Soil resistant yarn finish for synthetic organic polymer yarn

Claim 2

A yarn finish composition comprising: a. 15 to 80 weight percent of a quaternary ammonium salt selected from the group consisting of alkyl dodecyl ammonium salt and cocotrialkyl ammonium salt, wherein the alkyl is methyl or ethyl and the anion of the salt is selected from the group consisting of chloride, bromide, iodide, sulfate, ethosulfate, methosulfate and mixtures thereof; and b. 20 to 85 weight percent of a fluorochemical compound having the formula ##STR3## wherein the attachment of the fluorinated radials and the radicals CO 2 B to the nucleus is in asymmetrical positions with respect to rotation about the axis through the center of the nucleus; wherein "X" is fluorine, or perfluoroalkoxy of 1 to 6 carbon atoms, and m has arithmetic mean between 2 and 20; n is zero or unity; "W" and "Y" are alkylene, cycloalkylene or alkyleneoxy radicals of combined chain length from 2 to 20 atoms; (CF 2 ) m and "Y" have each at least 2 carbon atoms in the main chain; "Z" is oxygen and p is 1, or "Z" is nitrogen and p is 2; q is an integer of at least 2 but not greater than 5; "B" is CH 2 RCHOH or is CH 2 RCHOCH 2 RCHOH where "R" is hydrogen or methyl, or "B" is CH 2 CH(OH)CH 2 Q where Q is halogen, hydroxy, or nitrile; or "B" is CH 2 CH(OH)CH 2 OCH 2 -CH(OH)CH 2 Q; and r is an integer of at least 1 but not greater than q; and X(CF 2 ) m , W and Y are straight chains, branched chains or cyclic; and wherein the substituent chains of the above general formulas are the same or different.

Claim 3

An emulsion of water and 1.5 to 40 percent by weight of said emulsion of said composition as defined in claim 1.

Claim 4

The composition of claim 1 wherein the anion is chloride.

Claim 5

The composition of claim 1 wherein the anion is sulfate.

Claim 6

The composition of claim 1 wherein the quaternary ammonium salt is in a solution of water, isopropanol and propylene glycol.

Claim 7

The composition of claim 1 wherein the fluorochemical compound is a trimellitate, a pyromellitate, or a bis(diamide)/ester of trimellitic acid or of pyromellitic acid, wherein each fluorinated radical, of formula X(CF 2 ) m W(CONH) n Y, has a main chain containing at least six carbon atoms and contains at least four perfluorinated carbon atoms in the radical.

Claim 8

The composition of claim 1 wherein the fluorochemical compound is a mixture of pyromellitates having the structure ##STR4## A=(CH 2 ) 2 (CF 2 ) n CF 3 where n is 5-13 B=CH 2 CHOHCH 2 Cl.

Claim 9

A polyamide yarn having incorporated therewith the composition of claim 1.

Claim 10

A polyester yarn having incorporated therewith the composition of claim 1.

Claim 11

The polyamide yarn product having incorporated therewith the composition of claim 1.

Claim 12

The polyester yarn product having incorporated therewith the composition of claim 1.

Claim 13

A spin finish for yarn, made from synthetic organic polymer, to be processed into a yarn that is oil repellent and resistant to soiling, said spin finish comprising: a. 1.5 to 25 percent by weight of said spin finish of a first noncontinuous phase comprising: i. 15 to 80 weight percent of a quaternary ammonium salt selected from the group consisting of trialkyl dodecyl ammonium salt and cocotrialkyl ammonium salt, wherein the alkyl is methyl or ethyl and the anion of the salt is selected from the group consisting of chloride, bromide, iodide, sulfate, ethosulfate, methosulfate and mixtures thereof; and ii. 20 to 85 weight percent of a fluorochemical compound having the formula ##STR5## wherein the attachment of the fluorinated radicals and the radicals of CO 2 B to the nucleus is in asymmetrical positions with respect to rotation about the axis through the center of the nucleus; wherein "X" is fluorine, or perfluoroalkoxy of 1 to 6 carbon atoms, and m has arithmetic mean between 2 and 20; n is zero or unity; "W" and "Y" are alkylene, cycloalkylene or alkyleneoxy radicals of combined chain length from 2 to 20 atoms; (CF 2 ) m and "Y" have each at least 2 carbon atoms in the main chain; "Z" is oxygen and p is 1, or "Z" is nitrogen and p is 2; q is an integer of at least 2 but not greater than 5; "B" is CH 2 RCHOH or is CH 2 RCHOCH 2 RCHOH where "R" is hydrogen or methyl, or "B" is CH 2 CH(OH)CH 2 Q where Q is halogen, hydroxy, or nitrile; or "B" is CH 2 CH(OH)CH 2 OCH 2 CH(OH)CH 2 Q; and r is an integer of at least 1 but not greater than q; and X(CF 2 ) m , W and Y are straight chains, branched chains or cyclic; and wherein the substituent chains of the above general formulas are the same or different; b. 50 to 96 percent by weight of said spin finish of water; and c. 2.5 to 30 percent by weight of said spin finish of a second noncontinuous phase which is capable of being emulsified with said first noncontinuous phase and said water without separation of any of the component parts of said spin finish.

Claim 14

A spin finish for yarn, made from synthetic organic polymer, to be processed into a yarn that is oil repellent and resistant to soiling, said spin finish comprising: a. 1.5 to 25 percent by weight of said spin finish of a first noncontinuous phase comprising: i. 15 to 80 weight percent of a quaternary ammonium salt selected from the group consisting of trialkyl dodecyl ammonium salt and cocotrialkyl ammonium salt, wherein the alkyl is methyl or ethyl and the anion of the salt is selected from the group consisting of chloride, bromide, iodide, sulfate, ethosulfate, methosulfate and mixtures thereof; and ii. 20 to 85 weight percent of a fluorochemical compound having the formula ##STR5## wherein the attachment of the fluorinated radicals and the radicals of CO 2 B to the nucleus is in asymmetrical positions with respect to rotation about the axis through the center of the nucleus; wherein "X" is fluorine, or perfluoroalkoxy of 1 to 6 carbon atoms, and m has arithmetic mean between 2 and 20; n is zero or unity; "W" and "Y" are alkylene, cycloalkylene or alkyleneoxy radicals of combined chain length from 2 to 20 atoms; (CF 2 ) m and "Y" have each at least 2 carbon atoms in the main chain; "Z" is oxygen and p is 1, or "Z" is nitrogen and p is 2; q is an integer of at least 2 but not greater than 5; "B" is CH 2 RCHOH or is CH 2 RCHOCH 2 RCHOH where "R" is hydrogen or methyl, or "B" is CH 2 CH(OH)CH 2 Q where Q is halogen, hydroxy, or nitrile; or "B" is CH 2 CH(OH)CH 2 OCH 2 CH(OH)CH 2 Q; and r is an integer of at least 1 but not greater than q; and X(CF 2 ) m , W and Y are straight chains, branched chains or cyclic; and wherein the substituent chains of the above general formulas are the same or different; b. 50 to 96 percent by weight of said spin finish of water; and c. 2.5 to 30 percent by weight of said spin finish of a second noncontinuous phase which is capable of being emulsified with said first noncontinuous phase and said water without separation of any of the component parts of said spin finish.

Claim 15

The spin finish of claim 12 wherein none of the component parts of said spin finish separate during commercial processing of said yarn.

Claim 16

The spin finish of claim 12 wherein the fluorochemical compound is a trimellitate, a pyromellitate, or a bis(diamide)/ester of trimellitic acid or of pyromellitic acid, wherein each fluorinated radical, of formula X(CF 2 ) m W(CONH) m Y, has a main chain containing at least six carbon atoms and contains at least four perfluorinated carbon atoms in the radical.

Claim 17

A polyamide yarn having incorporated therewith the spin finish of claim 14.

Claim 18

A polyester yarn having incorporated therewith the spin finish of claim 14.

Claim 19

The spin finish of claim 12 wherein the fluorochemical compound is a mixture of pyromellitates having the structure: ##STR6## A=(CH 2 ) 2 CF 2 ) n CF 3 where n is 5-13 B=CH 2 CHOHCH 2 Cl.

Claim 20

A polyamide yarn having incorporated therewith the spin finish of claim 17.

Claim 21

A polyester yarn having incorporated therewith the spin finish of claim 17.

Claim 22

The spin finish of claim 12 wherein the anion is chloride.

Claim 23

The spin finish of claim 12 wherein the anion is sulfate.

Claim 24

The spin finish of claim 12 wherein said second noncontinuous phase is selected from the group consisting of: a. 40 to 65 percent by weight of coconut oil, 15 to 35 percent by weight of polyoxyalkylene oleyl ether containing 5 to 20 moles of alkylene oxide per mole of olely alcohol, 2 to 10 percent by weight of polyoxyalkylene nonyl phenol containing 5 to 15 moles of alkylene oxide per mole of nonyl phenol, about 5 to 25 percent by weight of polyoxyalkylene stearate containing 4 to 15 moles of alkylene oxide per mole of stearic acid; b. 40 to 65 percent by weight of coconut oil, 15 to 35 percent by weight of polyoxyalkylene oleyl ether containing 8 to 20 moles of alkylene oxide per mole of oleyl alcohol, 2 to 10 percent by weight of polyoxyalkylene oleate containing 2 to 7 moles of alkylene oxide per mole of oleic acid, and 5 to 25 percent by weight of polyoxyalkylene castor oil containing 2 to 10 moles of alkylene oxide per mole of castor oil; c. 40 to 50 percent by weight of an alkyl stearate wherein the alkyl group contains 4 to 18 carbon atoms, 25 to 30 percent by weight of sorbitan monooleate, and 25 to 30 percent by weight of polyoxyalkylene tallow amine containing 18 to 22 moles of alkylene oxide per mole of tallow amine; d. 20 to 70 percent by weight of coconut oil, 10 to 50 percent by weight of polyoxyalkylene oleyl ether containing 5 to 20 moles of alkylene oxide per mole of oleyl alcohol, and 5 to 30 percent by weight of polyoxyalkylene stearate containing 4 to 15 moles of alkylene oxide per mole of stearic acid; and e. 100 percent by weight of a polyalkylene glycol ether.

Claim 25

A polyamide yarn having incorporated therewith the spin finish of claim 22.

Claim 26

A polyester yarn having incorporated therewith the spin finish of claim 22.

Claim 27

A spin finish for yarn, made from synthetic organic polymer, to be processed into a yarn that is oil repellent and resistant to soiling, said spin finish comprising: a. 2 to 20 percent by weight of said spin finish of a first noncontinuous phase comprising: i. 20 to 50 weight percent of a quaternary ammonium salt selected from the group consisting of trimethyldodecyl ammonium chloride and cocotrimethyl ammonium sulfate; and ii. 50 to 80 weight percent of a fluorochemical compound having the formula ##STR7## wherein the attachment of the fluorinated radicals and the radicals CO 2 B to the nucleus is in asymmetrical positions with respect to rotation about the axis through the center of the nucleus; wherein "X" is fluorine, or perfluoroalkoxy of 1 to 6 carbon atoms, and m has arithmetic mean between 2 and 20; n is zero or unity; "W" and "Y" are alkylene, cycloalkylene or alkyleneoxy radicals of combined chain length from 2 to 20 atoms; (CF 2 ) m and "Y" have each at least 2 carbon atoms in the main chain; "Z" is oxygen and p is 1, or "Z" is nitrogen and p is 2; q is an integer of at least 2 but not greater than 5; "B" is CH 2 RCHOH or is CH 2 RCHOCH 2 RCHOH where "R" is hydrogen or methyl, or "B" is CH 2 CH(OH)CH 2 Q where Q is halogen, hydroxy, or nitrile; or "B" is CH 2 CH(OH)CH 2 OCH 2 CH(OH)CH 2 Q; and r is an integer of at least 1 but not greater than q; and X(CF 2 ) m , W and Y are straight chains, branched chains or cyclic; and wherein the substituent chains of the above general formula are the same or different; b. 60 to 93 percent by weight of said spin finish of water; and c. 5 to 20 percent by weight of said spin finish of a second noncontinuous phase which is capable of being emulsified with said first noncontinuous phase and said water without separation of any of the component parts of said spin finish.

Claim 28

A spin finish for yarn, made from synthetic organic polymer, to be processed into a yarn that is oil repellent and resistant to soiling, said spin finish comprising: a. 2 to 20 percent by weight of said spin finish of a first noncontinuous phase comprising: i. 20 to 50 weight percent of a quaternary ammonium salt selected from the group consisting of trimethyldodecyl ammonium chloride and cocotrimethyl ammonium sulfate; and ii. 50 to 80 weight percent of a fluorochemical compound having the formula ##STR7## wherein the attachment of the fluorinated radicals and the radicals CO 2 B to the nucleus is in asymmetrical positions with respect to rotation about the axis through the center of the nucleus; wherein "X" is fluorine, or perfluoroalkoxy of 1 to 6 carbon atoms, and m has arithmetic mean between 2 and 20; n is zero or unity; "W" and "Y" are alkylene, cycloalkylene or alkyleneoxy radicals of combined chain length from 2 to 20 atoms; (CF 2 ) m and "Y" have each at least 2 carbon atoms in the main chain; "Z" is oxygen and p is 1, or "Z" is nitrogen and p is 2; q is an integer of at least 2 but not greater than 5; "B" is CH 2 RCHOH or is CH 2 RCHOCH 2 RCHOH where "R" is hydrogen or methyl, or "B" is CH 2 CH(OH)CH 2 Q where Q is halogen, hydroxy, or nitrile; or "B" is CH 2 CH(OH)CH 2 OCH 2 CH(OH)CH 2 Q; and r is an integer of at least 1 but not greater than q; and X(CF 2 ) m , W and Y are straight chains, branched chains or cyclic; and wherein the substituent chains of the above general formula are the same or different; b. 60 to 93 percent by weight of said spin finish of water; and c. 5 to 20 percent by weight of said spin finish of a second noncontinuous phase which is capable of being emulsified with said first noncontinuous phase and said water without separation of any of the component parts of said spin finish.

Claim 29

A polyamide yarn having incorporated therewith the spin finish of claim 25.

Claim 30

A polyester yarn having incorporated therewith the spin finish of claim 25.

Claim 31

The spin finish of claim 25 wherein said second noncontinuous phase is selected from the group consisting of: a. 55 percent by weight of coconut oil, 25 percent by weight of polyoxyethylene oleyl ether containing 10 moles of ethlene oxide per mole of oleyl alcohol, 5 percent by weight of polyoxyethylene nonyl phenol containing 9 moles of ethylene oxide per mole of nonyl phenol, and 15 percent by weight of polyoxyethylene stearate containing 8 moles of ethylene oxide per mole of stearic acid; b. 55 percent by weight of coconut oil, 25 percent by weight of polyoxyethylene oleyl ether containing 10 moles of ethylene oxide per mole of oleyl alcohol, 5 percent by weight of polyoxyethylene oleate containing 5 moles of ethylene oxide per mole of oleic acid, and 15 percent by weight of polyoxyethylene castor oil containing 5 moles of ethylene oxide per mole of castor oil; c. 44.5 percent by weight of butyl stearate, 27.75 percent by weight of sorbitan monooleate, and 27.75 percent by weight of polyoxyethylene tallow amine containing 20 moles of ethylene oxide per mole of tallow amine. d. 50 percent by weight of coconut oil, 30 percent by weight of polyoxyethylene oleyl ether containing 10 moles of ethylene oxide per mole of oleyl alcohol, and 20 percent by weight of polyoxyethylene stearate containing 8 moles of ethylene oxide per mole of stearic acid; and e. 100 percent by weight of a polyalkyene glycol ether.

Claim 32

A polyamide yarn having incorporated therewith the spin finish of claim 28.

Claim 33

A polyester yarn having incorporated therewith the spin finish of claim 28.