Patent US4424302A successfully refreshed from Google Patents.
US4424302A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of forming polymer particles
Assignee: WR Grace and Co Conn
•
Filing: 1980-08-11
•
Granted: 1984-01-03
•
Expires: 2000-08-11
Abstract
Abstract A process for forming polymeric particles from water-soluble polymers by introducing the polymer into an aqueous salt solution in which the salt is of a composition and present in an amount sufficient to inhibit solubilization of the polymer therein and subsequently introducing into the aqueous medium a multifunctional reagent and mixing said aqueous medium for a time and at a temperature sufficient to cause reaction between the polymer and the reagent. The resultant solid polymer is readily recovered.
Inventors
- 👤 Jacob Block
- 👤 Alan S. Michaels
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-28 18:35
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/12; C08J3/16; Y; Y10; Y10S; Y10S507/00; Y10S507/903
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
134 words
A process for forming cross-linked polymeric particles comprising forming an aqueous salt solution; introducing into said salt solution a water-soluble polyvinyl alcohol polymer, said solution containing salt of a composition and present in an amount sufficient to inhibit solubilization of the polymer in the aqueous salt solution; introducing a polyfunctional reagent capable of reacting with at least two hydroxy groups of said polymer: said reagent selected from the group consisting of aldehyde containing compounds, di- and polycarboxylic acids, methylol and alkoxymethyl substituted ureas, or methylol and alkoxymethyl substituted melamines; mixing said aqueous solution at a temperature and for a time sufficient to cause said polyfunctional reagent to react with said polymeric hydroxyl groups; and recovering the polymeric product as a dry powder which is capable of forming discrete gelled particles when reconstituted with water.
Claim 2
Dependent Claim
134 words
A process for forming cross-linked polymeric particles comprising forming an aqueous salt solution; introducing into said salt solution a water-soluble polyvinyl alcohol polymer, said solution containing salt of a composition and present in an amount sufficient to inhibit solubilization of the polymer in the aqueous salt solution; introducing a polyfunctional reagent capable of reacting with at least two hydroxy groups of said polymer: said reagent selected from the group consisting of aldehyde containing compounds, di- and polycarboxylic acids, methylol and alkoxymethyl substituted ureas, or methylol and alkoxymethyl substituted melamines; mixing said aqueous solution at a temperature and for a time sufficient to cause said polyfunctional reagent to react with said polymeric hydroxyl groups; and recovering the polymeric product as a dry powder which is capable of forming discrete gelled particles when reconstituted with water.
Claim 3
Dependent Claim
49 words
The process of claim 1 wherein the polyfunctional reagent is selected from the group consisting of an aldehyde containing compound, a dicarboxylic acid or a polycarboxylic acid; and said salt is selected from the group consisting of an alkali metal, alkaline earth metal or ammonium sulfate, nitrate or phosphate.
Claim 4
Dependent Claim
33 words
The process of claim 1 wherein the polyfunctional reagent is the group consisting of formaldehyde, acetaldehyde, is selected from trioxane, glyoxal, paraformaldehyde, trimethylol melamine, hexamethylol melamine or tri(C 1 -C 3 alkoxymethyl) melamine.
Claim 5
Dependent Claim
29 words
The process of claim 1 wherein the polyvinyl alcohol has a weight average molecular weight of at least 20,000 and is at least about a 75 percent hydrolyzed product.
Claim 6
Dependent Claim
29 words
The process of claim 2 wherein the polyvinyl alcohol has a weight average molecular weight of at least 20,000 and is at least about a 75 percent hydrolyzed product.
Claim 7
Dependent Claim
29 words
The process of claim 3 wherein the polyvinyl alcohol has a weight average molecular weight of at least 20,000 and is at least about a 75 percent hydrolyzed product.
Claim 8
Dependent Claim
13 words
The process of claim 6 wherein the salt is an alkali metal sulfate.
Claim 9
Dependent Claim
13 words
The process of claim 6 wherein the salt is an alkali metal nitrate.
Claim 10
Dependent Claim
11 words
A cross-linked polymeric product formed by the process of claim 1.
Claim 11
Dependent Claim
11 words
A cross-linked polymeric product formed by the process of claim 7.
Claim 12
Dependent Claim
11 words
A cross-linked polymeric product formed by the process of claim 8.
References Cited (Backward Citations)
GB356408A
Cited
US2879268A
Cited
US3072635A
Cited
US3252904A
Cited
US3461115A
Cited
US3727688A
Cited
US3727689A
Cited
US3909423A
Cited
US4272470A
Cited
US4309535A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-01-02 | 1987-07-04 | 1988-01-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-01-02 | 1991-07-04 | 1992-01-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-01-02 | 1995-07-04 | 1996-01-03 | $7700.00 | Window Closed / Lapsed |