole % isophthalic acid, and 0-30 mole % phthalic acid; the diol having a molecular weight less than 250 is 1,4-butane diol and the poly(oxyalkylene) glycol is poly(oxyethylene) glycol having a molecular weight of about 400-2500.
Claim 9
Dependent Claim
170 words
A segmented thermoplastic copolyester consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head to tail through ester linkages, said short-chain ester units consisting of the reaction products of cyclic, alicyclic or aromatic low molecular weight diols with aliphatic, cycloaliphatic or aromatic dicarboxylic acids said ester having a number average molecular weight of less than about 500, long-chain ester units comprising from 40-70% by weight of the copolyester and being represented by the formula ##STR10## where L is a divalent radical remaining after the removal of terminal hydroxyl groups from poly(oxyalkylene) glycol having at least one thermally stable, hydantoin ring per molecule, each of said rings attached to said chain through amide or imide linkages and giving said radical L, a carbon to nitrogen ratio between about 3/1 and about 350/1, and a molecular weight between 200 and 8,000; and R is a divalent radical remaining after the removal of carboxyl groups from a dicarboxylic acid having a molecular weight of less than 300.
Claim 10
Dependent Claim
170 words
A segmented thermoplastic copolyester consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head to tail through ester linkages, said short-chain ester units consisting of the reaction products of cyclic, alicyclic or aromatic low molecular weight diols with aliphatic, cycloaliphatic or aromatic dicarboxylic acids said ester having a number average molecular weight of less than about 500, long-chain ester units comprising from 40-70% by weight of the copolyester and being represented by the formula ##STR10## where L is a divalent radical remaining after the removal of terminal hydroxyl groups from poly(oxyalkylene) glycol having at least one thermally stable, hydantoin ring per molecule, each of said rings attached to said chain through amide or imide linkages and giving said radical L, a carbon to nitrogen ratio between about 3/1 and about 350/1, and a molecular weight between 200 and 8,000; and R is a divalent radical remaining after the removal of carboxyl groups from a dicarboxylic acid having a molecular weight of less than 300.
Claim 11
Dependent Claim
17 words
The segmented thermoplastic copolyester of claim 8 wherein substantially all of the dicarboxylic acid is terephthalic acid.
Claim 12
Dependent Claim
21 words
The segmented thermoplastic copolyester of claim 8 wherein the dicarboxylic acid is about 70-100% terephthalic acid and about 0-30% isophthalic acid.
Claim 13
Dependent Claim
21 words
The segmented thermoplastic copolyester of claim 8 wherein the dicarboxylic acid is about 70-100% terephthalic acid and about 0-30% phthalic acid.
Claim 14
Dependent Claim
160 words
A segmented thermoplastic copolyester consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head to tail through ester linkages, said long-chain ester units comprising from 40-70% by weight of the copolyesters and being represented by the formula ##STR11## and said short-chain ester units being represented by the formula ##STR12## where L in the long-chain ester unit is a poly(oxyalkylene) glycol unit represented by the formula ##STR13## and X is 1,3-divalent-5,5-dialkylhydantoin; R is a divalent radical remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight of less than 300; E is a divalent radical remaining after removal of hydroxyl groups from a low molecular weight diol having 2-15 carbon atoms per molecule and a molecular weight of less than 250; the sum of m plus n in formula III and IV is within the range of 5 to 180; and x in formula IV has a maximum value of 10.
Claim 15
Dependent Claim
160 words
A segmented thermoplastic copolyester consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head to tail through ester linkages, said long-chain ester units comprising from 40-70% by weight of the copolyesters and being represented by the formula ##STR11## and said short-chain ester units being represented by the formula ##STR12## where L in the long-chain ester unit is a poly(oxyalkylene) glycol unit represented by the formula ##STR13## and X is 1,3-divalent-5,5-dialkylhydantoin; R is a divalent radical remaining after removal of carboxyl groups from a dicarboxylic acid having a molecular weight of less than 300; E is a divalent radical remaining after removal of hydroxyl groups from a low molecular weight diol having 2-15 carbon atoms per molecule and a molecular weight of less than 250; the sum of m plus n in formula III and IV is within the range of 5 to 180; and x in formula IV has a maximum value of 10.
Claim 16
Dependent Claim
17 words
The segmented thermoplastic copolyester of claim 12 wherein substantially all of the dicarboxylic acid is terephthalic acid.
Claim 17
Dependent Claim
21 words
The segmented thermoplastic copolyester of claim 12 wherein the dicarboxylic acid is about 70-100% terephthalic acid and about 0-30% isophthalic acid.
Claim 18
Dependent Claim
21 words
The segmented thermoplastic copolyester of claim 12 wherein the dicarboxylic acid is about 70-100% terephthalic acid and about 0-30% phthalic acid.
Claim 19
Dependent Claim
24 words
The segmented thermoplastic copolyester of claim 12 wherein substantially all of the diol having a molecular weight less than about 250 is 1,4-butane diol.
Claim 20
Dependent Claim
24 words
The segmented copolyester of claim 12 wherein the poly(oxyalkylene) glycol unit contains poly(oxyethylene) glycol residues having a number average molecular weight of about 400-2500.
Claim 21
Dependent Claim
58 words
The segmented copolyester of claim 12 wherein the dicarboxylic acid is 70-100 mole % terephthalic acid, 0-30 mole % isophthalic acid, and 0-30 mole % phthalic acid; the diol having a molecular weight of less than 250 is 1,4-butane diol and the poly(oxyalkylene) glycol unit contains poly(oxyethylene) glycol residues having a number average molecular weight of about 400-2500.
Claim 22
Dependent Claim
25 words
The segmented thermoplastic copolyester of claim 12 where X is ##STR14## and R 1 and R 2 are C 1 to C 12 alkyl groups.
Claim 23
Dependent Claim
29 words
The segmented thermoplastic copolyester of claim 12 wherein X is ##STR15## and R 1 and R 2 are joined to form a C 5 or C 6 ring structure.
Claim 24
Dependent Claim
20 words
The segmented thermoplastic copolyester of claim 12 wherein X is ##STR16## and R 1 and R 2 are methyl groups.
Claim 25
Dependent Claim
123 words
A segmented thermoplastic copolyester consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head to tail through ester linkages, said long- and short-chain ester units consisting essentially of divalent radicals remaining after removal of terminal hydroxyl groups from poly(oxyalkylene) glycols and divalent radicals remaining after removal of carboxyl groups from dicarboxylic acids, the improvement comprising incorporating from 40-70% by weight of the copolymer of long-chain ester units each having the formula ##STR17## where X is a thermally stable hydantoin ring, each of said rings attached to said long-chain ester unit through amide or imide linkages; m plus n is within the range of 5 to 20; and x in formula II has a maximum value of 10.
Claim 26
Dependent Claim
123 words
A segmented thermoplastic copolyester consisting essentially of a multiplicity of recurring long-chain ester units and short-chain ester units joined head to tail through ester linkages, said long- and short-chain ester units consisting essentially of divalent radicals remaining after removal of terminal hydroxyl groups from poly(oxyalkylene) glycols and divalent radicals remaining after removal of carboxyl groups from dicarboxylic acids, the improvement comprising incorporating from 40-70% by weight of the copolymer of long-chain ester units each having the formula ##STR17## where X is a thermally stable hydantoin ring, each of said rings attached to said long-chain ester unit through amide or imide linkages; m plus n is within the range of 5 to 20; and x in formula II has a maximum value of 10.
Claim 27
Dependent Claim
17 words
The segmented thermoplastic copolyester of claim 22 wherein substantially all of the dicarboxylic acid is terephthalic acid.
Claim 28
Dependent Claim
21 words
The segmented thermoplastic copolyester of claim 22 wherein the dicarboxylic acid is about 70-100% terephthalic acid and about 0-30% isophthalic acid.
Claim 29
Dependent Claim
21 words
The segmented thermoplastic copolyester of claim 22 wherein the dicarboxylic acid is about 70-100% terephthalic acid and about 0-30% phthalic acid.
Claim 30
Dependent Claim
25 words
The segmented thermoplastic copolyester of claim 22 wherein substantially all of the diol having a molecular weight of less than about 250 is 1,4-butane diol.
Claim 31
Dependent Claim
23 words
The segmented thermoplastic copolyester of claim 22 wherein the poly(oxyalkylene) glycol is poly(oxyethylene) glycol having a number average molecular weight of about 400-2500.
Claim 32
Dependent Claim
55 words
The segmented thermoplastic copolyester of claim 22 wherein the dicarboxylic acid is 70-100 mole % terephthalic acid, 0-30 mole % isophthalic acid, and 0-30 mole % phthalic acid; the diol having a molecular weight of less than 250 is 1,4-butane diol and the poly(oxyalkylene) glycol is poly(oxyethylene) glycol having a molecular weight of about 400-2500.
Claim 33
Dependent Claim
32 words
The segmented thermoplastic copolyester of claim 1 wherein the ratio of weight percent of the short-chain ester unit to long-chain ester unit is varied between 60 to 40 and 30 to 70.
Claim 34
Dependent Claim
17 words
The segmented thermoplastic copolyester of claim 29 wherein substantially all of the dicarboxylic acid is terephthalic acid.
Claim 35
Dependent Claim
24 words
The thermoplastic copolyester of claim 29 wherein substantially all of the diol having a molecular weight of less than about 250 is 1,4-butane diol.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1984-04-13 | 1984-10-13 | 1985-04-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-04-13 | 1988-10-13 | 1989-04-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-04-13 | 1992-10-13 | 1993-04-14 | $7700.00 | Window Closed / Lapsed |