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Heat curable epoxy resin compositions

Assignee: Lockheed Martin Corp
•
Filing: 1981-09-28
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Granted: 1983-09-13
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Expires: 2001-09-28
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Abstract

Abstract The invention relates to heat curable epoxy resin compositions consisting of an epoxy resin containing, on average, more than one epoxide group per molecule, an aromatic onium salt as catalyst, a copper complex compound as co-catalyst, and a light stabilizer. These compositions are less sensitive to UV irradiation and have a good shelf life at room temperature as well as a good high temperature reactivity.

Inventors

  • 👤 Sameer H. Eldin
  • 👤 Bruno Schreiber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 11:38
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/02; C08G65/04; C08G65/06; C08G65/08; C08G65/10; C08G65/105; C08G59/00; C08G59/18; C08G59/68

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 86 words
A heat curable epoxy resin composition which contains (a) an epoxy compound or an epoxy resin containing on average more than one epoxide group per molecule, (b) a catalytic amount of an aromatic onium salt, (c) a catalytic amount of an organic copper compound, wherein the copper is complexed, as co-catalyst, and (d) from 0.05 to 2 parts, based on 100 parts of epoxy resin, of a light stabilizer selected from the group consisting of the 2-hydroxybenzophenones, the 2-hydroxyphenylbenzotriazoles, 2,4-dibenzoylresorcinol, the arylsubstituted acrylates and the salicylates.
Claim 2
Dependent Claim 86 words
A heat curable epoxy resin composition which contains (a) an epoxy compound or an epoxy resin containing on average more than one epoxide group per molecule, (b) a catalytic amount of an aromatic onium salt, (c) a catalytic amount of an organic copper compound, wherein the copper is complexed, as co-catalyst, and (d) from 0.05 to 2 parts, based on 100 parts of epoxy resin, of a light stabilizer selected from the group consisting of the 2-hydroxybenzophenones, the 2-hydroxyphenylbenzotriazoles, 2,4-dibenzoylresorcinol, the arylsubstituted acrylates and the salicylates.
Claim 3
Dependent Claim 129 words
A composition according to claim 1 which contains (a) an aromatic, aliphatic or cycloaliphatic epoxy compound containing at least two epoxide groups per molecule, (b) an aromatic onium salt of formula I [Ar.sub.m Q]+·[MX.sub.n ]- (I), wherein each Ar is an aromatic radical, Q is iodine, sulfur or selenium, M is a metal or metalloid, X is halogen, m is 2 or 3 and greater by one than the valency of Q, and n is 4, 5 or 6 and greater by one than the valency of M, (c) an organic copper complex compound, and (d) from 0.05 to 2 parts, based on 100 parts of epoxy resin, of a light stabilizer selected from the group consisting of the 2-hydroxybenzophenones, the 2-hydroxyphenylbenzotriazoles, 2,4-dibenzoylresorcinol, the arylsubstituted acrylates and the salicylates.
Claim 4
Dependent Claim 21 words
A composition according to claim 1, wherein component (a) is a di- or polyglycidyl ether or a di- or polyglycidyl ester.
Claim 5
Dependent Claim 20 words
A composition according to claim 1, wherein component (a) is a di- or polyglycidyl ether of a diphenol or polyphenol.
Claim 6
Dependent Claim 17 words
A composition according to claim 1, wherein component (b) is an iodonium salt or a sulfonium salt.
Claim 7
Dependent Claim 126 words
A composition according to claim 2, wherein component (b) is an onium salt of the formula I, wherein each Ar independently is phenyl, naphthyl, or phenyl which is substituted by C 1 -C 4 alkyl, phenyl, phenoxy, halogen, nitro or C 1 -C 4 alkoxy, or two symbols Ar together are a divalent radical of the formula II ##STR2## wherein Y is a direct bond, --O--, --S-- or --CH 2 --, and each R 1 is hydrogen, C 1 --C 4 alkyl, halogen, nitro or C 1 -C 4 alkoxy, M is a metal or metalloid atom selected from the series consisting of B, P, As, Sb, Sn, Bi and Fe, X is fluorine or chlorine, and m and n are as defined for formula I.
Claim 8
Dependent Claim 49 words
A composition according to claim 2, wherein component (b) is a compound of the formula I, in which the anion [MX n ] - is one of the anions BF 4 - , PF 6 - , AsF 6 - , SbCl 6 - or SbF 6 - .
Claim 9
Dependent Claim 25 words
A composition according to claim 1, wherein component (c) is a copper complex in which the complex forming ligand is acetylacetone or a homolog thereof.
Claim 10
Dependent Claim 11 words
A composition according to claim 1 wherein component (d) is 2-[2-hydroxy-3,5-di(α,α-dimethylbenzyl)phenyl]-2H-benzotriazole.

References Cited (Backward Citations)

US3287314A Cited
US3461287A Cited
US4173551A Cited
US4283312A Cited
US4238587A Cited
US4342673A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-09-12 1987-03-14 1987-09-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-09-12 1991-03-14 1991-09-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-09-12 1995-03-14 1995-09-13 $7700.00 Window Closed / Lapsed

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