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Memory alloys based on copper or nickel solid solution alloys having oxide inclusions

Assignee: BBC BROWN BOVERI & Co Ltd
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Filing: 1981-03-02
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Granted: 1983-06-21
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Expires: 2001-03-02
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Abstract

Abstract Fine grained copper-based or nickel-based memory alloys having a matrix of beta -high temperature phase with metal oxide particles dispersed in the matrix which act to retard grain growth have improved mechanical characteristics such as elongation, toughness and workability, compared to cast and worked alloys. These alloys are produced by powder metallurgy.

Inventors

  • 👤 Keith Melton
  • 👤 Olivier Mercier
  • 👤 Helmut Riegger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 02:37
CPC Classifications
C; C22; C22C; C22C1/00; C22C1/04; C22C1/05; C22C1/059; C22F; C22F1/00; C22F1/006

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 122 words
A memory alloy prepared by powder metal technology consisting essentially of aluminum and at least one metal selected from the group consisting of copper, nickel, or copper and nickel having the β-phase solid solution structure which forms a matrix having a fine grained texture with a crystallite diameter of at most 100 μm, the Cu/Al or Cu/Al/Ni alloy containing Al in the range of 10.6-15.0 percent, and Ni in the range of 0-6 percent, the balance being copper, and the Ni/Al alloy containing Al in the range of 17-26%, the balance being Ni, and, dispersed in said matrix, 0.5 to 2.0 percent of finely divided inclusions of at least one metal oxide having a particle size of 1.0 nm to 1.0 micron.
Claim 2
Dependent Claim 122 words
A memory alloy prepared by powder metal technology consisting essentially of aluminum and at least one metal selected from the group consisting of copper, nickel, or copper and nickel having the β-phase solid solution structure which forms a matrix having a fine grained texture with a crystallite diameter of at most 100 μm, the Cu/Al or Cu/Al/Ni alloy containing Al in the range of 10.6-15.0 percent, and Ni in the range of 0-6 percent, the balance being copper, and the Ni/Al alloy containing Al in the range of 17-26%, the balance being Ni, and, dispersed in said matrix, 0.5 to 2.0 percent of finely divided inclusions of at least one metal oxide having a particle size of 1.0 nm to 1.0 micron.
Claim 3
Dependent Claim 16 words
The memory alloy of claim 1, wherein said inclusions are at least in part aluminum oxide.
Claim 4
Dependent Claim 24 words
The memory alloy of claim 1, wherein the metal oxide inclusions comprise 0.5 to 2% by weight of the total mass of the alloy.
Claim 5
Dependent Claim 25 words
The memory alloy of claim 1, wherein nickel is partially or completely replaced by a metal selected from the group consisting of manganese, iron, cobalt.
Claim 6
Dependent Claim 28 words
The memory alloy of claim 1, wherein said β-phase matrix consists essentially of 17 to 26% by weight of aluminum, the balance nickel and cobalt and inevitable impurities.
Claim 7
Dependent Claim 14 words
The memory alloy of claim 1, having an average crystallite diameter of 30 μm.
Claim 8
Dependent Claim 18 words
The memory alloy of claim 6 wherein the average crystallite diameter remains constant during annealing at 950° C.
Claim 9
Dependent Claim 21 words
The memory alloy of claim 1, having a martensite transition temperature M S in the temperature range -200° to +300° C.

References Cited (Backward Citations)

US2947068A Cited
US3783037A Cited
US4019925A Cited
US4285739A Cited
US4292079A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-06-20 1986-12-20 1987-06-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-06-20 1990-12-20 1991-06-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-06-20 1994-12-20 1995-06-21 $7700.00 Window Closed / Lapsed

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