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US4313014A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the separation of cyclohexene

Assignee: Toray Industries Inc
•
Filing: 1980-08-27
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Granted: 1982-01-26
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Expires: 2000-08-27
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Abstract

Abstract In the separation of cyclohexene from a feed which contains cyclohexene and cyclohexane, the feed is contacted with a type X and/or type Y aluminosilicate zeolite, thereby adsorbing cyclohexene selectively on the zeolite, and then the zeolite which adsorbed cyclohexene is contacted with a trimethylbenzene to desorb cyclohexene.

Inventors

  • 👤 Tsuneyuki Kondo
  • 👤 Kishio Miwa
  • 👤 Takehisa Inoue

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 18:29
CPC Classifications
C; C07; C07C; C07C7/00; C07C7/12; C07C7/13

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 56 words
A process for the separation of cyclohexene comprising the steps of: contacting a feed which contains a mixture of cyclohexene and cyclohexane with a type X aluminosilicate zeolite which contains sodium cations, whereby cyclohexene is selectively adsorbed thereon, and then contacting said zeolite which adsorbed cyclohexene with at least one trimethylbenzene, whereby cyclohexene is desorbed therefrom.
Claim 2
Dependent Claim 56 words
A process for the separation of cyclohexene comprising the steps of: contacting a feed which contains a mixture of cyclohexene and cyclohexane with a type X aluminosilicate zeolite which contains sodium cations, whereby cyclohexene is selectively adsorbed thereon, and then contacting said zeolite which adsorbed cyclohexene with at least one trimethylbenzene, whereby cyclohexene is desorbed therefrom.
Claim 3
Dependent Claim 83 words
A process for the separation of cyclohexene comprising the steps of: (a) contacting a feed which contains a mixture of cyclohexene and cyclohexane with a type X aluminosilicate zeolite adsorbent which contains sodium cations, whereby a greater percentage of cyclohexene than other components of said feed is adsorbed on said adsorbent; (b) contacting said adsorbent with a desorbent which contains at least one trimethylbenzene, whereby cyclohexene is desorbed therefrom; and (c) re-using in step (a) said adsorbent which desorbed cyclohexene and adsorbed trimethylbenzene.
Claim 4
Dependent Claim 83 words
A process for the separation of cyclohexene comprising the steps of: (a) contacting a feed which contains a mixture of cyclohexene and cyclohexane with a type X aluminosilicate zeolite adsorbent which contains sodium cations, whereby a greater percentage of cyclohexene than other components of said feed is adsorbed on said adsorbent; (b) contacting said adsorbent with a desorbent which contains at least one trimethylbenzene, whereby cyclohexene is desorbed therefrom; and (c) re-using in step (a) said adsorbent which desorbed cyclohexene and adsorbed trimethylbenzene.
Claim 5
Dependent Claim 23 words
A process according to claim 1 or 2, wherein said trimethylbenzene is a member selected from the group consisting of 1,2,3-trimethylbenzene and 1,3,5-trimethylbenzene.
Claim 6
Dependent Claim 11 words
A process according to claim 3, wherein said trimethylbenzene is 1,3,5-trimethylbenzene.
Claim 7
Dependent Claim 43 words
A process according to claim 1 or 2, wherein said adsorption and desorption steps are carried out at a temperature in the range of 0° to 300° C. and at a pressure in the range of atmospheric pressure to 40 kg/cm 2 .
Claim 8
Dependent Claim 42 words
A process according to claim 5, wherein said adsorption and desorption steps are carried out at a temperature in the range of room temperature to 200° C. and at a pressure in the range of atmospheric pressure to 30 kg/cm 2 .
Claim 9
Dependent Claim 14 words
A process according to claim 1 or 2, wherein said zeolite contains sodium cations.
Claim 10
Dependent Claim 14 words
A process according to claim 1 or 2, wherein said zeolite contains potassium cations.

References Cited (Backward Citations)

US4014949A Cited
US4159284A Cited
US4069172A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-01-25 1985-07-27 1986-01-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-01-25 1989-07-27 1990-01-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-01-25 1993-07-27 1994-01-26 $7700.00 Window Closed / Lapsed

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