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Dichroic liquid crystal compositions made with asymmetric tris-azo dyes

Assignee: Amespace Inc
•
Filing: 1981-11-12
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Granted: 1983-10-25
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Expires: 2001-11-12
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Abstract

Abstract Novel asymmetric tris-azo dye compositions and a liquid crystal composition containing the asymmetric tris-azo dye compositions are disclosed. The asymmetric dye compositions having asymmetric terminal groups have the general formula: ##STR1## wherein R 1 is one of the three following groups: ##STR2## 5-nitrothiazolyl group, 4-cyanophenyl group, and 4-nitrophenyl; wherein R 2 , R 3 , R 4 and R 5 are selected from the group consisting of hydrogen, alkyl, halogen and alkoxy, and R 6 is selected from the group consisting of N,N-diethylamino-3-methylphenyl; N,N-diethylamino-3-methylphenyl; N,N-diethylamino-3,5-dimethylphenyl; 2-pentylperimidyl; N-ethylamino-1-naphthyl; N,N-dimethylamino-1-naphthyl; and N,N-diethylamino-1-naphthyl. When the asymmetric tris-azo dichroic dyes are used as a guest in a host liquid crystal material, they form a novel liquid crystal composition for use in liquid crystal displays.

Inventors

  • 👤 Siegfried Aftergut
  • 👤 Herbert S. Cole

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 08:09
CPC Classifications
C; C09; C09B; C09B31/00; C09B31/16; C09B31/26; C09B31/28; C09B31/18; C09K; C09K19/00; C09K19/52; C09K19/60; C09K19/601

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 79 words
A liquid crystal composition for use in a liquid crystal display, comprising: a host liquid crystal material; and a guest tris-azo dichroic dye dissolved in said host liquid crystal material, said dichroic dye having a 5-nitrothiazolyl terminal group and the general formula, ##STR16## wherein R 2 , R 3 , R 4 and R 5 , are selected from the group consisting of hydrogen, alkyl halogen and alkoxy, and R 6 is selected from the group consisting of ##STR17##
Claim 2
Dependent Claim 79 words
A liquid crystal composition for use in a liquid crystal display, comprising: a host liquid crystal material; and a guest tris-azo dichroic dye dissolved in said host liquid crystal material, said dichroic dye having a 5-nitrothiazolyl terminal group and the general formula, ##STR16## wherein R 2 , R 3 , R 4 and R 5 , are selected from the group consisting of hydrogen, alkyl halogen and alkoxy, and R 6 is selected from the group consisting of ##STR17##
Claim 3
Dependent Claim 17 words
The liquid crystal composition of claim 1, wherein R 2 =R 3 =R 4 =R 5 .
Claim 4
Dependent Claim 37 words
The liquid crystal composition of claim 1, wherein about 0.05% by weight to about 1.0% by weight (based upon the weight of the liquid crystal) of the guest dichroic dye is dissolved in the host liquid crystal.
Claim 5
Dependent Claim 46 words
The liquid crystal composition of claim 1, wherein the host material is a nematic liquid crystal of positive or negative dielectric anisotropy, a cholesteric liquid crystal of positive or negative dielectric anisotropy and mixtures thereof or any of the foregoing modified with other optically active compounds.
Claim 6
Dependent Claim 12 words
The liquid crystal composition of claim 1, wherein the alkyl is methyl.
Claim 7
Dependent Claim 12 words
The liquid crystal composition of claim 1, wherein the alkoxy is methoxy.
Claim 8
Dependent Claim 20 words
The liquid crystal composition of claim 1, wherein the halogen is selected from the group consisting of chlorine and bromine.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-10-24 1987-04-25 1987-10-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-10-24 1991-04-25 1991-10-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-10-24 1995-04-25 1995-10-25 $7700.00 Window Closed / Lapsed

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