US4301016A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Borehole drilling fluid and method
Assignee: Baroid Technology Inc
•
Filing: 1979-02-02
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Granted: 1981-11-17
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Expires: 1999-02-02
Abstract
Abstract An improved drilling fluid and method for drilling a borehole, the drilling fluid comprising an aqueous dispersion of an emulsion polymerized latex comprised of an interpolymer of an olefinically unsaturated carboxylic acid monomer and at least one other, non-carboxylated polymerizable monomer, the latex being of a type which undergoes rapid increase in viscosity upon the addition of a sufficient amount of a basic material.
Inventors
- 👤 David B. Carriere
- 👤 Rodrigue V. Lauzon
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 18:34
CPC Classifications
C; C09; C09K; C09K8/00; C09K8/02; C09K8/04; C09K8/14; C09K8/18; C09K8/22; C09K8/24; Y; Y10; Y10S; Y10S507/00; Y10S507/904; Y10S507/907
Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
197 words
In a method for drilling a borehole wherein a drilling fluid is circulated within said borehole while drilling, the improvement comprising circulating in said borehole an aqueous composition comprising an effective amount of an emulsion polymerized polymer in water latex consisting of (1) an interpolymer of an olefinically unsaturated carboxylic acid monomer selected from the group consisting of acrylic acid, methacrylic acid and mixtures thereof and at least one other non-carboxylated polymerizable monomer having the general formula: ##STR10## wherein R 1 is a member of the class consisting of alkyl groups having from 1 to 30 carbon atoms and R 2 is hydrogen or a methyl group, said interpolymer having a molecular weight of from about 1,000,000 to about 4,000,000, and (2) water the API apparent viscosity of an aqueous dispersion of said latex containing 0.5 lbs. of polymer solids per barrel of said dispersion in a pH range above about 6 being at least 600% greater than the API apparent viscosity of said mixture in a pH range below about 6, the pH of said aqueous composition being above about 7, said latex serving to viscosify said drilling fluid without the addition of a clay viscosifier.
Claim 2
Dependent Claim
197 words
In a method for drilling a borehole wherein a drilling fluid is circulated within said borehole while drilling, the improvement comprising circulating in said borehole an aqueous composition comprising an effective amount of an emulsion polymerized polymer in water latex consisting of (1) an interpolymer of an olefinically unsaturated carboxylic acid monomer selected from the group consisting of acrylic acid, methacrylic acid and mixtures thereof and at least one other non-carboxylated polymerizable monomer having the general formula: ##STR10## wherein R 1 is a member of the class consisting of alkyl groups having from 1 to 30 carbon atoms and R 2 is hydrogen or a methyl group, said interpolymer having a molecular weight of from about 1,000,000 to about 4,000,000, and (2) water the API apparent viscosity of an aqueous dispersion of said latex containing 0.5 lbs. of polymer solids per barrel of said dispersion in a pH range above about 6 being at least 600% greater than the API apparent viscosity of said mixture in a pH range below about 6, the pH of said aqueous composition being above about 7, said latex serving to viscosify said drilling fluid without the addition of a clay viscosifier.
Claim 3
Dependent Claim
12 words
The method of claim 1 wherein said aqueous composition comprises fresh water.
Claim 4
Dependent Claim
23 words
The method of claim 1 wherein said aqueous composition comprises up to 2 lbs. of polymer solids per barrel of said aqueous composition.
Claim 5
Dependent Claim
26 words
The method of claim 1 wherein said carboxylic acid is present in said interpolymer in an amount of from about 10 to about 70% by weight.
Claim 6
Dependent Claim
27 words
The method of claim 1 wherein said non-carboxylated polymerizable monomer is present in said interpolymer in an amount of from about 30 to about 80% by weight.
Claim 7
Dependent Claim
26 words
The method of claim 1 wherein said non-carboxylated polymerizable monomer is selected from the class consisting of methyl acrylate, ethyl acrylate, methyl methacrylate and mixtures thereof.
Claim 8
Dependent Claim
26 words
The method of claim 1 wherein said aqueous composition includes sufficient suspended, finely divided solids to form a filter cake on the wall of said borehole.
Claim 9
Dependent Claim
14 words
The method of claim 7 wherein said finely divided solids comprise an argillaceous material.
Claim 10
Dependent Claim
60 words
The method of claim 1 wherein said aqueous composition includes an indicating amount of an acid-base indicator, said indicator being of a type which undergoes a color change in said aqueous mixture at about the pH where the apparent viscosity is about at least 150% greater than the apparent viscosity of said mixture in a pH range below about 6.
Claim 11
Dependent Claim
28 words
The method of claim 1 including the further step of reducing the pH of said aqueous composition below about 7 and circulating said aqueous composition within said borehole.
Claim 12
Independent Claim
228 words
A method of preparing a water-based drilling fluid useful in drilling a borehole comprising: incorporating into an aqueous carrier an effective amount of an emulsion polymerized polymer in water latex consisting of (1) an interpolymer of an olefinically unsaturated carboxylic monomer selected from the class consisting of acrylic acid, methacrylic acid and mixtures thereof and at least one other, non-carboxylated polymerizable monomer having the general formula: ##STR11## wherein R 1 is a member of the class consisting of alkyl groups having from 1 to 30 carbon atoms and R 2 is hydrogen or a methyl group, said interpolymer having a molecular weight of from about 1,000,000 to about 4,000,000, and (2) water, the apparent API viscosity of an aqueous dispersion of said latex containing 0.5 lbs. of polymer solids per barrel of said mixture in a pH range above about 6 being at least 600% greater than the API apparent viscosity of said dispersion in a pH range below about 6, said latex serving to viscosify said drilling fluid without the addition of a clay viscosifier; adding to said aqueous carrier-latex composition a basic material in an amount such that the pH of said aqueous carrier-latex composition is at least about 7; and incorporating in said aqueous carrier-latex composition a sufficient amount of suspended, finely divided solids to form a filter cake on the wall of said borehole.
Claim 13
Independent Claim
228 words
A method of preparing a water-based drilling fluid useful in drilling a borehole comprising: incorporating into an aqueous carrier an effective amount of an emulsion polymerized polymer in water latex consisting of (1) an interpolymer of an olefinically unsaturated carboxylic monomer selected from the class consisting of acrylic acid, methacrylic acid and mixtures thereof and at least one other, non-carboxylated polymerizable monomer having the general formula: ##STR11## wherein R 1 is a member of the class consisting of alkyl groups having from 1 to 30 carbon atoms and R 2 is hydrogen or a methyl group, said interpolymer having a molecular weight of from about 1,000,000 to about 4,000,000, and (2) water, the apparent API viscosity of an aqueous dispersion of said latex containing 0.5 lbs. of polymer solids per barrel of said mixture in a pH range above about 6 being at least 600% greater than the API apparent viscosity of said dispersion in a pH range below about 6, said latex serving to viscosify said drilling fluid without the addition of a clay viscosifier; adding to said aqueous carrier-latex composition a basic material in an amount such that the pH of said aqueous carrier-latex composition is at least about 7; and incorporating in said aqueous carrier-latex composition a sufficient amount of suspended, finely divided solids to form a filter cake on the wall of said borehole.
Claim 14
Dependent Claim
12 words
The method of claim 11 wherein said aqueous carrier comprises fresh water.
Claim 15
Dependent Claim
24 words
The method of claim 11 wherein said aqueous carrier-latex composition comprises up to 2 lbs. of polymer solids per barrel of said aqueous composition.
Claim 16
Dependent Claim
26 words
The method of claim 11 wherein said carboxylic acid is present in said interpolymer in an amount of from about 10 to about 70% by weight.
Claim 17
Dependent Claim
27 words
The method of claim 11 wherein said non-carboxylated polymerizable monomer is present in said interpolymer in an amount of from about 30 to about 80% by weight.
Claim 18
Dependent Claim
26 words
The method of claim 11 wherein said non-carboxylated polymerizable monomer is selected from the class consisting of methyl acrylate, ethyl acrylate, methyl methacrylate and mixtures thereof.
Claim 19
Dependent Claim
14 words
The method of claim 11 wherein said finely divided solids comprise an argillaceous material.
Claim 20
Dependent Claim
64 words
The method of claim 11 including incorporating in said carrier-latex aqueous composition an indicating amount of an acid-base indicator, said indicator being of a type which undergoes a color change in said aqueous dispersion at about the pH where the API apparent viscosity is about at least 150% greater than the API apparent viscosity of said dispersion in a pH range below about 6.
Claim 21
Dependent Claim
28 words
The method of claim 11 wherein said basic material is selected from the class consisting of alkali metal hydroxides, ammonium hydroxide, sodium carbonate, diammonium phosphate and mixtures thereof.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1984-11-16 | 1985-05-18 | 1985-11-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1988-11-16 | 1989-05-18 | 1989-11-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1992-11-16 | 1993-05-18 | 1993-11-17 | $7700.00 | Window Closed / Lapsed |