Reaction products of an olefin, a norbornene and a cyclopentadiene

Claim 2

A process for preparing a product mixture containing a norbornene and a tetracyclododecene in a desired molar ratio which is in the range of about 95/5 to 5/95 comprising heating in a reactor an olefin of 2 to 22 carbon atoms, a cyclopentadiene or a dicyclopentadiene, and a norbornene; maintaining ratio of reactants, temperature, pressure, and residence time in the reactor such that formation of the norbornene and the tetracyclododecene is favored; and recovering the norbornene and the tetracyclododecene from the product mixture.

Claim 3

Process of claim 1 wherein the olefin is selected from monoolefins and diolefins of 2 to 12 carbon atoms, and the norbornene and the tetracyclododecene are defined respectively as follows: ##STR2## where R 1 and R 2 are independently selected from hydrogen, alkyl and alkylene groups of 1 to 20 carbon atoms, provided that total number of carbon atoms for R 1 and R 2 does not exceed 20; and where R 1 and R 2 , together with the ring carbons to which they are bonded, form one or two saturated or unsaturated rings of 6 to 16 carbon atoms.

Claim 4

Process of claim 3 wherein R 1 and R 2 are independently selected from hydrogen, alkyl and alkylene groups of 1 to 10 carbon atoms.

Claim 5

Process of claim 3 wherein the olefin contains 2 to 4 carbon atoms; and R 1 and R 2 are individually selected from hydrogen and alkyl groups of 1 to 2 carbon atoms, provided that one of R 1 and R 2 is hydrogen.

Claim 6

Process of claim 3 wherein temperature of the reaction is in the range of 100° to 400° C., pressure is 100 to 5000 psi, and residence time of 0.1 to 5 hours.

Claim 7

Process of claim 4 wherein the reaction is carried out at a temperature of 200° to 300° C., pressure of 500 to 4000 psi, and residence time of 0.5 to 2 hours.

Claim 8

Process of claim 3 wherein the relative ratio of the reactants is as follows: 1 to 20 moles of the olefin, 1 to 5 moles of cyclopentadiene or one-half of this amount of dicyclopentadiene, and 1 to 5 moles of the norbornene.

Claim 9

Process of claim 4 wherein the relative ratio of the reactants is as follows: 2 to 10 moles of the olefin, 1 to 5 moles of cyclopentadiene or one-half of this amount of dicyclopentadiene, and 1 to 5 moles of the norbornene.

Claim 10

Process of claim 8 wherein the reaction is conducted at a relatively high temperature of the range of 100° to 400° C., relatively low olefin level, relatively high cyclopentadiene or dicyclopentadiene level, and relatively high norbornene level to produce mostly the tetracyclododecene.

Claim 11

Process of claim 9 which includes the step of recycling a portion of the norbornene to the reactor.

Claim 12

Process of claim 6 which includes step of recycling a portion of the norbornene to the reactor, the quantity of recycled norbornene being sufficient to maintain the process on a continuous basis.

Claim 13

Process of claim 11 wherein the reaction is carried out at 240° to 280° C. and about 2000 psi.