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US4366002A Expired / Lapsed US ⏱️ 0.0 years remaining

Non-volatile hot stripper

Assignee: Henkel Corp
•
Filing: 1981-10-13
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Granted: 1982-12-28
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Expires: 2001-10-13
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Abstract

Abstract An aqueous alkaline composition having increased effectiveness and bath life when used at elevated temperatures to remove siccative coatings from substrates coated therewith containing one or more alkaline compounds and at least two of the following three materials: tetrahydrofurfuryl alcohol, an ethoxylated furfuryl alcohol and an ethoxylated tetrahydrofurfuryl alcohol; and preferably containing one or more of a sequestering agent, a composition-stabilizing compound, and a surfactant.

Inventors

  • 👤 Carmen M. Carandang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 18:12
CPC Classifications
C; C09; C09D; C09D9/00

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 91 words
An aqueous alkaline composition for use at elevated temperatures to remove siccative coatings from substrates coated therewith comprising one or more alkaline compounds in an amount effective to impart a pH to the composition of about 9.5 to about 14+ and at least two of the following three materials: tetrahydrofurfuryl alcohol and the ethoxylated materials of the formula RO(CH.sub.2 CH.sub.2 O).sub.n H wherein R is ##STR2## and n is about 0.5 to about 10, said ingredients being present in amounts effective to remove the siccative coating from a substrate coated therewith.
Claim 2
Dependent Claim 91 words
An aqueous alkaline composition for use at elevated temperatures to remove siccative coatings from substrates coated therewith comprising one or more alkaline compounds in an amount effective to impart a pH to the composition of about 9.5 to about 14+ and at least two of the following three materials: tetrahydrofurfuryl alcohol and the ethoxylated materials of the formula RO(CH.sub.2 CH.sub.2 O).sub.n H wherein R is ##STR2## and n is about 0.5 to about 10, said ingredients being present in amounts effective to remove the siccative coating from a substrate coated therewith.
Claim 3
Dependent Claim 29 words
A composition according to claim 1 wherein the alkaline compound is present in an amount effective to impart a pH to the composition of about 12 to about 14+.
Claim 4
Dependent Claim 24 words
A composition according to claim 1 including a sequestering agent in an amount effective to substantially prevent the formation of precipitants in the composition.
Claim 5
Dependent Claim 43 words
A composition according to claim 3 including a composition-stabilizing compound selected from the group consisting of aliphatic primary alcohols, aliphatic secondary alcohols, alkyl amines, and mixtures thereof, said composition-stabilizing compound being present in an amount effective to substantially prevent separation of said composition.
Claim 6
Dependent Claim 52 words
A composition according to claim 1 including at least about 80 g/l of said alkaline compound, at least about 1 g/l of a sequestering agent, and at least about 10 g/l of a composition-stabilizing compound selected from the group consisting of aliphatic primary alcohols, aliphatic secondary alcohols, alkyl amines and mixtures thereof.
Claim 7
Dependent Claim 25 words
A composition according to claim 5 wherein the ethoxylated material is the reaction product of furfuryl alcohol and wherein n is about 0.5 to 1.5.
Claim 8
Dependent Claim 14 words
A composition according to claim 6 wherein n is about 0.85 to about 1.08.
Claim 9
Dependent Claim 26 words
A composition according to claim 5 wherein the ethoxylated material is the reaction product of tetrahydrofurfuryl alcohol and wherein n is about 3 to about 8.
Claim 10
Dependent Claim 31 words
A composition according to claim 5 wherein the alkaline compound is selected from the group consisting of alkali metal and ammonium hydroxides, carbonates, silicates and phosphates, and amines, and mixtures thereof.
Claim 11
Dependent Claim 24 words
A composition according to claim 5, 6 or 7 wherein the ethoxylated material is present in an amount of at least about 5 g/l.
Claim 12
Dependent Claim 17 words
A composition according to claim 5 including at least about 0.5 g/l of one or more surfactants.
Claim 13
Dependent Claim 98 words
A composition according to claim 1 comprising an alkaline component in an amount of about 150 to about 350 g/l, said alkaline component comprising about 3.5 to about 350 g/l of sodium hydroxide and about 3.5 to about 350 g/l of potassium hydroxide, about 1 to about 100 g/l of a sequestering agent, about 50 to about 100 g/l of a composition-stabilizing compound selected from the group consisting of methanol, monoethanolamine, diethylene glycol, n-butyl amine and mixtures thereof, about 2.5 to about 200 g/l of tetrahydrofurfuryl alcohol, and about 5 to about 200 g/l of an ethoxylated material.
Claim 14
Dependent Claim 14 words
A composition according to claim 12 wherein n is about 0.85 to about 1.08.
Claim 15
Dependent Claim 41 words
A method of stripping siccative coatings from substrates coated therewith comprising contacting the coated substrate with the composition of claim 1, 5 or 12 at a composition temperature effective and a time sufficient to remove the siccative coating from the substrate.
Claim 16
Dependent Claim 31 words
An aqueous concentrate which when added to water at a concentration of about 10 to about 99% by volume produces an aqueous alkaline composition according to claim 1, 5 or 12.
Claim 17
Dependent Claim 153 words
An aqueous concentrate for use in forming an aqueous alkaline solution which is effective at elevated temperatures in stripping siccative coatings from substrates coated therewith, comprising about 10 to about 85 wt. % water, an alkaline component in an amount of about 10 to about 50 wt. %, said alkaline component comprising about 0.5 to about 50 wt. % of sodium hydroxide and about 0.5 to about 50 wt % of potassium hydroxide, about 0.1 to about 10 wt. % of a sequestering agent, about 1 to about 20 wt. % of a composition-stabilizing compound selected from the group consisting of methanol, monoethanolamine, diethylene glycol, n-butyl amine, and mixtures thereof, about 1 to about 10 wt. % of tetrahydrofurfuryl alcohol and about 1 to about 20 wt. % of the reaction product of furfuryl alcohol and ethylene oxide represented by the formula of claim 1 wherein n is about 0.5 to about 1.5.
Claim 18
Dependent Claim 13 words
The concentrate of claim 16 wherein n is about 0.85 to about 1.08.
Claim 19
Dependent Claim 54 words
An aqueous composition for use in replenishing a hot stripper composition, comprising one or more alkaline compounds in an amount of about 1 to about 200 g/l, at least about 200 g/l of tetrahydrofurfuryl alcohol, and an ethoxylated material as defined in claim 1 in an amount of about 20 to about 200 g/l.
Claim 20
Dependent Claim 16 words
A method according to claim 14 wherein the siccative coating is a cathodically electrodeposited paint film.
Claim 21
Dependent Claim 54 words
A composition according to claim 1 wherein the total amount of the ingredients comprising the mixture of at least two of the said materials THFA and said ethoxylated materials is at least about 7.5 g/l, with at least two of said ingredients each being present in an amount of at least about 2.5 g/l.
Claim 22
Dependent Claim 17 words
A composition according to claim 1 including about 4 to about 100 g/l of said tetrahydrofurfuryl alcohol.
Claim 23
Dependent Claim 17 words
A composition according to claim 1 including about 10 to about 100 g/l of said ethoxylated material.

References Cited (Backward Citations)

US3335092A Cited
US3551340A Cited
US3847839A Cited
US4090001A Cited
DE2436488A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1985-12-27 1986-06-28 1986-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1989-12-27 1990-06-28 1990-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1993-12-27 1994-06-28 1994-12-28 $7700.00 Window Closed / Lapsed

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