Fluoro-alkyl ester-terminated linear aromatic polyester of enhanced hydrolytic stability

Claim 2

In a linear aromatic polyester which comprises monomer residues of a bisphenol and a dicarboxylic acid and in which the terminal residues of the polyester chain comprise a residue of said dicarboxylic acid, the improvement wherein the end carboxylate groups of said terminal dicarboxylic acid residues comprise at least about 5 mole percent of a carboxylate ester of a fluorine substituted saturated aliphatic monofunctional alcohol of 1 to 45 carbon atoms, said proportion being based on the total moles of end groups in the polyester.

Claim 3

The polyester of claim 1 wherein said dicarboxylic acid has the formula: ##STR8## wherein Z is alkylene, --Ar-- or --Ar--Y--Ar-- where Ar is aromatic, Y is alkylene, haloalkylene, --O--, --S--, --SO 2 --, --SO 3 --, --CO--, ##STR9## or GN<, wherein G is alkyl, haloalkyl, aryl, haloaryl, alkylaryl, haloalkylaryl, arylalkyl, haloarylalkyl, cycloalkyl or cyclohaloalkyl; and n is 0 or 1, the organic residue of said fluorine-substituted alcohol is an acyclic alkyl group which contains only fluorine and hydrogen substituents or only fluorine substituents, and about 5 mole percent to 100 mole percent of the polyester end groups are carboxylate ester end groups derived from said fluorine substituted alcohol.

Claim 4

The polyester of claim 2 wherein said dicarboxylic acid is an aromatic dicarboxylic acid, and about 25 mole percent to about 100 mole percent of the polyester end groups are carboxylate ester groups derived from a polyfluorinated alcohol containing only hydrogen and fluorine substituents.

Claim 5

The polyester of claim 3 wherein said aromatic dicarboxylic acid is selected from the group consisting of isophthalic acid, terephthalic acid, and mixtures thereof, and about 50 mole percent to about 100 mole percent of the polyester end groups are carboxylate ester groups derived from a fluorine-substituted primary alcohol.

Claim 6

The polyester of claim 4 wherein said bisphenol has the formula: ##STR10## wherein Ar is aromatic, G is alkyl, haloalkyl, aryl, haloaryl, alkylaryl, haloalkylaryl, arylalkyl, haloarylalkyl, cycloalkyl, or cyclohaloalkyl; E is divalent alkylene, haloalkylene, cycloalkylene, halocycloalkylene, arylene, or haloarylene, --O--, --S--, --SO--, --SO 2 --, --SO 3 --, --CO--, ##STR11## or GN<; T and T' are independently selected from the group consisting of halogen, G and OG; m is an integer from 0 to the number of replaceable hydrogen atoms on E; b is an integer from 0 to the number of replaceable hydrogen atoms on Ar, and x is 0 or 1, and said fluorine substituted aliphatic alcohol is a straight chain primary alcohol of 3 to 20 carbon atoms.

Claim 7

The polyester of claim 5 wherein the bisphenol is bisphenol-A and the fluorine substituted aliphatic alcohol is of the formula: H(CF.sub.2 --CF.sub.2).sub.a CH.sub.2 OH wherein a is an integer 1 to 8.

Claim 8

The polyester of claim 6 wherein the carboxylate ester groups derived from said fluorine-substituted alcohol are present in a proportion of about 50 mole percent based on the total end groups in the polyester and a is 5.

Claim 9

A linear aromatic polyester consisting of monomer residues of bisphenol A and a dicarboxylic acid selected from isophthalic acid, terephthalic acid and mixtures thereof containing about 5 to 100 mole percent, based on the total end groups in the polyester, of carboxylate ester end groups of monofunctional saturated acyclic aliphatic alcohol, the aliphatic residue of which contains only fluorine substituents or only fluorine and hydrogen substituents and 3 to 20 carbon atoms.

Claim 10

A linear aromatic polyester consisting of monomer residues of bisphenol A and a dicarboxylic acid selected from isophthalic acid, terephthalic acid and mixtures thereof containing about 5 to 100 mole percent, based on the total end groups in the polyester, of carboxylate ester end groups of monofunctional saturated acyclic aliphatic alcohol, the aliphatic residue of which contains only fluorine substituents or only fluorine and hydrogen substituents and 3 to 20 carbon atoms.

Claim 11

In the process of preparing a linear aromatic polyester which comprises monomer residues of a bisphenol and a dicarboxylic acid by the polymerization esterification reaction of said bisphenol and a diacyl halide of said dicarboxylic acid, the improvement wherein a minor molar proportion, based on the molar proportion of the diacyl halide, of a fluorine-substituted saturated monofunctional aliphatic alcohol of 1 to 45 carbon atoms is reacted into the polyester.

Claim 12

In the process of preparing a linear aromatic polyester which comprises monomer residues of a bisphenol and a dicarboxylic acid by the polymerization esterification reaction of said bisphenol and a diacyl halide of said dicarboxylic acid, the improvement wherein a minor molar proportion, based on the molar proportion of the diacyl halide, of a fluorine-substituted saturated monofunctional aliphatic alcohol of 1 to 45 carbon atoms is reacted into the polyester.

Claim 13

The process of claim 9 wherein the fluorine-substituted alcohol is reacted with the diacyl halide reactant prior to the polymerization esterification reaction of the diacyl halide and the bisphenol, and the molar proportion of the fluorine-substituted alcohol is about 0.1 mole percent to about 25 mole percent.

Claim 14

The process of claim 9 wherein the fluorine-substituted alcohol is mixed and reacted with the diacyl halide simultaneously with mixing of the bisphenol and the diacyl halide to commence the polymerization esterification reaction, and the molar proportion of the fluorine-substituted alcohol is about 0.1 mole percent to about 25 mole percent.